Safety Data Sheet Revision Date: 11/22/16

Transcription

1 1. IDENTIFICATION Safety Data Sheet Revision Date: 11/22/16 Catalog Number / Product Name: / DHA PiONA Standard Company: Address: Restek Corporation 110 Benner Circle Bellefonte, Pa Phone#: Fax#: Emergency#: (CHEMTREC) (Outside the US) Revision Number: 2 Intended use: For Laboratory use only 2. HAZARD(S)IDENTIFICATION Emergency Overview: GHS Hazard Symbols: GHS Classification: GHS Signal Word: GHS Hazard: GHS Precautions: Safety Precautions: First Aid Measures: Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Specific Target Organ Systemic Toxicity (STOT) - Repeated Exposure Category 1 Flammable Liquid Category 2 Skin Corrosion/Irritation Category 2 Hazardous to the aquatic environment - Acute Category 2 Hazardous to the aquatic environment - Chronic Category 2 Danger Highly flammable liquid and vapour. Causes skin irritation. May cause genetic defects.. May cause cancer. Causes damage to organs through prolonged or repeated exposure. Toxic to aquatic life.. Toxic to aquatic life with long lasting effects. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilation and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands and skin thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower / DHA PiONA Standard Page 1 of 17

2 IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Specific treatment see section 4. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use extinguishing media in section 5 for extinction. Collect spillage. Storage: Disposal: Single Exposure Target Organs: Repeated Exposure Target Organs: Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container according to section 13 of the SDS. 3. COMPOSITION / INFORMATION ON INGREDIENT Chemical Name CAS # EINEC # % Composition Toluene octene hexene cis-1,2-dimethyl cyclohexane methylpentane Benzene Ethylbenzene cyclopentane n-decane n-tetradecane n-pentadecane hexane n-pentane nonane n-dodecane Heptane tridecane N-Undecane n-octane pentene ethylcyclopentane methyloctane nonene heptene Trimethyl cyclohexane, 1,1,4- & other isomers methylpentane phenylhexane Methylcyclopentane trans-1,3- Dimethylcyclopentane ,4-dimethylpentane / DHA PiONA Standard Page 2 of 17

3 3-methylheptane ,5-dimethylhexane Methylnonane Cyclohexane methyl-4-isopropylbenzene ,4-Dimethylcyclohexane-trans Cyclopentane, 1,2,3-trimethyl-, (1.alpha.,2.alpha.,3.beta.) methylheptane methylhexane ,3-dimethylpentane N-Propylcyclopentane cis-4-nonene trans-2-heptene t-1-methyl-2-npropylcyclohexane 1-tert-Butyl-3,4,5- trimethylbenzene ,2,3-Trimethylcyclohexane Methylcyclohexane ,5-Dimethylheptane Isobutylcyclohexane trans-1,2- Dimethylcyclopentane o-xylene t-1-methyl-2(4- Methylphenyl)cyclopentane m-xylene isobutylbenzene trans-3-heptene Propylbenzene isoprene ,2,3-trimethylpentane trans-2-octene methyl-2-pentene cis-2-heptene methyl-1-nonene Methyl-1-pentene methyl-2-isopropylbenzene ethyl-3-methylbenzene cis-2-octene ,2,4-Trimethylcyclohexane cis-3-nonene cis-2-hexene trans-2-pentene ,2-Dimethyl-3-ethylbenzene Methyl-2-propylbenzene, isopropylbenzene (cumene) ,3,5-triethylbenzene Methyl-3-propylbenzene, Benzene, 1,4-dimethyl-2-ethyl / DHA PiONA Standard Page 3 of 17

