MATERIAL SAFETY DATA SHEET

Transcription

1 Page: 1 of 6 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT INFORMATION Product Name: Drum Brake Lining (Non-Asbestos) I Product Synonyms: Generic MSDS - This MSDS covers multiple products DEL-GG-FF, DEL-ND-EE, DEL-OM-FE, DEL-PC-FF (Product Edgecode) Article. OSHA Hazard Communication Standard does not apply Recommended Use: Product Use Overview: These products are intended for use as automotive or truck friction components and are not considered to be hazardous. The ingredients listed below are bound in a non-friable resin matrix, therefore, personal exposure during the normal handling and use is considered minimal. The warnings expressed on this MSDS have been provided to communicate the hazardous nature associated with exposure to the individual components. We have provided this information regardless of the risk of exposure and have considered this during both normal use and foreseeable misuse. Using good work practices will minimize the risk of adverse health effects from overexposure to the hazardous components. As supplied, this friction material does not require sanding, drilling or other machining Operations. MANUFACTURER INFORMATION Address: 4400 PRIME PARKWAY USA ILLINOIS MCHENRY MAILING Communication Lines: Phone EMERGENCY Phone INFO This product is to be used in the workplace for a specific end use. Consequently, the OSHA Hazard Communication Standard does not apply. The reason for the exemption is contained in 29 CFR, Part , (B)(6)(V), as amended August 12, 1994 per the Federal Register. 2 INGREDIENT INFORMATION FORMULATION Ingredients: Chemical Name CAS Number Prefix Value Unit Limits ORGANIC RESINS < 100 %Wt No BARIUM SULFATE < 100 %Wt Yes GRAPHITE < 100 %Wt Yes ALUMINUM OXIDE (2:3) < 100 %Wt Yes IRON < 100 %Wt Yes Glass, oxide, chemicals < 100 %Wt No SILICA, CRYSTALLINE < 100 %Wt Yes QUARTZ Additional ingredient information is not required because this product is OSHA exempt. 3 HAZARDS IDENTIFICATION Hazards Overview: Emergency Overview: Drum brake lining products are not considered hazardous products. They will not support combustion but may release irritating and potentially toxic combustion products under fire conditions. Breathing dust generated during sanding or grinding may cause respiratory irritation. Prolonged overexposure may result in lung disease or damage. These products contain a small amount of crystalline silica. Prolonged overexposure to respirable crystalline silica may cause lung disease (silicosis) and increase the risk of lung cancer. Risk of cancer depends on duration and level of exposure. The hazardous components in this product are bound in a resin matrix and are not released during normal handling in finished form. Specific Hazards (Routes Of ): Routes Duration Observation Eye Contact Acute Dust from product may cause abrasive irritation. Skin Contact Acute Prolonged contact with dust from product may cause irritation. Inhalation Acute Inhalation of excessive concentrations of dust may cause mucous membrane and respiratory irritation. Ingestion Acute a potential route of exposure.

2 Page: 2 of 6 Routes Duration Observation Inhalation Chronic Inhalation of excessive concentrations of any dust, including dust from this material, may cause lung injury. This product contains a small amount of crystalline silica. Prolonged overexposure to respirable crystalline silica may cause silicosis, a progressive, disabling, fatal lung disease. Symptoms of silicosis include cough, shortness of breath, wheezing and reduced pulmonary function. Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage is occurring. Medical Conditions Aggravated By : Persons with pre-existing skin and respiratory disorders may be at an increased risk from exposure. 4 FIRST AID MEASURES First Aid By:: Inhalation If symptoms develop, remove person from source of exposure to fresh air. Get medical attention if irritation persists. Skin Contact Wash area of contact gently with soap and water. Launder contaminated clothing before reuse. Get medical attention if irritation persists Eye Contact Do not rub eyes. Flush immediately with large amounts of water. Eyelids should be held away from the eyeball to ensure thorough rinsing. If irritation persists or for foreign body in the eye, get immediate medical attention. Ingestion a potential route of exposure. 5 FIRE FIGHTING MEASURES Flash Point: Explosive Limits: Upper Explosive Limit Flammability Limit (UEL) Lower Explosive Limit Flammability Limit (LEL) Autoignition Temperature: Extinguishing Media: Use any media suitable for the surrounding fire. Fire and Explosion Hazards: The organic resins may burn at high temperatures, however, this material will not support combustion. Combustion Products: Combustion products from organic resins may include carbon monoxide, carbon dioxide, nitrogen oxides, sulfur dioxide, aldehydes, phenols, cyanide, ammonia and various hydrocarbons. Special Fire Fighting Procedures: Avoid breathing combustion products if product is involved in a fire. For firefighting, use self-contained breathing apparatus. 6 ACCIDENTAL RELEASE MEASURES PRECAUTIONS IN CASE OF ACCIDENTAL RELEASE Personal Precautions: Personal safety and exposure recommendations described elsewhere in this data sheet apply to exposure during clean up of spilled material. Environmental Precautions: Refer to Section 15 for Release Reporting information, if applicable. SPILL OR LEAK PROCEDURES Recovery: Pick up large pieces. Use HEPA vacuum to clean up any dust. Wet dust with water where sweeping is necessary. Disposal: Refer to Section 13 for disposal considerations. 7 HANDLING AND STORAGE HANDLING Safe Handling Procedures: Avoid generating and breathing dust. Do not grind, sand, drill or machine these parts. Follow good housekeeping to prevent accumulation of dust on floors, machinery and equipment. Do not dry sweep dust. Wet dust with water before sweeping or use a HEPA vacuum to collect dust and clean equipment. Do not use compressed air for cleaning. Wash thoroughly after work using soap and water.

