SAFETY DATA SHEET. This SDS complies with REACH 1907/2006 and 2001/58/EC, GHS, OSHA 29CFR

Transcription

1 SAFETY DATA SHEET This SDS complies with REACH 1907/2006 and 2001/58/EC, GHS, OSHA 29CFR SDS Page 1 of 5 Section 1: Chemical Product and Company Identification CHEMICAL SUPPLIER COMPANY NAME EMERGENCY TELEPHONE Shin-Etsu MicroSi, Inc. Chemtrec 24 hrs: (800) South 51 st Street Information: (480) Phoenix, AZ Fax: (480) Safety Data Sheet Competent Person: Customer Service csteam@microsi.com MANUFACTURER S NAME: Nissin Chemical Industry Co., Ltd. ADDRESS: Uchikanda TK Bldg Uchikanda, Chiyodaku, Tokyo, , Japan TELEPHONE NUMBER: FAX NUMBER: DATE PREPARED: February 23, 2009 DATE REVIEWED: December 14, 2012 PRODUCT NAME: VINYBLAN 701 CHEMICAL FAMILY: PRODUCT USE: Section 2: Hazards Identification Colloidal dispersion of PVC copolymer in water. This product is intended for use in inks, coatings, adhesives and sealants. GHS Hazard Class Not Applicable Signal word: Hazard Statement: Precautionary Statements: Prevention Response Storage Disposal <15 % of mixture consists of ingredients of unknown acute toxicity HAZARD CLASSIFICATION: Not Hazardous FIRE AND EXPLOSION: Not considered flammable or combustible. NFPA RATINGS: Component Health (Blue) Flammability (Red) Instability (Yellow) Special (White) VINYBLAN POTENTIAL HEALTH EFFECTS INGESTION: INHALATION: SKIN CONTACT: EYE CONTACT:. May cause slight irritation to mucous membranes and upper respiratory tract. May cause slight skin irritation or reaction. May cause eye irritation. Section 3: Composition, Information on Ingredients PRODUCT COMPOSITION APPROX ACGIH OSHA NIOSH CAS % TLV PEL REL NO. Water Acrylic resin TS Polyvinyl Chloride Some items on this MSDS may be designated as trade secrets (TS). Bona fide requests for disclosure of trade secret information to medical personnel must be made in accordance with the provisions contained in 29 CFR I 1-13.

2 Section 4: First Aid Measures SDS Page 2 of 5 INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: Section 5: Fire-fighting Measures FLASH POINT: FLAMMABLE LIMITS IN AIR (% by vol): EXTINGUISHING MEDIA: SPECIAL FIREFIGHTING PROCEDURES: UNUSUAL FIRE AND EXPLOSION HAZARDS: Section 6: Accidental Release Measures ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wear proper protective equipment as specified in the protective equipment section. Absorb spill with inert material. Warn other workers of spill. Prevent spills or contaminated rinse water from entering sewers or watercourses. DISPOSAL METHOD: Disposal of this container: Reference Section 13 of this MSDS. Section 7: Handling and Storage PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Use only in well ventilated areas. Store upright in a cool, well ventilated location. Prevent freezing of product. Protect from direct sunlight. Keep container closed when not in use. Wear proper protective equipment when handling this material. Avoid contact with skin, eyes or clothing. Wash hands after handling this material. Follow all applicable local regulations for handling and storage. Utilize chemical segregation. INFORMATION ON EMPTIED CONTAINER Dispose of this container according to local, state, and federal laws in your country. Do not reuse this container. This container may be hazardous when emptied. Section 8: Exposure Controls/Personal Protection Remove to fresh air. If not breathing, provide CPR (cardio pulmonary resuscitation) get immediate medical attention. Wash skin with clean water. Get medical attention if irritation persists. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. If swallowed do not induce vomiting, give large quantities of water to drink. Never give anything to an unconscious person. Get immediate medical attention. Not applicable Lower: Not Applicable; Upper: Not Applicable Foam, Dry Chemical, Carbon Dioxide, Fine Water Spray Firefighters should wear proper protective equipment. During fire, irritating and highly toxic gas may be generated by thermal decomposition or combustion. VENTILATION: RESPIRATORY PROTECTION: PROTECTIVE GLOVES: EYE PROTECTION: PROTECTIVE CLOTHING: OTHER EQUIPMENT: WORK/HYGIENE PRACTICES: Always provide good general, mechanical room ventilation where this chemical is used. Not required. Wear chemical impervious gloves at all times while working with this product. Recommended glove types include: Laminate Film, Nitrile, or Tri-polymer. Check with your company s glove supplier to ensure chemical resistance. Safety Glasses, Chemical goggles, face shield Wear suitable protective clothing to prevent skin contact. Make safety shower, eyewash stations, and hand washing equipment available in the work area. Avoid contact with eyes. Wash hands after handling.

