Safety Data Sheet Revision Date: 11/22/16

Transcription

1 1. IDENTIFICATION Safety Data Sheet Revision Date: 11/22/16 Catalog Number / Product Name: / DHA PONA Standard Company: Address: Restek Corporation 110 Benner Circle Bellefonte, Pa Phone#: Fax#: Emergency#: (CHEMTREC) (Outside the US) Revision Number: 3 Intended use: For Laboratory use only 2. HAZARD(S)IDENTIFICATION Emergency Overview: GHS Hazard Symbols: GHS Classification: GHS Signal Word: GHS Hazard: GHS Precautions: Safety Precautions: Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Specific Target Organ Systemic Toxicity (STOT) - Repeated Exposure Category 1 Flammable Liquid Category 2 Skin Corrosion/Irritation Category 2 Hazardous to the aquatic environment - Acute Category 2 Hazardous to the aquatic environment - Chronic Category 2 Acute Toxicity - Oral Category 4 Danger Highly flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. May cause genetic defects.. May cause cancer. Causes damage to organs through prolonged or repeated exposure. Toxic to aquatic life.. Toxic to aquatic life with long lasting effects. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilation and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands and skin thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection / DHA PONA Standard Page 1 of 18

2 First Aid Measures: Storage: Disposal: Single Exposure Target Organs: Repeated Exposure Target Organs: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Specific treatment see section 4. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use extinguishing media in section 5 for extinction. Collect spillage. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container according to section 13 of the SDS. 3. COMPOSITION / INFORMATION ON INGREDIENT Chemical Name CAS # EINEC # % Composition Ethanol n-pentane hexane methylpentane methylpentane isopentane Toluene Heptane Butane Methylcyclohexane methylhexane Benzene methylheptane methyloctane Ethylbenzene Cyclohexane n-octane methylhexane ,4-dimethylpentane tert-amyl methyl ether (TAME) methylheptane Methylcyclopentane ,5-dimethylhexane ,3-dimethylpentane nonane Methylnonane octene ,3-dimethylbutane / DHA PONA Standard Page 2 of 18

3 1-hexene n-decane methanol n-pentadecane n-tetradecane n-dodecane tridecane N-Undecane tert-butanol (2-methyl-2- propanol) phenylhexane ,2,3-trimethylpentane ,5-Dimethylheptane pentene m-xylene Isobutane isopropyltoluene (p-cumene) ,2-dimethylpentane nonene cis-1,2-dimethyl cyclohexane ethylcyclopentane heptene o-xylene tert-Butyl-3,4,5- trimethylbenzene cyclopentane ,3-dimethylpentane isobutylbenzene Propylbenzene sec-butylbenzene ethyl-3-methylbenzene MTBE methyl-2-isopropylbenzene ,5-Dimethylheptane trans-1,2- Dimethylcyclopentane Octane, 2,2-dimethyl Methylheptane cis-4-nonene ,3-Diethylpentane Trimethyl cyclohexane, 1,1,4- & other isomers Ethylpentane ,2,4-trimethylbenzene ,2-Dimethyl-3-ethylbenzene Methyl-2-propylbenzene, methyl-4-ethylbenzene ,3-Dimethylheptane Isopropylbenzene Methyl-3-propylbenzene, ,3,5-triethylbenzene / DHA PONA Standard Page 3 of 18

4 butylbenzene tert-1-butyl-2-methylbenzene Benzene, 1,4-dimethyl-2-ethyl p-tert-butylethylbenzene Methyl-4-propylbenzene tert-butylbenzene pentylbenzene trans-1,4-dimethylcyclohexane trans-1,3- Dimethylcyclopentane / DHA PONA Standard Page 4 of trans-3-heptene Methylnonane isoprene methyloctane trans-2-octene methyl-2-pentene methyl-1-nonene Methyl-1-pentene ,4-dimethylhexane ethyl-2-methylbenzene cis-3-nonene cis-2-hexene Propane N-Propylcyclopentane p-xylene trans-2-pentene ,3-dimethylheptane ,2-dimethylbutane Ethyloctane Isobutylcyclohexane ctc-1,2,3-trimethylcyclohexane t-1-methyl-2-npropylcyclohexane t-1-methyl-2(4- Methylphenyl)cyclopentane trans-3-nonene cis-2-octene trans-2-nonene decene methyl-1-butene m-cymene cyclopentane ,2,4-triethylbenzene ,4-Dimethylheptane ,2,4-Trimethylcyclohexane Octane, 3,3-dimethyl ,2,3-trimethylbutane ,2-dimethylhexane Benzene, 1,2-dimethyl-4-ethyl trans-1,2-dimethyl cyclohexane ,2,4,5-tetramethylbenzene

