SAFETY DATA SHEET 1. IDENTIFICATION OF SUBSTANCE/ MIXTURE AND THE COMPANY/ UNDERTAKING

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1 SAFETY DATA SHEET 1. IDENTIFICATION OF SUBSTANCE/ MIXTURE AND THE COMPANY/ UNDERTAKING PRODUCT: Dionex Six Cation-I Standard Dionex Six Cation-II Standard Dionex Six Cation Retention Time Standard Dionex Six Cation Retention Time Standard (100x) Thermo Fisher Scientific Emergency Phone: (CHEMTREC) (INTERNATIONAL) Information Phone: Sunnyvale, California Date Revised: 6/7/2016 For laboratory use. 2. HAZARD(S) IDENTIFICATION Classification of the Substance or Mixture: Signal Word: Danger Hazard Statements: H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. Precautionary Statements: All Classifications meet the CLP/GHS requirements. P280 Wear protective gloves/protective clothing/eye protection/face protection. P260 Do not breathe dust/fume/gas/mist/vapour/spray P234 Keep only in original packaging/container P264 Wash thoroughly after handling P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P353+P361+P363 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/. P390 Absorb spillage to prevent material-damage. P405 Store locked up. P406 Store in a corrosion resistant container with a resistant inner liner. P501 Dispose of contents/container in accordance with local regulations. SDS , Rev. 18 Page 1 of 7

2 CLP/GHS CLASSIFICATION (1272/2008): SKIN CORROSIVE: (Category 1B) METAL CORROSIVE: (Category 1) EYE DAMAGE/IRRITATION (Category 1) GHS Label Elements: Corrosive 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Water Hydrochloric Acid Sodium Lithium Ammonium Potassium Magnesium Calcium PERCENT (%) < 0.01 < 0.1 < 0.1 < 0.1 < CAS NO EINECS NO CLASSIFICATI ON Met. Corr. 1; Skin Corr. 1B; Eye Dam. 1; STOT SE 3; H290, H314, H335 Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2A; STOT SE 3; Aquatic Acute 3; H302, H315, H319, H335, H402 See section 16 for full H-statements and abbreviations 4. FIRST AID MEASURES GENERAL: EYES: SKIN: INHALATION: INGESTION: Acute Tox. 4; Eye Irrit. 2A; Aquatic Acute 2; Aquatic Chronic 2; H302, H319, H411 Remove contaminated clothing, wash thoroughly before reuse. Flush with water for at least 15 minutes occasionally raising upper and lower eyelids. Remove contact lenses. Seek medical attention if necessary. Remove contaminated clothing and wash skin with soap and water thoroughly. Seek medical attention if necessary. Move to fresh air. If not breathing, give artificial respiration. Seek medical attention if symptoms persist. Eye Irrit. 2A; H319 If large amounts are swallowed, get medical help immediately. If patient is conscious, give large quantities of water. DO NOT INDUCE VOMITING! Seek medical attention if necessary. 5. FIRE FIGHTING MEASURES Hazardous Combustion Products: Extinguishing Media: Special Protective Actions For Fire Fighters: SDS , Rev. 18 Page 2 of 7

3 6. ACCIDENTAL RELEASE MEASURES Ventilate area and wear respiratory protective equipment if necessary. Wear appropriate personal protective equipment. Avoid breathing vapours, mist or gas. Evacuate personnel to a safe area. Do not let product enter drains. Contain spill and neutralize. Collect or absorb with an inert material (vermiculite, dry sand, earth, etc.) Mop up and store in a suitable waste container. Wash contaminated areas with soap and water. 7. HANDLING AND STORAGE Ensure good ventilation. Avoid breathing vapours, mist or gas. Avoid skin or eye contact. Do not ingest. Wear appropriate personal protective equipment when handling (see Section 8). Have an eye wash/shower in the immediate area in case of emergency. Store at room temperature. Keep container tightly closed and upright. Use good laboratory practice when working with any chemical whether it is considered hazardous or not. Wash hands after use. 8. EXPOSURE CONTROL/PERSONAL PROTECTION Routes of Entry: Health Hazards: Ventilation: Protective Clothing Or Equipment: INHALATION: SKIN: INGESTION: ACUTE: CHRONIC: LOCAL EXHAUST: MECHANICAL (GENERAL): SPECIAL: OTHER: GLOVES: EYE PROTECTION: No Yes Yes May cause burns to skin, eyes and mucous membranes. Good laboratory ventilation is acceptable. Use in fume hood if possible Chemical resistant gloves Face shield, safety glasses or goggles SDS , Rev. 18 Page 3 of 7

