MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 MATERIAL SAFETY DATA SHEET Product Name CAS # Product use Manufacturer LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal Product and Company Identification Rid O' Rust Exterior Rust Stain Remover (Powder Formula) Mixture Rust Stain Remover Pro Products LLC 7201 Engle Road Fort Wayne, IN US Phone Emergency Phone: (CHEMTREC) Health Flammability Physical Hazard Personal Protection / B 2 Hazards Identification Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms DANGER -- CORROSIVE POISON Eye, Skin contact, Inhalation, Ingestion Causes chemical burns May cause blindness Causes chemical burns May cause respiratory tract irritation or chemical burns Toxic and is harmful if swallowed May cause chemical burns to mouth, throat and stomach Eyes Respiratory system Skin Chronic inhalation of oxalic acid can result in formation of kidney and urinary tract stones Prolonged or repeated exposure can cause drying, defatting and dermatitis Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting The product causes burns of eyes, skin and mucous membranes 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent First aid procedures Eye contact Skin contact Inhalation Ingestion 4 First Aid Measures Immediately flush with cool water Remove contact lenses, if applicable, and continue flushing for 15 minutes Obtain medical attention immediately Brush away excess of dry material Immediately flush with cool water for 15 minutes Obtain medical attention if irritation persists Wash contaminated clothing well before reuse or discard If symptoms develop, move victim to fresh air If symptoms persist, obtain medical attention If breathing has stopped, trained personnel should administer CPR immediately Do not induce vomiting Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration #19500 Page 1 of 6

2 Notes to physician General advice Treat patient symptomatically Avoid contact with eyes and skin Keep out of reach of children Immediate medical attention is required Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance 5 Fire Fighting Measures Flammable properties Not flammable by WHMIS/OSHA criteria Extinguishing media Suitable extinguishing media Dry chemical Water spray Alcohol foam Carbon dioxide Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon Formic acid 6 Accidental Release Measures Personal precautions Methods for containment Methods for cleaning up Handling Storage Exposure limits Ingredient(s) Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Use broom or dry vacuum to collect material for proper disposal without raising dust Rinse area with water Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice 7 Handling and Storage Avoid breathing dust Use good industrial hygiene practices in handling this material Do not get this material in your eyes, on your skin, or on your clothing Keep out of the reach of children Store in a closed container away from incompatible materials 8 Exposure Controls / Personal Protection Exposure Limits Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection Local exhaust recommended Wear chemical goggles ACGIH-TLV TWA: 1 mg/m3 STEL: 2 mg/m3 OSHA-PEL TWA: 1 mg/m3 Impervious gloves Confirm with reputable supplier first As required by employer code Use of an impervious apron is recommended Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product #19500 Page 2 of 6

3 9 Physical and Chemical Properties Appearance Color Form Odor Odor threshold Physical state ph Melting point Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Crystalline Colorless Solid Odorless Solid Specific gravity 165 Octanol/water coefficient Solubility (H2O) Percent volatile 13 (01M solution) F (1015 C) F ( C) Not applicable Not applicable Soluble Molecular weight Stability and Reactivity Chemical stability Conditions to avoid Incompatible materials Stable under recommended storage conditions Do not mix with other chemicals Caustics Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Formic acid Possibility of hazardous reactions Hazardous polymerization does not occur 11 Toxicological Information Component analysis - LC50 Ingredient(s) Component analysis - Oral LD50 Ingredient(s) Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Local effects Chronic effects Carcinogenicity LC50 LD mg/kg rat Causes chemical burns May cause blindness Causes chemical burns May cause respiratory tract irritation or chemical burns Toxic and is harmful if swallowed May cause chemical burns to mouth, throat and stomach Non-hazardous by WHMIS/OSHA criteria Toxic if swallowed Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria #19500 Page 3 of 6

4 Mutagenicity Reproductive effects Teratogenicity Synergistic Materials Ecotoxicity Environmental effects Aquatic toxicity Persistence / degradability Bioaccumulation / accumulation Partition coefficient Mobility in environmental media Chemical fate information Other adverse effects Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria 12 Ecological Information 13 Disposal Considerations Review federal, state/provincial, and local government requirements prior to disposal 14 Transport Information US Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Corrosive solid, acidic, organic, nos (ETHANEDIOIC ACID, DIHYDRATE) Hazard class UN number Packing group Additional information: Special provisions Packaging exceptions ERG number 8 UN3261 III IB8, IP3, T1, TP Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name CORROSIVE SOLID, ACIDIC, ORGANIC, NOS (ETHANEDIOIC ACID, DIHYDRATE) Hazard class UN number Packing group Additional information: Special provisions 8 UN3261 III 16 #19500 Page 4 of 6

5 Canadian federal regulations US Federal regulations 15 Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the US EPA TSCA Inventory List CERCLA/SARA Hazardous Substances - Not applicable Occupational Safety and Health Administration (OSHA) 29 CFR hazardous Yes chemical CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) WHMIS status WHMIS classification WHMIS labeling Controlled Class D - Division 1B, Class E - Corrosive Material State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm US - Pennsylvania - RTK (Right to Know) List Present US - Rhode Island - Hazardous Substance List Flammable Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Effective date Expiry date 16 Other Information Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 15-Aug Aug-2012 Prepared by Dell Tech Laboratories Ltd (519) #19500 Page 5 of 6

6 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #19500 Page 6 of 6