5 trans-2-hexene ,3-Dimethyl-2-ethylbenzene methyl-1-butene ,3,5-Trimethylcyclohexane Ethylhexane ,1-2-Trimethylcyclohexane FIRST-AID MEASURES Inhalation: Eyes: Skin Contact: Ingestion: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately Get medical attention immediately. Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention. Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. No data. Induce vomiting as a last measure. Induced vomiting may lead to aspiration of the material into the lungs potentially causing chemical pneumonitis that may be fatal. 5. FIRE- FIGHTING MEASURES Extinguishing Media: Fire and/or Explosion Hazards: Fire Fighting Methods and Protection: Hazardous Combustion Products: 6. ACCIDENTAL RELEASE MEASURES Personal Precautions and Equipment: Methods for Clean-up: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire. Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back Empty containers that retain product residue (liquid, solid/sludge, or vapor) can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury or death. Container may explode in heat of fire. Do not enter fire area without proper protection including self-contained toxic breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Use water spray/fog for cooling. Carbon dioxide, Carbon monoxide Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. 7. HANDLING AND STORAGE Handling Technical Measures and Precautions: Storage Technical Measures and Conditions: Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Ground and bond containers when transferring material Keep in air-tight containers- material is hygroscopic. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. Store in a cool dry ventilated location. Isolate from / DHA PONA Standard Page 5 of 18

6 8. EXPOSURE CONTROLS / PERSONAL PROTECTION incompatible materials and conditions. Keep container(s) closed. Keep away from heat, sparks, and flame Do not store near combustible materials United States: Chemical Name CAS No. IDLH ACGIH STEL ACGIH TLV-TWA OSHA Exposure Limit Ethanol ppm IDLH n-pentane ppm IDLH (10% LEL) hexane ppm IDLH (10% LEL) 1000 ppm STEL 2-methylpentane ND 1000 ppm under Hexane isomers other than n- hexane) 3-methylpentane ND 1000 ppm under Hexane isomers other than n- hexane) 1000 ppm TWA; ppm TWA (listed under Pentane, all 1000 ppm TWA; ppm TWA; ppm 50 ppm TWA 500 ppm TWA; ppm TWA (listed under Hexane isomers other than n-hexane) 500 ppm TWA (listed under Hexane isomers other than n-hexane) isopentane ND 600 ppm TWA (listed under Pentane, all Toluene ppm IDLH Heptane ppm IDLH 500 ppm under Heptane, all Butane ND 1000 ppm STEL Methylcyclohexane ppm IDLH (10% LEL) 2-methylhexane ND 500 ppm under Heptane, all Benzene ppm IDLH 2.5 ppm STEL 2.5 ppm STEL; 8 mg/m3 STEL 20 ppm TWA 50 ppm TWA; ppm TWA (listed under Heptane, all 400 ppm TWA; ppm TWA; ppm TWA 400 ppm TWA; ppm TWA (listed under Heptane, all 0.5 ppm TWA 0.5 ppm TWA; ppm TWA; C 300 ppm 500 ppm TWA; 2000 No PEL established 500 ppm TWA; ppm TWA (apply only to exempt industry segments) 3-methylheptane ND No TLV 3-methyloctane ND No TLV Ethylbenzene ppm IDLH 20 ppm TWA 100 ppm TWA; ppm TWA; 435 Cyclohexane ppm IDLH n-octane ppm IDLH (10% LEL) 125 ppm STEL; 543 mg/m3 STEL (375) ppm STEL; (1750) mg/m3 STEL 3-methylhexane ND 500 ppm under 100 ppm TWA (300) ppm TWA; ppm TWA 300 ppm TWA; ppm TWA (listed under Heptane, all 300 ppm TWA; ppm TWA; / DHA PONA Standard Page 6 of 18

