MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Revision date Version # 01 CAS # Mixture Product code 271XX Product use Lubricant. Manufacturer/Supplier Star brite Distributing, Inc SW 47th Avenue Fort Lauderdale, FL US General Information: (954) Contact Person: Vincent Waclawek Emergency 24-Hour Emergency: CHEMTREC: (703) or (800) Hazards Identification Physical state Appearance Emergency overview Green liquid. WARNING! Harmful if swallowed - may enter lungs if swallowed or vomited. OSHA regulatory status This product is hazardous according to OSHA 29 CFR Potential health effects Routes of exposure Inhalation. Skin contact. Ingestion. Eyes Direct contact with eyes may cause temporary irritation. Skin Prolonged or repeated contact may dry skin and cause irritation. Inhalation Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and respiratory tract irritation. Ingestion Harmful if swallowed - may enter lungs if swallowed or vomited. Signs and symptoms Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and respiratory tract irritation. Potential environmental effects t expected to be harmful to aquatic organisms. 3. Composition / Information on Ingredients CAS # Percent Distillates (petroleum), solvent-refined heavy paraffinic Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion tes to physician Any material that contacts the eye should be washed out imtely with water. If easy to do, remove contact lenses. Get medical attention if symptoms persist. Wash with soap and water. Get medical attention if irritation persists after washing. If symptomatic, move to fresh air. Get medical attention if symptoms persist. DO NOT induce vomiting. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than the hips to help prevent aspiration. Call a physician or poison control center imtely. Treat symptomatically. 1 / 5

2 5. Fire Fighting Measures Flammable properties Extinguishing Suitable extinguishing Unsuitable extinguishing Fire fighting equipment/instructions Specific methods Hazardous combustion unusual fire or explosion hazards noted. Carbon dioxide (CO2). Foam. Dry chemical. Water fog. ne known. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Carbon oxides. Nitrogen oxides. Sulfur oxides. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for Personal Protective Equipment. Collect and dispose of spillage as indicated in Section 13 of the MSDS. Dike the spilled material, where this is possible. Prevent entry into waterways, sewer, basements or confined areas. Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Other information 7. Handling and Storage Handling Storage Never return spills to original containers for re-use. Following product recovery, flush area with water. Clean surface thoroughly to remove residual contamination. Clean up in accordance with all applicable regulations. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrial hygiene practices. Keep container tightly closed and in a well-ventilated place. Store in closed original container at room temperature. Store away from incompatible materials. 8. Exposure Controls / Personal Protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) PEL 2000 mg/m3 5 mg/m3 Mist. 500 ppm Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents) Distillate s (petroleum), TWA 1600 mg/m3 Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) TWA 5 mg/m3 Mist. 2 / 5

3 Mexico. Occupational Exposure Limit s Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations 9. Physical & Chemical Properties TWA 5 mg/m3 Mist. Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors. Use approved safety goggles or face shield. Wear appropriate chemical resistant clothing to prevent any possibility of skin contact. In case of inadequate ventilation, use respiratory protection. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Appearance Green liquid. Color Green. Odor Petroleum. Odor threshold Physical state ph 7 Approximate. Melting point Freezing point Boiling point > 550 F (> C) Flash point 375 F (190.6 C) Cleveland Open Cup Evaporation rate Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity Solubility (water) Insoluble. Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity 0.92 (20 C) 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition Possibility of hazardous reactions Material is stable under normal conditions. Contact with incompatible materials. Strong oxidizing agents. hazardous decomposition are known. Will not occur. 3 / 5

4 11. Toxicological Information Acute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and respiratory tract irritation. Sensitization ne known. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. ACGIH Carcinogens Distillates (petroleum), solvent-refined heavy paraffinic A4 t classifiable as a human carcinogen. 12. Ecological Information Ecotoxicity Persistence and degradability Bioaccumulation / Accumulation Partition coefficient (n-octanol/water) Mobility in environmental t expected to be harmful to aquatic organisms. 13. Disposal Considerations Disposal instructions Waste from residues / unused Contaminated packaging Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of waste and residues in accordance with local authority requirements. Since emptied containers retain product residue, follow label warnings even after container is emptied. 14. Transport Information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. TDG t regulated as dangerous goods. 15. Regulatory Information US federal regulations This product is hazardous according to OSHA 29 CFR TSCA Section 12(b) Export tification(40 CFR 707, Subpt. D) t regulated. CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4) ne Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Imte Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - Section 302 extremely hazardous substance (40 CRF 355, Appendix A) Section 311/312 (40 CFR 370) 4 / 5

5 Drug Enforcement Administration (DEA) (21 CFR ) Canadian regulations WHMIS status t controlled This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. n-controlled Inventory status Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada n-domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of tified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance US - Massachusetts RTK - Substance: Listed substance US - New Jersey RTK - Substances: Listed substance 16. Other Information HMIS ratings Health: 2 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 1 Instability: 0 Disclaimer The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Star brite assumes no responsibility for injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Star brite assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material. Issue date / 5