4 p-tert-butylethylbenzene butylbenzene tert-1-butyl-2-methylbenzene Methyl-4-propylbenzene methyl-4-ethylbenzene ,2,4-trimethylbenzene tert-butylbenzene pentylbenzene ,3,5-Trimethylcyclohexane ,2-dimethylpentane methylhexane ,3-dimethylbutane ,5-Dimethylheptane trans-3-nonene ,3-dimethylpentane trans-2-nonene decene methyl-1-butene Octane, 2,2-dimethyl ,1,2-Trimethylcyclohexane ,3-Diethylpentane ethyl-2-methylbenzene ,3-Dimethylheptane trans-1,2-dimethyl cyclohexane trans-2-hexene isopentane Methylnonane Methyl-1-ethylcyclopentane methyl-1-butene Methylheptane ,4-dimethylhexane Isobutylcyclopentane Isopropylcyclopentane methyloctane m-cymene p-xylene ,2,4-triethylbenzene ,3-dimethylheptane Benzene, 1,2-dimethyl-4-ethyl cis-2-pentene Ethyloctane ,2,4,5-tetramethylbenzene ,3-Dimethyl-2-ethylbenzene Ethylpentane ,4-Dimethylheptane Octane, 3,3-dimethyl ,2-dimethylhexane ,2,3-trimethylbutane FIRST-AID MEASURES / DHA PiONA Standard Page 4 of 17

5 Inhalation: Eyes: Skin Contact: Ingestion: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately Get medical attention immediately. Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor the eye daily as advised by your physician. Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. No data. Induce vomiting as a last measure. Induced vomiting may lead to aspiration of the material into the lungs potentially causing chemical pneumonitis that may be fatal. 5. FIRE- FIGHTING MEASURES Extinguishing Media: Fire and/or Explosion Hazards: Fire Fighting Methods and Protection: Hazardous Combustion Products: 6. ACCIDENTAL RELEASE MEASURES Personal Precautions and Equipment: Methods for Clean-up: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire. Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back Do not enter fire area without proper protection including self-contained toxic breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Use water spray/fog for cooling. Carbon dioxide, Carbon monoxide Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. 7. HANDLING AND STORAGE Handling Technical Measures and Precautions: Storage Technical Measures and Conditions: Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Use spark-proof tools and explosion-proof equipment Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Keep away from heat, sparks, and flame 8. EXPOSURE CONTROLS / PERSONAL PROTECTION United States: Chemical Name CAS No. IDLH ACGIH STEL ACGIH TLV-TWA OSHA Exposure Limit Toluene ppm IDLH 20 ppm TWA 50 ppm TWA; 188 mg/m3 TWA 200 ppm TWA; C 300 ppm 1-octene ND No TLV 1-hexene ND 50 ppm TWA cis-1,2-dimethyl ND No TLV cyclohexane 3-methylpentane ND 1000 ppm under Hexane isomers other 500 ppm TWA (listed under Hexane isomers other than n-hexane) / DHA PiONA Standard Page 5 of 17

6 than n- hexane) Benzene ppm IDLH 2.5 ppm STEL 2.5 ppm STEL; ppm TWA 0.5 ppm TWA; 1.6 mg/m3 TWA 10 ppm TWA (apply only to exempt industry segments) mg/m3 STEL Ethylbenzene ppm IDLH 125 ppm STEL; ppm TWA 100 ppm TWA; ppm TWA; 435 mg/m3 TWA mg/m3 STEL mg/m3 TWA cyclopentane ND 600 ppm TWA n-decane ND No TLV n-tetradecane ND No TLV n-pentadecane ND No TLV hexane ppm IDLH (10% LEL) n-pentane ppm IDLH (10% LEL) 1000 ppm 50 ppm TWA 500 ppm TWA; 1800 mg/m3 TWA 600 ppm TWA (listed under Pentane, all 1000 ppm TWA; 2950 mg/m3 TWA nonane ND 200 ppm TWA n-dodecane ND No TLV Heptane ppm IDLH 500 ppm TWA; 2000 mg/m3 TWA 500 ppm under Heptane, all 400 ppm TWA (listed under Heptane, all 400 ppm TWA; 1640 mg/m3 TWA tridecane ND No TLV N-Undecane ND No TLV n-octane ppm IDLH (10% LEL) (375) ppm STEL; (1750) mg/m3 STEL 300 ppm TWA 300 ppm TWA; 1400 mg/m3 TWA 500 ppm TWA; 2350 mg/m3 TWA 1-pentene ND No TLV ethylcyclopentane ND No TLV 3-methyloctane ND No TLV 1-nonene ND No TLV 1-heptene ND No TLV Trimethyl cyclohexane, 1,1,4- & other isomers ND No TLV 2-methylpentane ND 1000 ppm under Hexane isomers other than n- hexane) 500 ppm TWA (listed under Hexane isomers other than n-hexane) 1-phenylhexane ND No TLV Methylcyclopentane ND No TLV trans-1,3- Dimethylcyclopentan e ND No TLV 2,4-dimethylpentane ND 500 ppm under Heptane, all 400 ppm TWA (listed under Heptane, all 3-methylheptane ND No TLV 2,5-dimethylhexane ND No TLV 3-Methylnonane ND No TLV Cyclohexane ND 100 ppm TWA (300) ppm TWA; 1030 mg/m3 TWA 1-methyl-4- isopropylbenzene 1,4- Dimethylcyclohexane -trans 300 ppm TWA; 1050 mg/m3 TWA ND No TLV ND No TLV t-1-methyl-2-n- ND No TLV / DHA PiONA Standard Page 6 of 17