7 Heptane, all 2,4-dimethylpentane ND 500 ppm under Heptane, all tert-amyl methyl 400 ppm TWA (listed under Heptane, all ND 20 ppm TWA ether (TAME) 2-methylheptane ND No TLV Methylcyclopentane ND No TLV 2,5-dimethylhexane ND No TLV 2,3-dimethylpentane ND 500 ppm under Heptane, all 400 ppm TWA (listed under Heptane, all nonane ND 200 ppm TWA 3-Methylnonane ND No TLV 1-octene ND No TLV 2,3-dimethylbutane ND 1000 ppm under Hexane isomers other than n- hexane) 500 ppm TWA (listed under Hexane isomers other than n-hexane) 1-hexene ND 50 ppm TWA n-decane ND No TLV methanol ND 250 ppm STEL 200 ppm TWA 200 ppm TWA; 260 n-pentadecane ND No TLV n-tetradecane ND No TLV n-dodecane ND No TLV tridecane ND No TLV N-Undecane ND No TLV tert-butanol (2- methyl-2-propanol) ND 100 ppm TWA 100 ppm TWA; phenylhexane ND No TLV 2,2,3- trimethylpentane ND No TLV 2,5-Dimethylheptane ND No TLV 1-pentene ND No TLV m-xylene ND 150 ppm 100 ppm TWA STEL Isobutane ND 1000 ppm No TLV STEL 4-isopropyltoluene ND No TLV (p-cumene) 2,2-dimethylpentane ND 500 ppm under Heptane, all 400 ppm TWA (listed under Heptane, all 1-nonene ND No TLV cis-1,2-dimethyl ND No TLV cyclohexane ethylcyclopentane ND No TLV 1-heptene ND No TLV o-xylene ND 150 ppm 100 ppm TWA STEL 1-tert-Butyl-3,4, ND No TLV trimethylbenzene cyclopentane ND 600 ppm TWA 3,3-dimethylpentane ND No TLV isobutylbenzene ND No TLV Propylbenzene ND No TLV sec-butylbenzene ND No TLV / DHA PONA Standard Page 7 of 18

8 1-ethyl ND No TLV methylbenzene MTBE ND 50 ppm TWA 1-methyl-2- isopropylbenzene ND No TLV 3,5-Dimethylheptane ND No TLV trans-1,2- Dimethylcyclopentan e ND No TLV Octane, 2,2-dimethyl ND No TLV 4-Methylheptane ND No TLV cis-4-nonene ND No TLV 3,3-Diethylpentane ND No TLV Trimethyl ND No TLV cyclohexane, 1,1,4- & other isomers 3-Ethylpentane ND No TLV 1,2, ND No TLV trimethylbenzene 1,2-Dimethyl ND No TLV ethylbenzene Methyl ND No TLV propylbenzene, 1-1-methyl-4- ethylbenzene ND No TLV 3,3-Dimethylheptane ND No TLV Isopropylbenzene ND 50 ppm TWA 50 ppm TWA; 245 Methyl-3- propylbenzene, ND No TLV 1,3,5-triethylbenzene ND No TLV butylbenzene ND No TLV tert-1-butyl-2- ND No TLV methylbenzene Benzene, 1, ND No TLV dimethyl-2-ethylp-tert ND No TLV Butylethylbenzene 1-Methyl ND No TLV propylbenzene tert-butylbenzene ND No TLV pentylbenzene ND No TLV trans-1,4- ND No TLV Dimethylcyclohexane trans-1,3- ND No TLV Dimethylcyclopentan e trans-3-heptene ND No TLV 2-Methylnonane ND No TLV isoprene ND No TLV 2-methyloctane ND No TLV trans-2-octene ND No TLV 2-methyl-2-pentene ND No TLV 2-methyl-1-nonene ND No TLV 4-Methyl-1-pentene ND No TLV 2,4-dimethylhexane ND No TLV 1-ethyl ND No TLV methylbenzene cis-3-nonene ND No TLV t-1-methyl-2-npropylcyclohexane ND No TLV cis-2-hexene ND No TLV Propane ND See Appendix F: Minimal Oxygen Content simple asphyxiant; 2500 ppm TWA 1000 ppm TWA; / DHA PONA Standard Page 8 of 18

