MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Revision date Version # 22 CAS # MSDS Number Product use Synonym(s) Manufacturer/Supplier General Information: Emergency 2. Hazards Identification Mixture 324B Curing Agent for MA-25S Type II Part A, Ablative Coating. MA25S Type II Part B, Firecoat Material Lockheed Martin Space Systems Company P.O. Box 29304, New Orleans, LA US keith.f.baty@lmco.com Contact Person: Program Manager Hour Emergency: CHEMTREC Physical state Appearance Emergency overview Liquid. Colorless, transparent viscous liquid. CAUTION! Prolonged or repeated skin contact may cause drying, cracking, or irritation. OSHA regulatory status This product is not hazardous according to OSHA 29CFR Potential health effects Eyes Direct contact with eyes may cause temporary irritation. Skin Prolonged or repeated skin contact may cause drying, cracking, or irritation. Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard. Ingestion harmful effects expected in amounts likely to be ingested by accident. Potential environmental effects t expected to be harmful to aquatic organisms. 3. Composition / Information on Ingredients Components CAS # Percent Organopolysiloxane Composition comments Mixture 100 All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion tes to physician Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. Get medical attention promptly if symptoms occur after washing. Wash skin with soap and water. Get medical attention promptly if symptoms occur after washing. If symptomatic, move to fresh air. Get medical attention if symptoms persist. Seek medical advice. Treat symptomatically. Exposure may aggravate pre-existing skin disorders. 5. Fire Fighting Measures Flammable properties unusual fire or explosion hazards noted. 1 / 5

2 Extinguishing media Suitable extinguishing media Fire fighting equipment/instructions Hazardous combustion products Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate personal protective equipment and clothing must be worn by responders. Carbon oxides. Silicon oxides. 6. Accidental Release Measures Personal precautions Wear appropriate personal protective equipment (See Section 8). Environmental precautions Environmental manager should be informed of all releases, as necessary. Reporting of releases to appropriate regulatory agencies may be required. Methods for cleaning up Stop leak if you can do so safely. Absorb spill with appropriate sand, clay or other inert sorbent material, then place in appropriate waste container. 7. Handling and Storage Large Spills: Flush area with water. Prevent runoff from entering drains, sewers, or streams. Dike for later disposal. Handling Wear appropriate personal protective equipment (See Section 8). Wash thoroughly after handling. Storage Keep container closed. Store away from incompatible materials (See Section 10). 8. Exposure Controls / Personal Protection Occupational exposure limits Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations exposure limits noted for ingredient(s). Ensure adequate ventilation, especially in confined areas. Wear safety glasses with side shields (or goggles). Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure. Contact glove manufacturer for specific information. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical & Chemical Properties Appearance Color Odor Odor threshold Physical state Form ph Melting point Freezing point Boiling point Flash point Evaporation rate Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Colorless, transparent viscous liquid. Transparent. Odorless. Liquid. Viscous liquid. 2 / 5

3 Vapor pressure Vapor density Specific gravity Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Percent volatile Insoluble. 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Material is stable under normal conditions. Excessive heat. Strong oxidizing agents. Acids. Bases. hazardous decomposition products are known. Hazardous polymerization does not occur. 11. Toxicological Information Acute effects Sensitization Carcinogenicity Direct contact with eyes may cause temporary irritation. Prolonged or repeated skin contact may cause drying, cracking, or irritation. sensitizing effects known. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. 12. Ecological Information Ecotoxicity Persistence and degradability Bioaccumulation / Accumulation Partition coefficient (n-octanol/water) Mobility in environmental media t expected to be harmful to aquatic organisms. data available. data available. 13. Disposal Considerations Disposal instructions Contaminated packaging Dispose of contents/container in accordance with local/regional/national/international regulations. When this product as supplied is to be discarded as waste, it does not meet the definition of a RCRA waste under 40 CFR 261. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport Information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. TDG t regulated as dangerous goods. 15. Regulatory Information US federal regulations This product is not hazardous according to OSHA 29CFR / 5

4 TSCA Section 12(b) Export tification(40 CFR 707, Subpt. D) t regulated. CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4) ne Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance (40 CRF 355, Appendix A) Section 311/312 (40 CFR 370) Drug Enforcement Administration (DEA) (21 CFR ) Canadian regulations WHMIS status Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - t controlled This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. n-controlled Inventory status Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada n-domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of tified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Mexico regulations This safety data sheet was prepared in accordance with the Official Mexican Standard (NOM-018-STPS-2000). 16. Other Information Further information WHMIS: Workplace Hazardous Materials Information System. HMIS is a registered trade and service mark of the NPCA. This safety data sheet contains revisions in the following section(s): 1-16 Document format revised to conform to current ANSI Z400.1 and ISO standards. HMIS ratings Health: 1 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 0 Flammability: 1 Instability: 0 4 / 5

5 Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Issue date / 5