7 propylcyclohexane Cyclopentane, 1,2,3- trimethyl-, (1.alpha.,2.alpha.,3.b eta.) ND No TLV 2-methylheptane ND No TLV 2-methylhexane ND 500 ppm under Heptane, all 400 ppm TWA (listed under Heptane, all 2,3-dimethylpentane ND 500 ppm under Heptane, all 400 ppm TWA (listed under Heptane, all N ND No TLV Propylcyclopentane cis-4-nonene ND No TLV trans-2-heptene ND No TLV 1-tert-Butyl-3,4, ND No TLV trimethylbenzene 1,2,3- Trimethylcyclohexan e ND No TLV Methylcyclohexane ND 400 ppm TWA 400 ppm TWA; 1610 mg/m3 TWA 500 ppm TWA; 2000 mg/m3 TWA 2,5-Dimethylheptane ND No TLV Isobutylcyclohexane ND No TLV trans-1,2- Dimethylcyclopentan e ND No TLV o-xylene ND 150 ppm 100 ppm TWA STEL t-1-methyl-2(4- Methylphenyl)cyclop entane ND No TLV m-xylene ND 150 ppm 100 ppm TWA STEL isobutylbenzene ND No TLV trans-3-heptene ND No TLV Propylbenzene ND No TLV isoprene ND No TLV 2,2, ND No TLV trimethylpentane trans-2-octene ND No TLV 2-methyl-2-pentene ND No TLV cis-2-heptene ND No TLV 2-methyl-1-nonene ND No TLV 4-Methyl-1-pentene ND No TLV 1-methyl-2- ND No TLV isopropylbenzene 1-ethyl ND No TLV methylbenzene cis-2-octene ND No TLV 1,2,4- Trimethylcyclohexan e ND No TLV cis-3-nonene ND No TLV cis-2-hexene ND No TLV trans-2-pentene ND No TLV 1,2-Dimethyl ND No TLV ethylbenzene Methyl ND No TLV propylbenzene, 1- isopropylbenzene ND 50 ppm TWA 50 ppm TWA; / DHA PiONA Standard Page 7 of 17

8 (cumene) mg/m3 TWA 1,3,5-triethylbenzene ND No TLV Methyl ND No TLV propylbenzene, 1- Benzene, 1, ND No TLV dimethyl-2-ethylp-tert ND No TLV Butylethylbenzene butylbenzene ND No TLV tert-1-butyl-2- ND No TLV methylbenzene 1-Methyl ND No TLV propylbenzene 1-methyl ND No TLV ethylbenzene 1,2, ND No TLV trimethylbenzene tert-butylbenzene ND No TLV pentylbenzene ND No TLV 1,3, ND No TLV Trimethylcyclohexan e 2,2-dimethylpentane ND 500 ppm under Heptane, all 400 ppm TWA (listed under Heptane, all 3-methylhexane ND 500 ppm under Heptane, all 2,3-dimethylbutane ND 1000 ppm under Hexane isomers other than n- hexane) 400 ppm TWA (listed under Heptane, all 500 ppm TWA (listed under Hexane isomers other than n-hexane) 3,5-Dimethylheptane ND No TLV trans-3-nonene ND No TLV 3,3-dimethylpentane ND No TLV trans-2-nonene ND No TLV 1-decene ND No TLV 2-methyl-1-butene ND No TLV Octane, 2,2-dimethyl ND No TLV 1,1,2- Trimethylcyclohexan e ND No TLV 3,3-Diethylpentane ND No TLV 1-ethyl-2- methylbenzene ND No TLV 3,3-Dimethylheptane ND No TLV trans-1,2-dimethyl ND No TLV cyclohexane trans-2-hexene ND No TLV isopentane ND 600 ppm TWA (listed under Pentane, all 2-Methylnonane ND No TLV 1-Methyl ND No TLV ethylcyclopentane 3-methyl-1-butene ND No TLV 4-Methylheptane ND No TLV 2,4-dimethylhexane ND No TLV Isobutylcyclopentane ND No TLV Isopropylcyclopentan e ND No TLV / DHA PiONA Standard Page 8 of 17

9 2-methyloctane ND No TLV m-cymene ND No TLV p-xylene ND 150 ppm STEL 100 ppm TWA 1,2,4-triethylbenzene ND No TLV 2,3-dimethylheptane ND No TLV Benzene, 1, ND No TLV dimethyl-4-ethylcis-2-pentene ND No TLV 3-Ethyloctane ND No TLV 1,2,4, ND No TLV tetramethylbenzene 1,3-Dimethyl-2- ND No TLV ethylbenzene 3-Ethylpentane ND No TLV 3,4-Dimethylheptane ND No TLV Octane, 3,3-dimethyl ND No TLV 2,2-dimethylhexane ND No TLV 2,2,3-trimethylbutane ND No TLV Personal Protection: Engineering Measures: Respiratory Protection: Eye Protection: Skin Protection: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure. Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate symptoms. Wear chemically resistant safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material. Do not wear contact lenses. Have an eye wash station available. Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance, color: Odor: None Physical State: ph: Vapor Pressure: Boiling Point: Flash Point: -63 Flammability: Extremely Flammable Upper Flammable/Explosive Limit, % in air: Lower Flammable/Explosive Limit, % in air: Autoignition Temperature: deg C Decomposition Temperature: Evaporation Rate: 2.24 Odor Threshold: ND Solubility: Not determined Partition Coefficient: n-octanol in water: VOC % by weight: 1.9 Molecular Weight: 10. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Materials to Avoid / Chemical Incompatiability: Hazardous Decomposition Products: Stable under normal conditions. Temperatures above flash point in combination with sparks, open flames, or other sources of ignition.contamination High temperatures Strong oxidizing agents Carbon dioxide Carbon monoxide 11. TOXICOLOGICAL INFORMATION / DHA PiONA Standard Page 9 of 17

10 Routes of Entry: Inhalation, Skin Contact, Eye Contact, Ingestion Target Organs Potentially Affected By Exposure: Central nervous system stimulation, Eyes, Liver, Respiratory Tract, Skin, Blood, Bone Marrow (leukemia), Peripheral Nervous System Chemical Interactions That Change Toxicity: None Known Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. Skin Contact: Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Eye Contact: Contact with the eyes may cause moderate to severe eye injury. Eye contact may result in tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Ingestion Irritation: May be harmful if swallowed. Long-Term (Chronic) Health Effects: Carcinogenicity: Reproductive and Developmental Toxicity: Inhalation: Skin Contact: Skin Absorption: Contains a probable or known human carcinogen. Contains a known human reproductive and/or developmental hazard. Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.toxic! Can cause systemic damage upon prolonged and/or repeated exposure (see "Target Organs). Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Upon prolonged or repeated exposure, toxic if absorbed through the skin. Likely to cause systemic damage. Component Toxicological Data: NIOSH: Chemical Name CAS No. LD50/LC50 Toluene Inhalation LC50 Rat : 49 gm/m3/4h; Inhalation LC50 Mouse : 400 ppm/24h; Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : ul/kg 1-Octene Dermal LD50 Rabbit >10 g/kg (no deaths occurred); Inhalation LC50 Rat 8050 ppm 4 h; Oral LD50 Rat >5000 mg/kg 1-Hexene Dermal LD50 Rabbit >2000 mg/kg Benzene Dermal LD50 Rabbit >8200 mg/kg Benzene, ethyl Oral LD50 Rat : 3500 mg/kg; Dermal LD50 Rabbit : ul/kg Cyclopentane Oral LD50 Rat mg/kg Decane Inhalation LC50 Rat >1369 ppm 8 h (no deaths occurred, vapor); Dermal LD50 Rat >2000 mg/kg (no deaths occurred); Oral LD50 Rat >5000 mg/kg Tetradecane Dermal LD50 Rat >5000 mg/kg n-hexane Oral LD50 Rat 25 g/kg Pentane Oral LD50 Rat >2000 mg/kg; Dermal LD50 Rabbit 3000 mg/kg; Inhalation LC50 Rat 364 g/m3 4 h Nonane Inhalation LC50 Rat 3200 ppm 4 h (Source: IUCLID) Dodecane Inhalation LC50 Rat >142 ppm 8 h (Source: IUCLID) Heptane Dermal LD50 Rabbit 3000 mg/kg n-tridecane Dermal LD50 Rabbit >5000 mg/kg (no deaths occurred); Inhalation LC50 Rat >41 ppm 8 h; Oral LD50 Rat >5000 mg/kg N-Undecane Inhalation LC50 Rat >2.82 mg/l 8 h n-octane Inhalation LC50 Rat : 118 gm/m3/4h Octane Isoprene Dermal LD50 Rat >1 ml/kg / DHA PiONA Standard Page 10 of 17

