PACT CARBON CAPTURE PLANT

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1 PACT OPENING Advanced Manufacturing Park, Sheffield 20/06/2014 PACT CARBON CAPTURE PLANT Dr Kris Milkowski Dr Muhammad Akram

2 Overview Solvent based carbon capture plant for capture of CO 2 from combustion flue/process gases Operates in an integrated system with: 330kW Gas Turbine 250kWth PF (Coal/Biomass) rig Synthetic flue/process gas mixing facility

3 General Specification Comprises: 8m/300mm Absorber/Desorber Water wash column Integrated FGD (carbonate) Treats 210 Nm 3 /h of flue gas Removes 1 tonne of CO 2 per day (Coal flue gas with MEA) Equipped with: Gas analysis for monitoring flue gas inlet and outlets from absorber, desorber and water wash Solvent sampling on columns Material corrosion testing Trace gas injection capability

4 Example Applications Testing & development of alternative capture solvents. Benchmarking & energy requirements Solvent degradation & enhancement Assessment of plant and integrated system flexibility Fuel testing Integrated systems modelling and control Validation of baseline economics

5 Operating principles

6 Integrated facilities 250kW PF Rig

7 PF rig Carbon Capture Plant Example Applications Post Combustion Capture research from: Coal Biomass Co-firing Natural gas High oxygen firing Impact of trace gasses on solvent stability Integrated system modelling Integrated System Specification Portion (150kW eqiv.) of flue gas treated Flue gas filtered & cooled by 2 heat exchanger FGD package: DCC SOx reduction to ~10ppm

8 Gas Turbines - Carbon Capture Plant Example Applications Post combustion capture research for gas turbines Development of FGR technology Impact of transient operations Integrated system modelling Specification Portion of flue gas treated by Carbon Capture Plant FGD by-passed CO2 Concentration 1.5%; Flue gas modulation through CO 2 and/or N 2 injection

9 Gas Mixing Facility Specification Gas metering and mixing skid for O 2, CO 2 and N 2 fed from cryogenic storage tanks. Complemented by trace gas injection. Applications Synthetic flue/process gasses Modulation of flue gases from PACT facilities to mimic specific gas concentrations. Bespoke solutions for CO2 capture from power generation and industrial processes Evaluation of the impact and system flexibility for different process conditions/fuels Mechanistic solvent stability studies

10 History Plant donated from RWE npower (Didcot) Feb 2012 Installation commenced Mar 2012 Installation completed and commissioning commenced in Dec 2012 Experimental operation August 19 th 2013 PACT, April 2012 RWE npower Didcot 2008 PACT, August 2013

11 Operational stats Until end of March 2014 (~7months) completed over 1200 operating hours on the Carbon Capture Plant (combination of 24 and 8 hr operations) Longest continuous operation: 18 days Primarily industrial R&D Testing: MEA Novel commercial solvents

12 Sample Results

13 Initial testing MEA 35% 6 days continuous run Testing operation and capture performance Flue gas from Gas turbine, modulated with CO 2 injection to 4.5% % CO 2 Solvent flow rate kg/h

14 Solvent concentration variations Solvent concentration 35 changes against running 30 time No fresh solvent was 25 introduced 20 Solvent concentration 15 decreased slightly with 10 time 5 Both rich and lean are 0 similar Amine Concentration (%) Rich amine Lean amine Runining hours

15 Wash column performance Solvent concentration in the wash column as a function of time The concentration increases although fresh water is introduced Water consumption rate 6 l/h at 4.5% CO2, 12 l/h at 8% CO2 concentration in the flue gas Amine Concentration (%) Running hours Filled fresh water

16 CO2 loadings Rich and lean loadings against time CO2 Loadings (mol CO2/mol MEA) Rich Lean Running hours

17 Capture plant performance Captured CO2 fraction Captured CO2 fraction Energy input boiler (GJ/tonne CO2) L/Kg CO2

18 Plant development Following initial testing the plant has been significantly upgraded to expand and automate data recording : New temperature & pressure sensors across column and cross exchanger Heat flow measurements Enhanced gas flow measurments

19 Plant development Enhanced gas analysis: New CO 2 analyser Emissions monitoring: GASMET FTIR monitoring water wash inlet and outlet Liquid analysis by GCMS

20 Acquisition of Ferrybride Pilot CC100+ Equipment Online monitoring equipment: GASMET FTIR and 5-chanel heated sampling system Metrohm Applickon AD 12045TL Process analyzer Siemens ammonia analyser CO 2 and O 2 analyser Laboratory facilities Auto-titrator Ion chromatography Laboratory equipment Plant instrumentation Density meters, conductivity probes Pressure sensors and DPs Temp. sensors Flow meters ( liquid and gas),

21 Further development New absorber column packing in partnership with Sulzer New zero emissions wash column Structural plant modifications to extend operating capabilities and deliver better data for modelling Enhanced control system (flexibility)

22 Summary Integrated 1 tonne/ day carbon capture plant Variety of flue gases: GT, PF rig & Gas Mixing Facility Open access for industry and academia High level of utilisation Upgrades to enhance research capability and international standing

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