SAFETY DATA SHEET BIOCIDE BQ According to Regulation (EC) No 1907/2006, Annex II

Transcription

1 SAFETY DATA SHEET According to Regulation (EC) No 1907/2006, Annex II SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number BC-BQ 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Biocide 1.3. Details of the supplier of the safety data sheet Supplier Feedwater Limited Tarran Way Tarran Estate Moreton Wirral CH46 4TU Tel: Emergency telephone number National emergency telephone number National Chemical Emergency Centre (UK Only) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Environmental hazards Not Classified Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification (67/548/EEC or 1999/45/EC) N;R50/ Label elements Pictogram Signal word Hazard statements Warning H410 Very toxic to aquatic life with long lasting effects. 1/7

2 Precautionary statements Supplemental label information P273 Avoid release to the environment. P391 Collect spillage. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of water. P401 Store in accordance with national regulations. P501 Dispose of contents/container in accordance with national regulations. BPR001 Use biocides safely. Always read the label and product information before use. RCH002b For professional users only Other hazards Not applicable. SECTION 3: Composition/information on ingredients 3.2. Mixtures N,N-Dimethyl-2-hydroxypropylammonium chloride polymer 10-30% CAS number: M factor (Acute) = 10 M factor (Chronic) = 10 Classification Acute Tox. 4 - H302 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification (67/548/EEC or 1999/45/EC) Xn;R22. N;R50/53. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Move affected person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Never give anything by mouth to an unconscious person. Do not induce vomiting. Rinse mouth thoroughly with water. Get medical attention if any discomfort continues. Remove affected person from source of contamination. Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues. Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed None noted, however, the casualty should be transferred to hospital if any unusual adverse symptoms develop Indication of any immediate medical attention and special treatment needed Notes for the doctor No specific recommendations. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media The product is non-combustible. Use fire-extinguishing media suitable for the surrounding fire Special hazards arising from the substance or mixture 2/7

3 Specific hazards Hazardous combustion products No unusual fire or explosion hazards noted. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Oxides of carbon. Oxides of nitrogen Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters No specific firefighting precautions known. Wear chemical protective suit. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Environmental precautions Do not discharge into drains or watercourses or onto the ground. Observe all national regulations 6.3. Methods and material for containment and cleaning up Methods for cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush contaminated area with plenty of water. Avoid the spillage or runoff entering drains, sewers or watercourses Reference to other sections Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Good personal hygiene procedures should be implemented. For professional users only. Use biocides safely. Always read the label and product information before use Conditions for safe storage, including any incompatibilities Storage precautions Storage class Only store in correctly labelled containers. Store in a closed container. Keep containers upright. Use appropriate containment to avoid environmental contamination. Chemical storage Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. Usage description Use only with dosing equipment approved by supplier SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Ingredient comments No exposure limits known for ingredient(s) Exposure controls Protective equipment 3/7

4 Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Hygiene measures Respiratory protection Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupational exposure limits for the product or ingredients. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Chemical splash goggles or face shield. Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. Wear appropriate clothing to prevent any possibility of skin contact. Wash promptly if skin becomes contaminated. Promptly remove non-impervious clothing that becomes contaminated. When using do not eat, drink or smoke. No specific recommendations. Respiratory protection may be required if excessive airborne contamination occurs. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Colour Odour Colourless. Mild. ph ph (concentrated solution): 7 Flash point >100 C Vapour pressure 2.5x10^-4 C Relative density C 9.2. Other information Other information None. SECTION 10: Stability and reactivity Reactivity Reactivity There are no known reactivity hazards associated with this product Chemical stability Possibility of hazardous reactions Possibility of hazardous reactions Conditions to avoid Not known. Not relevant. Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials to avoid Strong alkalis. Strong oxidising agents. Strong acids. Anionic polymers and detergents Hazardous decomposition products Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Oxides of carbon. Oxides of nitrogen. SECTION 11: Toxicological information Information on toxicological effects 4/7

5 Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg) Species Skin corrosion/irritation Extreme ph Skin sensitisation Skin sensitisation 10,000.0 Rat Not irritating. - : Not sensitising. This product has low toxicity. Only large quantities are likely to have adverse effects on human health. SECTION 12: Ecological Information Toxicity Acute toxicity - fish Acute toxicity - aquatic invertebrates Acute toxicity - aquatic plants Acute toxicity - terrestrial LC₅₀, 96 hours: 0.51 mg/l, Fish EC₅₀, 48 hours: 0.56 mg/l, Daphnia magna IC₅₀, 72 hours: 0.60 mg/l, Algae, >: > 6000 mg/kg, Eisenia Fetida (Earthworm) Persistence and degradability Persistence and degradability The product is not expected to be biodegradable Bioaccumulative potential Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating Mobility in soil Mobility The product is soluble in water. The product contains substances which are bound to particulate matter and are retained in soil Results of PBT and vpvb assessment Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria Other adverse effects Other adverse effects Not known. SECTION 13: Disposal considerations Waste treatment methods Disposal methods Contact a licensed waste disposal company. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. SECTION 14: Transport information UN number UN No. (ADR/RID) /7

6 UN No. (IMDG) 3082 UN No. (ICAO) 3082 UN No. (ADN) UN proper shipping name Proper shipping name (ADR/RID) Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains N,N- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains N,N- Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains N,N- Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains N,N Transport hazard class(es) ADR/RID class 9 ADR/RID classification code M6 ADR/RID label 9 IMDG class 9 ICAO class/division 9 ADN class 9 Transport labels Packing group ADR/RID packing group IMDG packing group ADN packing group ICAO packing group Environmental hazards Environmentally hazardous substance/marine pollutant Special precautions for user EmS F-A, S-F ADR transport category 3 Emergency Action Code Hazard Identification Number (ADR/RID) 3Z 90 6/7

7 Tunnel restriction code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Guidance Workplace Exposure Limits EH Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Key literature references and sources for data Only trained personnel should use this material. Further details may be available from the supplier. REACH registered substances database Other safety data sheets relevant to individual chemical constituents within this product. Revision date 01/06/2015 Revision 7 Supersedes date 01/11/2012 SDS status Risk phrases in full Hazard statements in full Approved. R22 Harmful if swallowed. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 7/7