11 Component Carcinogenic Data: OSHA: Chemical Name CAS No. Benzene Monograph 29, Supplement 7; 1987; {IARC - Group 1 (carcinogenic to humans)}; Known Carcinogen; {NTP Eighth Report - Known Carcinogens}; 1 ppm TWA; 5 ppm STEL; 0.5 ppm TWA action limit; Cancer hazard; Flammable (see 29 CFR ); {OSHA - 29 CFR 1910 Specifically Regulated Chemicals} Ethylbenzene Present Isoprene Present ACGIH: Chemical Name CAS No. Toluene A4 - Not Classifiable as a Human Carcinogen Benzene A1 - Confirmed Human Carcinogen A1-confirmed human carcinogen Ethyl benzene A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans NIOSH: Chemical Name CAS No. Benzene potential occupational carcinogen NTP: Chemical Name CAS No. Benzene Known Carcinogen IARC: Chemical Name CAS No. Group No. Monograph 29, Supplement 7; Group No data. Group 2A Ethylbenzene Group 2B Isoprene Group 2B 12. ECOLOGICAL INFORMATION Overview: Mobility: Persistence: Bioaccumulation: Degradability: Ecological Toxicity Data: 13. DISPOSAL CONSIDERATIONS Waste Description of Spent Product: Disposal Methods: Waste Disposal of Packaging: Moderate ecological hazard. This product may be dangerous to plants and/or wildlife. No data No data No data No data Spent or discarded material is a hazardous waste. Dispose of by incineration following Federal, State, Local, or Provincial regulations. Comply with all Local, State, Federal, and Provincial Environmental Regulations. 14. TRANSPORTATION INFORMATION United States: DOT Proper Shipping Name: Flammable liquids, n.o.s. (Toluene, Benzene) UN Number: UN1993 Hazard Class: 3 Packing Group: II International: IATA Proper Shipping Name: Flammable liquids, n.o.s. (Toluene, Benzene) UN Number: UN1993 Hazard Class: 3 Packing Group: II / DHA PiONA Standard Page 11 of 17