9 N ND No TLV Propylcyclopentane p-xylene ND 150 ppm 100 ppm TWA STEL trans-2-pentene ND No TLV 2,3-dimethylheptane ND No TLV 2,2-dimethylbutane ND 1000 ppm 500 ppm TWA (listed under Hexane isomers other than n- hexane) under Hexane isomers other than n-hexane) 3-Ethyloctane ND No TLV Isobutylcyclohexane ND No TLV ctc-1,2,3- ND No TLV Trimethylcyclohexan e t-1-methyl-2(4- ND No TLV Methylphenyl)cyclop entane trans-3-nonene ND No TLV cis-2-octene ND No TLV trans-2-nonene ND No TLV 1-decene ND No TLV 2-methyl-1-butene ND No TLV m-cymene ND No TLV 1-2-cyclopentane ND No TLV 1,2,4-triethylbenzene ND No TLV 3,4-Dimethylheptane ND No TLV 1,2,4- Trimethylcyclohexan e ND No TLV Octane, 3,3-dimethyl ND No TLV 2,2,3-trimethylbutane ND No TLV 2,2-dimethylhexane ND No TLV Benzene, 1, ND No TLV dimethyl-4-ethyltrans-1,2-dimethyl ND No TLV cyclohexane 1,2,4, ND No TLV tetramethylbenzene trans-2-hexene ND No TLV 1,3-Dimethyl-2- ND No TLV ethylbenzene 3-methyl-1-butene ND No TLV 1,3, ND No TLV Trimethylcyclohexan e 3-Ethylhexane ND No TLV 1,1-2- Trimethylcyclohexan e ND No TLV Personal Protection: Engineering Measures: Respiratory Protection: Eye Protection: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure. Engineering controls must be designed to meet the OSHA chemical specific standard in 29 CFR Facilities storing or using this material should be equipped with an eyewash and safety shower. Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate symptoms.follow a respiratory protection program that meets 29 CFR and ANSI Z88.2 requirements whenever work place conditions warrant the use of a respirator. Wear chemically resistant safety glasses with side shields when handling this product. Do not wear contact lenses / DHA PONA Standard Page 9 of 18

10 Skin Protection: Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance, color: Odor: None Physical State: ph: Vapor Pressure: Boiling Point: Flash Point: -76 Flammability: Extremely Flammable Upper Flammable/Explosive Limit, % in air: Lower Flammable/Explosive Limit, % in air: Autoignition Temperature: deg C Decomposition Temperature: Evaporation Rate: 2.24 Odor Threshold: ND Solubility: Complete; 100% Partition Coefficient: n-octanol in water: -0.3 VOC % by weight: 2.71 Molecular Weight: 10. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Materials to Avoid / Chemical Incompatiability: Hazardous Decomposition Products: Stable under normal conditions. Temperatures above flash point in combination with sparks, open flames, or other sources of ignition.contamination High temperatures Strong oxidizing agents Oxidizing materials Carbon dioxide Carbon monoxide 11. TOXICOLOGICAL INFORMATION Routes of Entry: Inhalation, Skin Contact, Eye Contact, Ingestion Target Organs Potentially Affected By Exposure: Eyes, Respiratory Tract, Central nervous system stimulation, Liver, Skin, Blood, Reproductive System, Peripheral Nervous System, Bone Marrow (leukemia) Chemical Interactions That Change Toxicity: None Known Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. Skin Contact: Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Eye Contact: Can cause moderate irritation, tearing and reddening, but not likely to permanently injure eye tissue. Ingestion Irritation: May be harmful if swallowed. Long-Term (Chronic) Health Effects: Carcinogenicity: Reproductive and Developmental Toxicity: Inhalation: Skin Contact: Skin Absorption: Contains a probable or known human carcinogen. Contains a known human reproductive and/or developmental hazard. Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.toxic! Can cause systemic damage upon prolonged and/or repeated exposure (see "Target Organs). Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Upon prolonged or repeated exposure, toxic if absorbed through the skin. Likely to cause systemic damage / DHA PONA Standard Page 10 of 18

