SDS for Product: Non-para Block Toilet Bowl Deodorizer, Rev. Date: 05 April Sheet No. 66 Revision Date: 05 April 2018
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1 Sheet No. 66 Revision Date: 05 April 2018 HMIS: Health- 1 Flammability- 0 Reactivity- 0 Pers. Protection- N WHMIS: Not regulated Product: Non-para Block Toilet Bowl Deodorizer NILODOR, INC INDUSTRIAL PARKWAY NW BOLIVAR, OHIO 44612, USA Non-Emergency: US International EMERGENCY OVERVIEW Appearance/Odor: SAFETY DATA SHEET NFPA: Health- 1 Flammability- 0 Reactivity- 0 Special Hazard- N Section 1: Product and Company Identification Synonyms: 24 hr Emergency Spill Information: Chem-Tel, Inc. Blue solid in white plastic cage US, Canada: International: Section 2. Hazards Identification WARNING Flammability : Not classified as flammable Health Hazards Listed : May be a mild irritant Ecological Hazards Listed : Potential Health Effects: See section 11 for more information. Risk Phrases: Safety Phrases: Hazard Phrases: Precautionary Phrases: R22 - Harmful if swallowed R36/37/38 - Irritating to eyes, respiratory system and skin S2 - Keep out of the reach of children S37 - Wear suitable gloves H303 - May be harmful if swallowed H333 - May be harmful if inhaled P202 - Do not handle until all safety precautions have been read and understood. P280 - Wash thoroughly after handling. Likely Routes of Exposure: Not applicable 1
2 Eye: Skin: Ingestion: Medical Conditions Aggravated By Exposure: Allergies to fragrances Target Organs: Not applicable Not applicable Not expected to be a problem Not likely to be a problem This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Potential Environmental Effects: (See section 12 for more information.) Section 3. Composition/Information on Ingredients Component CAS# % by Weight Sodium Borate Pentahydrate Y Sodium Sulfate Not stated N Polyethylene Glycol Not stated N Only ingredients known Sodium Dodecylbenzene Sulfonate Y Eye Contact: Skin Contact: Ingestion: Note to Physicians: Suitable Extinguishing Media: Unsuitable Extinguishing Media: Products of Combustion: Protection of Firefighters: Personal Precautions: Environmental Precautions: Methods for Containment: Methods for Clean-Up: Other Information: HANDLING Section 4. First Aid Measures WHMIS Controlled Flush eyes with copious amounts of clean water, holding lids open. If irritation persists, consult a physician Wash with soap and water. Remove to fresh air. Give water or milk to drink if conscious. Section 5. Fire Fighting Measures As for surrounding fire. Oxides of carbon, sulfur, boron As for surrounding fire Section 6. Accidental Release Measures Keep cake away from skin and eyes Keep out of surface waters If dry, not applicable. If wet, contain affected water with sand, clay or or other suitable material Gather up scattered units Section 7. Handling and Storage Reasonable care. Keep away from skin and eyes. Do not open inner bag until ready to install STORAGE SDS for Product: Non-para Block Toilet Bowl Deodorizer, Rev. Date: 05 April 2018 Keep out of the reach of children. Store in original container at ambient conditions. 2
3 Section 8. Exposure Controls/Personal Protection EXPOSURE GUIDELINES COMPONENT: TWA: LD-50 Sodium Borate Pentahydrate TLV 1 mg/cubic m More than 3200 mg/kg Sodium Sulfate None established 5989 mg/kg Polyethylene Glycol None established mg/kg Only ingredients known Sodium Dodecylbenzene Sulfonate None established 1260 mg/kg Engineering Controls: Not normally necessary Eye/Face Protection: Not normally necessary Skin Protection: Not necessary if unit handled by plastic cage Respiratory Protection: Not normally necessary General Hygiene Considerations: Keep away from food and beverages Section 9. Physical and Chemical Properties Color: Blue cake in white cage Odor: Spicy (Original, 2003) Physical State: Solid ph: Not applicable Evaporation Rate: Not applicable Flash Point: Not applicable Upper Flammability Limit: Not applicable Vapor Pressure: Not determined Vapor Density: Not determined Volatile Organic Compound (VOC),%weight: Information not available. All fragrances Stability: Stable Conditions to Avoid: Incompatable Materials: Hazardous Decomposition Products: Odor Treshhold: Freezing Point: Not applicable Boiling Point: Not applicable Flammability(solid,gas): Not considered flammable Lower Flammabilty Limit: Not applicable Specific Gravity: Not applicable Auto-ignition Temperature: Not determined Solubility (water): Cake is soluble. Cage is insoluble. Percent Volatile: Information not available. All fragrances Section 10. Stability and Reactivity Possibility of Hazardous Reactions: Extremely improbable ACCUTE EFFECTS Oral LD50: Dermal LD50: Eye Irritation: Skin Irritation: Sensitization: CHRONIC EFFECTS Carcinogenicity: Section 11. Toxicology Information Not determined for mixture. No components at less than 1200 mg/kg. Not determined for mixture. No components at less than 2000 mg/kg. Not determined. Weighted average more than 3 mg/l Direct contact with particles of cake can irritate Direct contact with cake can irritate 3
4 Mutagenicity: Reproductive Effects: Developmental Effects: Section 12. Ecological Information Ecotoxicity: Persistence/Degradability: Moderately biodegradable Bioaccumulation/Accumulation: Not determined Mobility in Enviroment: Not determined Section 13. Disposal Considerations Disposal: Dispose according to Commonwealth, State and Local regulations Section 14. Transportation Information US DOT (ground) Proper Shipping Description: Not a Hazardous Material CANADA TDG (ground) ICAO (air) IMDG (water) Section 15. Regulatory Information Global Inventories TSCA: United States Included DSL: Canada Included ECL: Korea PICCS: Philippines ENCS: Japan AICS: Australia Included IECS: China EINECS: European Union Included SARA 313 Information : No SARA 313 substances present California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65) No Proposition 65 substances present WHMIS: Canadian Workplace Hazardous Material Information System Not regulated Section 16. Other Information Legends: NFPA, HMIS: 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard Prepared By: Technical Dept. 4
5 While we believe that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for which we assume legal responsibility. The information is offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws. 5
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