12 Marine Pollutant: No Chemical Name CAS# Marine Pollutant Severe Marine Pollutant 15. REGULATORY INFORMATION United States: Chemical Name CAS# CERCLA SARA 313 SARA EHS TSCA 313 Toluene X X - X 1-octene X 1-hexene X cis-1,2-dimethyl X cyclohexane 3-methylpentane X Benzene X X - X Ethylbenzene X X - X cyclopentane X n-decane X n-tetradecane X n-pentadecane X hexane X X - X n-pentane X nonane X n-dodecane X Heptane X tridecane X N-Undecane X n-octane X 1-pentene X ethylcyclopentane methyloctane nonene X 1-heptene X Trimethyl cyclohexane, ,1,4- & other isomers 2-methylpentane X 1-phenylhexane X Methylcyclopentane X trans-1,3- Dimethylcyclopentane 2,4-dimethylpentane X 3-methylheptane X 2,5-dimethylhexane Methylnonane Cyclohexane X X - X 1-methyl-4- isopropylbenzene 1,4- Dimethylcyclohexanetrans t-1-methyl-2-npropylcyclohexane Cyclopentane, 1,2,3- trimethyl-, (1.alpha.,2.alpha.,3.beta. ) methylheptane methylhexane X 2,3-dimethylpentane X N-Propylcyclopentane cis-4-nonene trans-2-heptene / DHA PiONA Standard Page 12 of 17

13 1-tert-Butyl-3,4, X trimethylbenzene 1,2, Trimethylcyclohexane Methylcyclohexane X 2,5-Dimethylheptane Isobutylcyclohexane trans-1, Dimethylcyclopentane o-xylene X X - X t-1-methyl-2(4- Methylphenyl)cyclopenta ne m-xylene X X - X isobutylbenzene X trans-3-heptene Propylbenzene X isoprene X X - X 2,2,3-trimethylpentane trans-2-octene methyl-2-pentene cis-2-heptene methyl-1-nonene Methyl-1-pentene X 1-methyl-2- isopropylbenzene 1-ethyl-3-methylbenzene cis-2-octene ,2, Trimethylcyclohexane cis-3-nonene cis-2-hexene trans-2-pentene X 1,2-Dimethyl X ethylbenzene Methyl-2-propylbenzene, X 1- isopropylbenzene X X - X (cumene) 1,3,5-triethylbenzene X Methyl-3-propylbenzene, X 1- Benzene, 1,4-dimethyl- 2-ethyl X p-tert-butylethylbenzene butylbenzene X tert-1-butyl-2- methylbenzene 1-Methyl-4- propylbenzene X 1-methyl-4-ethylbenzene X 1,2,4-trimethylbenzene X - X tert-butylbenzene X pentylbenzene X 1,3, Trimethylcyclohexane 2,2-dimethylpentane X 3-methylhexane X 2,3-dimethylbutane X 3,5-Dimethylheptane X trans-3-nonene ,3-dimethylpentane X trans-2-nonene decene X 2-methyl-1-butene X Octane, 2,2-dimethyl ,1, / DHA PiONA Standard Page 13 of 17

14 Trimethylcyclohexane 3,3-Diethylpentane ethyl-2-methylbenzene X 3,3-Dimethylheptane trans-1,2-dimethyl X cyclohexane trans-2-hexene isopentane X 2-Methylnonane Methyl ethylcyclopentane 3-methyl-1-butene X 4-Methylheptane ,4-dimethylhexane Isobutylcyclopentane Isopropylcyclopentane 2-methyloctane m-cymene X p-xylene X X - X 1,2,4-triethylbenzene ,3-dimethylheptane Benzene, 1,2-dimethyl X 4-ethylcis-2-pentene X 3-Ethyloctane X 1,2,4, X tetramethylbenzene 1,3-Dimethyl-2- ethylbenzene 3-Ethylpentane ,4-Dimethylheptane Octane, 3,3-dimethyl ,2-dimethylhexane ,2,3-trimethylbutane X The following chemicals are listed on CA Prop 65: Chemical Name CAS # Regulation Benzene Prop 65 Cancer Ethylbenzene Prop 65 Cancer Isoprene Prop 65 Cancer Cumene Prop 65 Cancer Toluene Prop 65 Devolop Tox Benzene Prop 65 Devolop Tox Benzene Prop 65 Rep Male State Right To Know Listing: Chemical Name CAS# New Jersey Massachusetts Pennsylvania California Toluene X X X X 1-octene X X - 1-hexene X X X - cis-1,2-dimethyl cyclohexane 3-methylpentane X X - Benzene X X X X Ethylbenzene X X X X cyclopentane X X X X n-decane X - X - n-tetradecane n-pentadecane hexane X X X - n-pentane X X X X nonane X X X X n-dodecane Heptane X X X X tridecane N-Undecane X / DHA PiONA Standard Page 14 of 17

15 n-octane X X X X 1-pentene X X X - ethylcyclopentane X X - 3-methyloctane X X - 1-nonene heptene X - Trimethyl cyclohexane, ,1,4- & other isomers 2-methylpentane X X X - 1-phenylhexane Methylcyclopentane X X X - trans-1,3- Dimethylcyclopentane 2,4-dimethylpentane X X X - 3-methylheptane ,5-dimethylhexane Methylnonane Cyclohexane X X X X 1-methyl-4- isopropylbenzene 1,4- Dimethylcyclohexanetrans t-1-methyl-2-npropylcyclohexane Cyclopentane, 1,2,3- trimethyl-, (1.alpha.,2.alpha.,3.bet a.) X X methylheptane methylhexane X X - 2,3-dimethylpentane X X X - N-Propylcyclopentane cis-4-nonene trans-2-heptene X X - 1-tert-Butyl-3,4, trimethylbenzene 1,2, Trimethylcyclohexane Methylcyclohexane X X X X 2,5-Dimethylheptane Isobutylcyclohexane trans-1, Dimethylcyclopentane o-xylene X X X X t-1-methyl-2(4- Methylphenyl)cyclopent ane m-xylene X X X X isobutylbenzene X X X - trans-3-heptene Propylbenzene X X X - isoprene X X X X 2,2,3-trimethylpentane X X - trans-2-octene methyl-2-pentene X X - cis-2-heptene methyl-1-nonene Methyl-1-pentene X X - 1-methyl-2- isopropylbenzene 1-ethyl-3- methylbenzene cis-2-octene ,2, / DHA PiONA Standard Page 15 of 17

16 Trimethylcyclohexane cis-3-nonene cis-2-hexene X - - trans-2-pentene X X X - 1,2-Dimethyl ethylbenzene Methyl propylbenzene, 1- isopropylbenzene X X X X (cumene) 1,3,5-triethylbenzene Methyl propylbenzene, 1- Benzene, 1,4-dimethyl ethylp-tert Butylethylbenzene butylbenzene X - X - tert-1-butyl methylbenzene 1-Methyl-4- propylbenzene 1-methyl ethylbenzene 1,2,4-trimethylbenzene X X X - tert-butylbenzene X X X - pentylbenzene X - X - 1,3, Trimethylcyclohexane 2,2-dimethylpentane methylhexane X X X - 2,3-dimethylbutane X X X - 3,5-Dimethylheptane trans-3-nonene ,3-dimethylpentane trans-2-nonene decene methyl-1-butene X X X - Octane, 2,2-dimethyl ,1, Trimethylcyclohexane 3,3-Diethylpentane X X - 1-ethyl methylbenzene 3,3-Dimethylheptane X X - trans-1,2-dimethyl cyclohexane trans-2-hexene isopentane X X X - 2-Methylnonane Methyl ethylcyclopentane 3-methyl-1-butene X X X - 4-Methylheptane ,4-dimethylhexane X X - Isobutylcyclopentane Isopropylcyclopentane 2-methyloctane X X - m-cymene p-xylene X X X X 1,2,4-triethylbenzene ,3-dimethylheptane Benzene, 1,2-dimethyl ethylcis-2-pentene X X X / DHA PiONA Standard Page 16 of 17

17 3-Ethyloctane ,2,4, tetramethylbenzene 1,3-Dimethyl-2- ethylbenzene 3-Ethylpentane ,4-Dimethylheptane Octane, 3,3-dimethyl ,2-dimethylhexane ,2,3-trimethylbutane X X OTHER INFORMATION Prior Version Date: 04/25/14 Other Information: Any changes to the SDS compared to previous versions are marked by a vertical line in front of the concerned paragraph. References: Disclaimer: Restek Corporation provides the descriptions, data and information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. It is provided for your guidance only. Because many factors may affect processing or application/use, Restek Corporation recommends you perform an assessment to determine the suitability of a product for your particular purpose prior to use. No warranties of any kind, either expressed or implied, including fitness for a particular purpose, are made regarding prodcuts described, data or information set forth. In no case shall the descriptions, information, or data provided be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk / DHA PiONA Standard Page 17 of 17