11 Component Toxicological Data: NIOSH: Chemical Name CAS No. LD50/LC50 Ethyl alcohol Inhalation LC50 Rat : ppm/10h; Inhalation LC50 Mouse : 39 gm/m3/4h; Oral LD50 Rat : 7060 mg/kg; Oral LD50 Mouse : 3450 mg/kg Pentane Oral LD50 Rat >2000 mg/kg; Dermal LD50 Rabbit 3000 mg/kg; Inhalation LC50 Rat 364 g/m3 4 h n-hexane Oral LD50 Rat 25 g/kg Toluene Inhalation LC50 Rat : 49 gm/m3/4h; Inhalation LC50 Mouse : 400 ppm/24h; Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : ul/kg Heptane Dermal LD50 Rabbit 3000 mg/kg Butane Inhalation LC50 Rat : 658 gm/m3/4h; Inhalation LC50 Mouse : 680 gm/m3/2h Methylcyclohexane Cyclohexane, methyl Inhalation LC50 Mouse : mg/m3/2h; Oral LD50 Mouse : 2250 mg/kg Benzene Dermal LD50 Rabbit >8200 mg/kg Benzene, ethyl Oral LD50 Rat : 3500 mg/kg; Dermal LD50 Rabbit : ul/kg Cyclohexane Oral LD50 Rat : mg/kg; Oral LD50 Mouse : 813 mg/kg n-octane Inhalation LC50 Rat : 118 gm/m3/4h Octane Butane, 2-methoxy-2-methyl Inhalation LC50 Rat >5400 mg/m3 4 h (no deaths occurred, vapor, whole body); Oral LD50 Rat 1602 mg/kg Nonane Inhalation LC50 Rat 3200 ppm 4 h (Source: IUCLID) Isoprene Dermal LD50 Rat >1 ml/kg Component Carcinogenic Data: OSHA: Chemical Name CAS No. Ethanol Present Benzene Monograph 29, Supplement 7; 1987; {IARC - Group 1 (carcinogenic to humans)}; Known Carcinogen; {NTP Eighth Report - Known Carcinogens}; 1 ppm TWA; 5 ppm STEL; 0.5 ppm TWA action limit; Cancer hazard; Flammable (see 29 CFR ); {OSHA - 29 CFR 1910 Specifically Regulated Chemicals} Ethylbenzene Present Isoprene Present ACGIH: Chemical Name CAS No. Ethanol A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans A4 - Not Classifiable as a Human Carcinogen Toluene A4 - Not Classifiable as a Human Carcinogen Benzene A1 - Confirmed Human Carcinogen A1-confirmed human carcinogen Ethyl benzene A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH: Chemical Name CAS No. Benzene potential occupational carcinogen NTP: Chemical Name CAS No. Benzene Known Carcinogen IARC: / DHA PONA Standard Page 11 of 18

12 Chemical Name CAS No. Group No. Ethanol Group 1 Monograph 29, Supplement 7; Group No data. Group 2A Ethylbenzene Group 2B Isoprene Group 2B 12. ECOLOGICAL INFORMATION Overview: Mobility: Persistence: Bioaccumulation: Degradability: Ecological Toxicity Data: 13. DISPOSAL CONSIDERATIONS Waste Description of Spent Product: Disposal Methods: Waste Disposal of Packaging: Moderate ecological hazard. This product may be dangerous to plants and/or wildlife. No data No data No data No data Spent or discarded material is a hazardous waste. Dispose of by incineration following Federal, State, Local, or Provincial regulations. Comply with all Local, State, Federal, and Provincial Environmental Regulations. 14. TRANSPORTATION INFORMATION United States: DOT Proper Shipping Name: Flammable liquids, n.o.s. (Ethanol, Pentane) UN Number: UN1993 Hazard Class: 3 Packing Group: II International: IATA Proper Shipping Name: Flammable liquids, n.o.s. (Ethanol, Pentane) UN Number: UN1993 Hazard Class: 3 Packing Group: II Marine Pollutant: No Chemical Name CAS# Marine Pollutant Severe Marine Pollutant 15. REGULATORY INFORMATION United States: Chemical Name CAS# CERCLA SARA 313 SARA EHS TSCA 313 Ethanol X n-pentane X hexane X X - X 2-methylpentane X 3-methylpentane X isopentane X Toluene X X - X Heptane X Butane X Methylcyclohexane X 2-methylhexane X Benzene X X - X 3-methylheptane X 3-methyloctane Ethylbenzene X X - X Cyclohexane X X - X n-octane X / DHA PONA Standard Page 12 of 18