3 Section 9: Physical and Chemical Properties SDS Page 3 of 5 APPEARANCE - COLOR: Milky white dispersion PHYSICAL STATE: Liquid SOLIDS: % ODOR: Peculiar Odor PRODUCT CRITERIA ODOR THRESHOLD PH FLASH POINT: LOWER EXPLOSIVE LIMIT; UPPER EXPLOSIVE LIMIT FLAMMABILITY (Solid, gas) EXPLOSIVE PROPERTIES OXIDIZING PROPERTIES SPECIFIC GRAVITY (@25 o C): EVAPORATION RATE: Negligible % VOLATILE by VOLUME PARTITION COEFFICIENT AUTO IGNITION TEMPERATURE DECOMPOSITION TEMPERATURE BOILING POINT: Approximately 100 ºC MELTING POINT: VAPOR PRESSURE Negligible VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER: Dispersion WATER SOLUBILITY IN THE SOLVENT FREEZING POINT: VISCOSITY VOC CONTENT Section 10: Stability and Reactivity STABILITY: CONDITIONS TO AVOID: INCOMPATIBILITY (MATERIALS TO AVOID): HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS POLYMERIZATION: Section 11: Toxicological Information <100 mpa s Stable. Heat, direct sunshine, contact with acids, metallic oxides, amines, combustible materials, sparks, and other sources of ignition. Acids, metallic oxides, amines, combustible materials. Toxic fumes of carbon monoxide, carbon dioxide and/or hydrogen chloride when heated to decomposition of the polymer. Will not occur. GHS Required Criteria Toxicity Criteria Toxicity Information Comments Chemical Constituent Acute Toxicity TDLo (Oral/Rat) 210 g/kg Polyvinyl Chloride TDLo (Intratracheal/Rat) 50 mg/kg Polyvinyl Chloride Skin Corrosion/Irritation Serious Eye Damage / Eye Irritation Respiratory or Skin Sensitization Germ Cell Mutagenicity Tumorigenic Carcinogenicity Not listed NTP Group 3, Human and Animal Inadequate Evidence 1979 IARC Not listed OSHA Reproductive Toxicity STOST -- Single Exposure STOST Repeated Exposure Aspiration Hazard STOST = Specific Target Organ Systemic Toxicity OTHER DATA:

4 Section 12: Ecological Information SDS Page 4 of 5 Chemical BIODEGRADATION: This substance is not biodegradable. BIOACCUMULATION:. ECO TOXICITY:. MOBILITY:. Note: No environmental hazards were identified based on a review of available data for the ingredients in this product. Not all of the ingredients have been tested for Ecotoxicity. Section 13: Disposal Considerations WASTE FROM RESIDUES / UNUSED PRODUCTS: Recommend waste material should be disposed of by using incineration. Follow the waste disposal requirements of your country, state, or local authorities. CONTAMINATED PACKAGING: Recommend contaminated packaging material should be disposed of by incineration as stated above for residues and unused product. RINSATE: Do not dispose of rinse water containing product in a sanitary sewer system, stormwater drainage system, or wastewater treatment system. Rinsate should be disposed of by incineration as stated above for residues and unused product. Section 14: Transport Information DOT TRANSPORT: ADR = International Carriage of Dangerous Goods by Road RAIL TRANSPORT: SEA TRANSPORT: AIR TRANSPORT: IATA/ICAO CLASS: Section 15: Regulatory Information TOXIC SUBSTANCES CONTROL ACT (TSCA) STATUS: This product is in compliance with rules, regulations, and orders of TSCA. All components are listed on the TSCA Inventory. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) TITLE III SECTION 313 SUPPLIER NOTIFICATION: This regulation requires submission of annual reports of toxic chemical(s) that appear in section 313 of the Emergency Planning and Community Right To Know Act of 1986 and 40 CFR 372. This information must be included in all MSDS s that are copied and distributed for the material. The toxic chemicals contained in this product are: CALIFORNIA PROPOSITION 65: This regulation requires a warning for California Proposition 65 chemical(s) under the statute. The California proposition 65 chemical(s) contained in this product are: STATE TOXIC SUBSTANCE OR HAZARDOUS SUBSTANCE LIST (State Right-to-Know): Florida Toxic Substance(s): Massachusetts hazardous substance: Pennsylvania hazardous substance: New Jersey Polyvinyl Chloride Illinois:

5 Section 16: Other Information SDS Page 5 of 5 Revision Comments: Updated from August 15, 2012 due to TSCA compliance status update. Revision Number: 0 Information Sources: RTECS, REACH, OSHA 29CFR FOR INDUSTRIAL USE ONLY THIS MATERIAL SAFETY DATA SHEET IS OFFERED SOLELY FOR YOUR INFORMATION, CONSIDERATION, AND INVESTIGATION. THE DATA DESCRIBED IN THIS MSDS CONSIST OF DATA ON LITERATURE, OUR ACQUISITIONAL DATA, AND ANALOGICAL INFERENCE BY DATA OF SIMILAR CHEMICAL SUBSTANCES OR PRODUCTS. SHIN-ETSU CHEMICAL CO. LTD. PROVIDES NO WARRANTIES, EITHER EXPRESSED OR IMPLIED, AND ASSUMES NO RESPONSIBILITY FOR THE ACCURACY OR COMPLETENESS OF THE DATA CONTAINED HEREIN. ADDITIONAL INFORMATION THIS DATA IS OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS MADE. THE RECOMMENDED HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE.