SAFETY DATA SHEET Page 1 of 6

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1 Revised: 5/9/18 NAME: PHENOBARBITAL SAFETY DATA SHEET Page 1 of 6 Humco Holding Group, Inc Alumax Dr Texarkana TX USA cs@humco.com 24-Hour Emergency Number (CHEMTREC) USA International All non-emergency calls should be directed to Customer Service at SDS NO. 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Phenobarbital Synonyms: Phenobarbitalum Recommended Use: No relevant information available. Manufacturer / Supplier: Humco Holding Group, Inc Alumax Dr Texarkana TX USA cs@humco.com 24-Hour Emergency Number (CHEMTREC) USA International All non-emergency calls should be directed to Customer Service at HAZARD IDENTIFICATION Pictogram: Classification: Signal Word: Hazard Statements: GHS06 GHS07 GHS08 Acute Tox. 3 H301 Toxic if swallowed. Carc. 2 H351 Suspected of causing cancer. Repr. 1A H360 May damage fertillity or the unbron child. Skin Sens. 1 H317 May cause an allergic skin reaction. Danger H301 Toxic if swallowed. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. May damage fertility or the unborn child.

2 Page 2 of 6 3. COMPOSITION / INGREDIENTS CHEMICAL NAME PHENOBARBITAL PHENOBARBITALUM CAS# The exact percentage has been withheld as a trade secret 4. FIRST-AID MEASURES ROUTE COMMON SYMPTOMS FIRST AID Inhalation Not determined In case of unconsciousness place patient stably in side position for transportation. Supply fresh air and be sure to call for a doctor. Ingestion Not determined Do not induce vomiting. Immediately call for help. Skin Not determined Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. Eyes Not determined Rinse opened eye for several minutes under running water. Then consult a doctor. 5. FIRE-FIGHTING MEASURES Flash Point: Auto Ignition: Extinguishing Media: Products of Combustion: Fire Fighting Equipment and Procedures: Not applicable Not determined Water, Foam, Carbon Dioxide, Fire-extinguishing powder, Sand. Formation of toxic gases is possible during heating or in case of fire. Nitrogen oxides (NOx) Carbon monoxide(co) Wear self-contained respiratory protective device. Wear fully protective suit. Collect contaminated firefighting water separately. It must not enter the sewage system.

3 Page 3 of 6 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Method of Containment: Method for Clean-Up: Not required Do not allow to enter sewers/surface or ground water. Ensure adequate ventilation Not determined 7. HANDLING AND STORAGE Handling: Storage: Open and handle receptacle with care. Store under lock and key and with access restricted to technical experts or their assistants only. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering Controls: Personal Protective Equipment (PPE) Eye/Face Protection: Skin Protection: Respiratory Protection General Hygiene Considerations: Normal room ventilation is usually adequate under normal use. Protective work clothes Not required Protective gloves Suitable respiratory protective device recommended, Filter P2 Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work.

4 Page 4 of 6 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Whitish Upper/Lower Flammability: Not Applicable Odor: Recognizable Vapor Pressure Not Applicable Odor Threshold: Vapor Density: Not Applicable ph: Not Applicable Relative Density: Melting point /Freezing Point: C ( F) / Solubilities: 1 g/l Boiling point/range: Partition coefficient: n-octanol/water: Flash point Not Applicable Auto-ignition temperature Evaporation rate Not Applicable Decomposition Temperature: Flammability: Product is not flammable. Viscosity Not Applicable 10. STABILITY AND REACTIVITY Reactivity: Chemical Stability: Possibility of Hazardous reactions: Conditions to Avoid: Incompatible materials: Hazardous Decomposition Products: Reacts with strong oxidizing agents. Risk of dust explosion Carbon Monoxide and Carbon Dioxide Nitrogen Oxides (NOx)

5 Page 5 of TOXICOLOGICAL INFORMATION Acute toxicity: Skin irritation: Eye contact damage: Respiratory damage: Ingestion overdose: Delayed, immediate, or chronic effects from short- and long-term exposure LD50 No Irritating effect. No irritating effect. 137 mg/kg (mus) 162 mg/kg (rat) Symptoms associated with exposure: Carcinogenicity: OSHA: NTP: IARC: Substance is not listed. Substance is not listed. 2B 12. ECOLOGICAL INFORMATION Acute or chronic aquatic toxicity: Chemical degradation: Biodegradation: Bioaccumulation potential Adsorption studies or leaching studies: Other adverse effects EC50 (24h) 1460 mg/l (Daphnia) LC50 (96h) 484 mg/l (Fish) Biodegradable

6 Page 6 of DISPOSAL CONSIDERATIONS Dispose in accordance with federal, state and local laws and regulations. Avoid release into environment. Must not be disposed of together with household garbage. Do not allow product to reach sewage system. 14. TRANSPORT INFORMATION DOT Hazard Classification: UN number: UN proper shipping name: Transport hazard class(es): Packing group number: Environmental hazards: Special precautions: Not determined. UN2811 Toxic solids, organic, n.o.s. (Phenobarbital Phenobarbitalum). 6.1 Toxic substances III Not applicable. Warning: Toxic substances. 15. REGULATORY INFORMATION 16. OTHER INFORMATION The information in this SDS is considered current and reliable. However, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal are beyond Humco s control, it is the responsibility of the user to determine safe conditions for use and to assume liability for loss, damage, or expenses arising from improper use. No warranty expressed or implied regarding the product described herein will be created by or inferred from any statement or omission. Various agencies may have specific regulations concerning the transportation, handling, storage, use or disposal of this product which may not be reflected in the SDS. The user should review these regulations to ensure full compliance.