13 3-methylhexane X 2,4-dimethylpentane X tert-amyl methyl ether X (TAME) 2-methylheptane Methylcyclopentane X 2,5-dimethylhexane ,3-dimethylpentane X nonane X 3-Methylnonane octene X 2,3-dimethylbutane X 1-hexene X n-decane X methanol X X - X n-pentadecane X n-tetradecane X n-dodecane X tridecane X N-Undecane X tert-butanol (2-methyl X - X propanol) 1-phenylhexane X 2,2,3-trimethylpentane ,5-Dimethylheptane pentene X m-xylene X X - X Isobutane X 4-isopropyltoluene (pcumene) X 2,2-dimethylpentane X 1-nonene X cis-1,2-dimethyl X cyclohexane ethylcyclopentane heptene X o-xylene X X - X 1-tert-Butyl-3,4, X trimethylbenzene cyclopentane X 3,3-dimethylpentane X isobutylbenzene X Propylbenzene X sec-butylbenzene X 1-ethyl-3-methylbenzene MTBE X X - X 1-methyl-2- isopropylbenzene 3,5-Dimethylheptane X trans-1, Dimethylcyclopentane Octane, 2,2-dimethyl Methylheptane cis-4-nonene ,3-Diethylpentane Trimethyl cyclohexane, ,1,4- & other isomers 3-Ethylpentane ,2,4-trimethylbenzene X - X 1,2-Dimethyl X ethylbenzene Methyl-2-propylbenzene, X 1-methyl-4-ethylbenzene X 3,3-Dimethylheptane Isopropylbenzene X X - X Methyl-3-propylbenzene, X / DHA PONA Standard Page 13 of 18

14 1-1,3,5-triethylbenzene X butylbenzene X tert-1-butyl-2- methylbenzene Benzene, 1,4-dimethyl- 2-ethyl X p-tert-butylethylbenzene Methyl X propylbenzene tert-butylbenzene X pentylbenzene X trans-1,4- Dimethylcyclohexane trans-1,3- Dimethylcyclopentane trans-3-heptene Methylnonane isoprene X X - X 2-methyloctane trans-2-octene methyl-2-pentene methyl-1-nonene Methyl-1-pentene X 2,4-dimethylhexane ethyl-2-methylbenzene X cis-3-nonene t-1-methyl-2-npropylcyclohexane cis-2-hexene Propane X N-Propylcyclopentane p-xylene X X - X trans-2-pentene X 2,3-dimethylheptane ,2-dimethylbutane X 3-Ethyloctane X Isobutylcyclohexane ctc-1,2,3- Trimethylcyclohexane t-1-methyl-2(4- Methylphenyl)cyclopenta ne trans-3-nonene cis-2-octene trans-2-nonene decene X 2-methyl-1-butene X m-cymene X 1-2-cyclopentane X 1,2,4-triethylbenzene ,4-Dimethylheptane ,2, Trimethylcyclohexane Octane, 3,3-dimethyl ,2,3-trimethylbutane X 2,2-dimethylhexane Benzene, 1,2-dimethyl X 4-ethyltrans-1,2-dimethyl X cyclohexane 1,2,4, X tetramethylbenzene trans-2-hexene ,3-Dimethyl-2- ethylbenzene 3-methyl-1-butene X / DHA PONA Standard Page 14 of 18

15 1,3, Trimethylcyclohexane 3-Ethylhexane X 1,1-2- Trimethylcyclohexane The following chemicals are listed on CA Prop 65: Chemical Name CAS # Regulation Ethanol Prop 65 Cancer Benzene Prop 65 Cancer Ethylbenzene Prop 65 Cancer Cumene Prop 65 Cancer Isoprene Prop 65 Cancer Ethyl alcohol Prop 65 Devolop Tox Toluene Prop 65 Devolop Tox Benzene Prop 65 Devolop Tox Methanol Prop 65 Devolop Tox Benzene Prop 65 Rep Male State Right To Know Listing: Chemical Name CAS# New Jersey Massachusetts Pennsylvania California Ethanol X X X X n-pentane X X X X hexane X X X - 2-methylpentane X X X - 3-methylpentane X X - isopentane X X X - Toluene X X X X Heptane X X X X Butane X X X X Methylcyclohexane X X X X 2-methylhexane X X - Benzene X X X X 3-methylheptane methyloctane X X - Ethylbenzene X X X X Cyclohexane X X X X n-octane X X X X 3-methylhexane X X X - 2,4-dimethylpentane X X X - tert-amyl methyl ether X (TAME) 2-methylheptane Methylcyclopentane X X X - 2,5-dimethylhexane ,3-dimethylpentane X X X - nonane X X X X 3-Methylnonane octene X X - 2,3-dimethylbutane X X X - 1-hexene X X X - n-decane X - X - methanol X X X X n-pentadecane n-tetradecane n-dodecane tridecane N-Undecane X tert-butanol (2-methyl X X X X 2-propanol) 1-phenylhexane ,2,3-trimethylpentane X X - 2,5-Dimethylheptane pentene X X X / DHA PONA Standard Page 15 of 18