4 RESPIRATORY: OTHER: Lab coats 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear ODOR: None ph: 1 MOLECULAR WEIGHT: MELTING POINT: BOILING POINT: Approximately 100 degrees C AUTOIGNITION TEMPERATURE: FLASH POINT: Not combustible LOWER EXPLOSION LIMIT: UPPER EXPLOSION LIMIT: SPECIFIC GRAVITY: Approximately 1 SOLUBILITY: FREEZING POINT: EVAPORATION RATE: FLAMMABILITY: Not combustible VAPOR PRESSURE: VAPOR DENSITY: DECOMPOSITION TEMPERATURE: VISCOSITY: SOLUBILITIES: PARTITION COEFFICIENT: 10. STABILITY & REACTIVITY STABILITY/CONDITIONS TO AVOID: INCOMPATIBILITY (MATERIALS TO AVOID): HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: HAZARDOUS POLYMERIZATION: Stable Strong bases Hydrogen chloride Will not occur 11. TOXICOLOGY INFORMATION PRODUCT TOXICOLOGY INFORMATION: Acute toxicity: Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitization: Germ cell mutagenicity:.... SDS , Rev. 18 Page 4 of 7

5 Carcinogenicity: Reproductive toxicity: STOT-single exposure: STOT-repeated exposure: Aspiration hazard: Likely routes of exposure: OSHA PEL: NTP: IARC Monographs: ACGIH TLV TWA: Ingestion, skin HAZARDOUS COMPONENT TOXICOLOGY INFORMATION: HAZARDOUS COMPONENTS: Hydrochloric Acid Lithium Calcium Ammonium RTECS #: MW OJ EV BP OSHA PEL: C 5 PPM 5 MG/M3 (CN) 10 MG/M3 FUME ACGIH TLV: C 2 PPM S, 5 MG/M3 (CN) 10 MG/M3 FUME TOXICITY DATA: UNK-MAN LDLo: 81 MG/KG IHL-HMN LCLo: 1300 PPM/30M 12. ECOLOGICAL INFORMATION ORL-HMN LDLo: 200 MG/KG/3D IPR-MUS LD50: 604 MG/KG on environmental toxicity for this solution. 13. DISPOSAL CONSIDERATIONS ORL-RAT LD50: 1000 MG/KG IPR-DOG LDLo: 110 MG/KG Dispose of product and packaging according to local, state and federal regulations. 14. TRANSPORT INFORMATION USDOT CLASSIFICATION: IATA CLASSIFICATION: PROPER SHIPPING NAME: CLASS OR DIVISION 8 HAZARD LABEL(S) PACKAGING GROUP Hydrochloric acid Corrosive III PROPER SHIPPING NAME: CLASS OR DIVISION: 8 HAZARD LABEL(S): PACKAGING GROUP: Hydrochloric acid Corrosive III ORL-DOG LDLo: 600 MG/KG IPR-MUS LD50: 485 MG/KG SDS , Rev. 18 Page 5 of 7

6 IMO/IMDG CLASSIFICATION: PROPER SHIPPING NAME: Hydrochloric acid CLASS OR DIVISION: 8 HAZARD LABEL(S): Corrosive PACKAGING GROUP: III ADR CLASSIFICATION: PROPER SHIPPING NAME: Hydrochloric acid CLASS OR DIVISION: 8 HAZARD LABEL(S): Corrosive PACKAGING GROUP: III Not a marine pollutant. 15. REGULATORY INFORMATION This product has been classified according to the hazard criteria of the CPR and the SDS contains information required by the CPR. This product does not contain any chemical components that are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components: The following chemicals are subject to reporting levels established by SARA Title III, section 313: Hydrochloric Acid, , revision date SARA 311/312 Hazards: Acute, Chronic Massachusetts Right to Know Components: Hydrochloric Acid, , revision date ; Ammonium, , revision date Pennsylvania Right to Know Components: Hydrochloric Acid, , revision date ; Lithium, ; Ammonium, , revision date ; Calcium, ; Water, New Jersey Right to Know Components: Hydrochloric Acid, , revision date ; Lithium, ; Ammonium, , revision date ; Calcium, ; Water, California Prop 65: This mixture does not contain any chemicals known to the State of California to cause cancer, birth defects or any other reproductive harm 16. OTHER INFORMATION Full H-statements: H290 May be corrosive to metals H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H402 Harmful to aquatic life H411 Toxic to aquatic life with long lasting effects SDS , Rev. 18 Page 6 of 7

7 Abbreviations: Acute Tox. Acute toxicity Aquatic Acute Acute aquatic toxicity Aquatic Chronic Chronic aquatic toxicity CLP Classification, Labelling and Packaging Eye Dam. Serious Eye Damage Eye Irrit. Eye irritation GHS Globally Harmonized System Met. Corr. Corrosive to Metals OSHA Occupational Safety & Health Administration PEL Permissible Exposure Limit Skin Corr. Skin corrosion Skin Irrit. Skin irritation STOT SE Specific target organ toxicity single exposure This Safety Data Sheet has been prepared in accordance with the Globally Harmonized System for the Classification and Labeling of Chemicals (GHS). It complies with the requirements of the Canadian Controlled Products Regulations and US 29CFR To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries makes any warranty of Merchantability or any other warranty, expressed or implied, which respect to such information, and we assume no liability resulting from its use. In no event shall Thermo Fisher Scientific be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages resulting from use of or reliance upon this information. SDS , Rev. 18 Page 7 of 7

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