MATERIAL SAFETY DATA SHEET ALLANTOIN Page 1

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1 ALLANTOIN Page 1 WHMIS controlled: Section 01 - Product Information Identification of the company: Clariant (Canada) Inc Cousens St-Laurent, Quebec H4S 1X3, Information of the substance/preparation: ESHA Phone (514) , Fax (514) Emergency tel. number: +1 CANUTEC (613) Trade name: ALLANTOIN CAS number: Chemical family: 5-Ureido-Hydantoin Primary product use: Raw material for cosmetics Section 02 - Composition information on hazardous ingredients Hazardous ingredients: The product does t contain hazardous components. Section 03 - Hazards identification Health effects of exposure: Any available toxicological data is shown in Section 11. No other information was found in the public literature for any effects of exposure and health evaluation is thus possible. Therefore, handle with care and avoid unnecessary exposures. Listed carcigen: IARC: No NTP: No OSHA: No Other: No Section 04 - First aid measures After inhalation: Get victim to fresh air. Loosen tight clothing such as collar, tie, belt or waistband. If breathing is difficult administer oxygen. If victim is t breathing, give mouth to mouth resuscitation. Get prompt medical attention. Warning: giving mouth to mouth resuscitation when the inhaled material is toxic may be hazardous to the person providing aid. After contact with skin: Remove contaminated clothing and wash affected areas with soap and plenty of water for at least 15 minutes. If redness or skin irritation occurs, seek medical attention.

2 ALLANTOIN Page 2 After contact with eyes: Immediately wash the eyes with flowing water for at least 15 minutes. Insure proper irrigation by occasionally lifting upper and lower eyelids. Thereafter seek prompt medical attention. After ingestion: If ingested, do t induce vomiting. Get immediate medical assistance. Advice to doctor / Treatment: None kwn. Section 05 - Fire fighting measures Flashpoint: Self ignition: Extinguishing media: Not applicable No self-ignition below the decomposition temperature. foam water mist Special fire fighting procedure: Wear self-contained breathing apparatus (SCBA) and full protective clothing. Unusual fire and explosion hazards: Emits toxic fumes under fire conditions. This product presents unusual fire or explosion hazards while sealed in a shipping container. During usage, if a dust cloud is generated, organic powders have the potential to be explosive with static spark or flame initiation. Section 06 - Accidental release measures Steps to be taken in case of spill or leak: Wear prescribed protective equipment. Sweep up or shovel into disposal containers using n-sparking tools. Eliminate ignition sources. Wet down with n-reactive liquid if required to limit dusting. If melted, allow to solidify first. Clean up spill location. Must t be released into sewers, drains or wells. Section 07 - Handling and storage Advice on safe handling: Avoid dust formation. Use only in well ventilated areas. Further info on storage conditions: Keep container tightly closed and dry Section 08 - Exposure controls / personal protection Occupational exposure limits: Component Particles (insoluble or poorly soluble) CAS number: Regulatory list Type of value Value 1 Value 2 US ACGIH Value_Time 10 mg/m3

3 ALLANTOIN Page 3 Particles (insoluble or poorly soluble) Values US ACGIH Values Weighted Average Value_Time Weighted Average 3 mg/m3 Respiratory protection: Hand protection: Eye protection: Other protective equipment: Wear an approved dust respirator when handling product. Rubber or Plastic Wear safety glasses with side-shields. Wear clothing suitable to avoid skin contact. Section 09 - Physical and chemical properties Form: Powder Color: white Odor: odourless ph: (5 g/l) Miscibility with water: approx. (20 C) Miscibility with water: approx. (75 C) Melting temperature : C Bulk density: approx. 600 kg/m3 Section 10 - Stability and reactivity Thermal decomposition: > 225 C Chemical stability: Hazardous Polymerization: Stable. Will t occur. Conditions to avoid: None kwn. Section 11 - Toxicological information Acute oral toxicity: Eye irritation: LD50 > 5,000 mg/kg (rat) Method: EEC 84/449, B.1 n-irritant (rabbit eye) Source: CIT Section 12 - Ecological information Biodegradation: > 80 % Method: OECD 302 B

4 ALLANTOIN Page 4 Fish toxicity: Bacteria toxicity: Chemical oxygen demand (COD): Biological oxygen demand (BOD): LC50 > 5,000 mg/l (Brachydanio rerio) Method: OECD 203 EC0 > 10 g/l (Pseudomonas putida) Source: IRCHA 240 mg/g 63.8 mg/g Section 13 - Disposal considerations Waste disposal information: Dispose in accordance with local regulations at a government approved incinerator or waste management site. Section 14 - Transport information TDG t restricted IATA t restricted IMDG t restricted Section 15 - Regulatory information Registration status DSL: NDSL: CEPA Listed as priority substance: Listed as toxic substance: yes TSCA Status: All components of this product are listed on the TSCA Inventory. FDA: This product is t registered with the FDA. Section 16 - Other information The information contained on this MSDS is to the best of our kwledge an accurate summary of the data available as of the date of preparation. Clariant (Canada) Inc. is t liable for the application or use of this information in situations beyond its control or outside the rmal and expected use of its product. Clariant (Canada) Inc. assumes

5 ALLANTOIN Page 5 responsibility for damage or injury from the use of the product described herein.

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