16 m-xylene X X X X Isobutane X X X - 4-isopropyltoluene (pcumene) X X - 2,2-dimethylpentane nonene cis-1,2-dimethyl cyclohexane ethylcyclopentane X X - 1-heptene X - o-xylene X X X X 1-tert-Butyl-3,4, trimethylbenzene cyclopentane X X X X 3,3-dimethylpentane isobutylbenzene X X X - Propylbenzene X X X - sec-butylbenzene X X - 1-ethyl methylbenzene MTBE X X X - 1-methyl-2- isopropylbenzene 3,5-Dimethylheptane trans-1, Dimethylcyclopentane Octane, 2,2-dimethyl Methylheptane cis-4-nonene ,3-Diethylpentane X X - Trimethyl cyclohexane, ,1,4- & other isomers 3-Ethylpentane ,2,4-trimethylbenzene X X X - 1,2-Dimethyl ethylbenzene Methyl propylbenzene, 1-1-methyl ethylbenzene 3,3-Dimethylheptane X X - Isopropylbenzene X X X X Methyl propylbenzene, 1-1,3,5-triethylbenzene butylbenzene X - X - tert-1-butyl-2- methylbenzene Benzene, 1,4-dimethyl ethylp-tert Butylethylbenzene 1-Methyl propylbenzene tert-butylbenzene X X X - pentylbenzene X - X - trans-1,4- Dimethylcyclohexane trans-1,3- Dimethylcyclopentane trans-3-heptene Methylnonane isoprene X X X X 2-methyloctane X X - trans-2-octene / DHA PONA Standard Page 16 of 18

17 2-methyl-2-pentene X X - 2-methyl-1-nonene Methyl-1-pentene X X - 2,4-dimethylhexane X X - 1-ethyl methylbenzene cis-3-nonene t-1-methyl-2-npropylcyclohexane cis-2-hexene X - - Propane X X X - N-Propylcyclopentane p-xylene X X X X trans-2-pentene X X X - 2,3-dimethylheptane ,2-dimethylbutane X X X - 3-Ethyloctane Isobutylcyclohexane ctc-1,2,3- Trimethylcyclohexane t-1-methyl-2(4- Methylphenyl)cyclopent ane trans-3-nonene cis-2-octene trans-2-nonene decene methyl-1-butene X X X - m-cymene cyclopentane ,2,4-triethylbenzene ,4-Dimethylheptane ,2, Trimethylcyclohexane Octane, 3,3-dimethyl ,2,3-trimethylbutane X X - 2,2-dimethylhexane Benzene, 1,2-dimethyl ethyltrans-1,2-dimethyl cyclohexane 1,2,4, tetramethylbenzene trans-2-hexene ,3-Dimethyl-2- ethylbenzene 3-methyl-1-butene X X X - 1,3, Trimethylcyclohexane 3-Ethylhexane ,1-2- Trimethylcyclohexane 16. OTHER INFORMATION Prior Version Date: 03/30/16 Other Information: Any changes to the SDS compared to previous versions are marked by a vertical line in front of the concerned paragraph. References: Disclaimer: Restek Corporation provides the descriptions, data and information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. It is provided for your guidance only. Because many factors may affect processing or application/use, Restek Corporation recommends you perform an assessment to determine the suitability of a product for your particular purpose prior to use. No warranties of any kind, either expressed or implied, including / DHA PONA Standard Page 17 of 18

18 fitness for a particular purpose, are made regarding prodcuts described, data or information set forth. In no case shall the descriptions, information, or data provided be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk / DHA PONA Standard Page 18 of 18