3 Page: 3 of 6 STORAGE Storage Conditions: Keep product dry. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: Use with adequate local exhaust ventilation and dust collection as necessary to maintain the concentration of airborne dust below the exposure limits. EXPOSURE LIMITS : Chemical Name CAS Number Type Value Specificati Source on BARIUM SULFATE PEL-T WA 15mg/m3 - OSHA - Permissible BARIUM SULFATE GM BARIUM SULFATE TLV- BARIUM SULFATE State- BARIUM SULFATE State- BARIUM SULFATE State- GRAPHITE PEL-T WA GRAPHITE GM GRAPHITE TLV- GRAPHITE State- GRAPHITE State- GRAPHITE State- ALUMINUM OXIDE (2:3) PEL-T WA ALUMINUM OXIDE (2:3) GM ALUMINUM OXIDE (2:3) TLV- Limits (PELs) 10mg/m3 - GM 10mg/m3 - Threshold 10mg/m3 - MICHIGAN 10mg/m3 - NEW YORK 10mg/m3 - TENNESSEE 5mg/m3 - OSHA - Permissible Limits (PELs) 2mg/m3 - GM 2mg/m3 - Threshold 2.5mg/m3 - MICHIGAN 2.5mg/m3 - NEW YORK 2.5mg/m3 - TENNESSEE 15mg/m3 - OSHA - Permissible Limits (PELs) 10mg/m3 - GM 10mg/m3 - Threshold

4 Page: 4 of 6 Chemical Name CAS Number Type Value Specificati on Source ALUMINUM OXIDE (2:3) State- 10mg/m3 - MICHIGAN ALUMINUM OXIDE (2:3) State- 10mg/m3 - NEW YORK ALUMINUM OXIDE (2:3) State- 10mg/m3 - TENNESSEE IRON GM 10mg/m3 - GM SILICA, CRYSTALLINE - QUARTZ TLV- SILICA, CRYSTALLINE - QUARTZ State- SILICA, CRYSTALLINE - QUARTZ State- SILICA, CRYSTALLINE - QUARTZ State- SILICA, CRYSTALLINE - QUARTZ GM PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment (PPE): Hand Protection Gloves recommended for handling brake parts. Contact local health and safety representative for appropriate glove type for your specific application(s). Eye Protection Safety glasses recommended. Respiratory If the concentrations exceed the Threshold Protection (TLV), a NIOSH approved particulate respirator appropriate for the exposure levels should be worn. Select based on consideration of the airborne workplace concentrations and duration of exposure. Select and use respirators in accordance with 29 CFR , ANSI Z88.2, the NIOSH Respirator Decision Logic and good industrial hygiene practice. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Physical State: Solid. Metallic parts with gray friction material. PHYSICAL PROPERTIES ph Value: Changes of State: Boiling Point Melting/Freezing Point Vapor Pressure: Applicab Melting Point 50ug/m3 - Threshold 100ug/m3 - MICHIGAN 100ug/m3 - NEW YORK 100ug/m3 - TENNESSEE 100ug/m3 - GM

5 Page: 5 of 6 le Vapor Density: Evaporation Rate: Specific Gravity: Range g/cc Solubility: Water Insoluble. Total Amount Of:: Percent Volatile Additional Chemical and Physical Data: Octanol/Water Partition Coefficient: 10 STABILITY AND REACTIVITY STABILITY INFORMATION Stability Under Normal Conditions: Stable Incompatible Materials: None determined. HAZARDOUS DECOMPOSITION Reactions: Type of Reaction Thermal Decomposition Decomposition 11 TOXICOLOGICAL INFORMATION OCCUPATIONAL EXPERIENCES Additional Observations: No acute toxicity data is available for this product or its components. Reaction Products Combustion Products: Combustion products from organic resins may include carbon monoxide, carbon dioxide, nitrogen oxides, sulfur dioxide, aldehydes, phenols, cyanide, ammonia and various hydrocarbons. Combustion products from organic resins may include carbon monoxide, carbon dioxide, nitrogen oxides, sulfur dioxide, aldehydes, phenols, cyanide, ammonia and various hydrocarbons. CLASSIFICATION OF INGREDIENTS Carcingenicity: These products contain a small amount of crystalline silica. Prolonged overexposure to respirable crystalline silica may cause lung disease (silicosis) and increase the risk of lung cancer. Risk of cancer depends on duration and level of exposure. The National Toxicology Program (NTP) has classified respirable crystalline silica as reasonably anticipated to be a carcinogen. The International Agency for Research on Cancer (IARC) has classified respirable crystalline silica as a group 1 carcinogen (carcinogenic to humans). IARC has classified man made vitreous fibers (including mineral wool fibers) as group 2B carcinogens (sufficient evidence in animals, inadequate evidence in humans). \California Proposition 65: This product contains the following chemicals known to the State of California to cause cancer: None Reproductive Effects: California Proposition 65: This product contains the following chemicals known to the State of California to cause reproductive harm: None 12 ECOLOGICAL INFORMATION ENVIRONMENTAL IMPACT This product is not anticipated to have an adverse effect on the environment. ECOTOXICITY No ecotoxicity data is available. 13 DISPOSAL CONSIDERATIONS Waste Disposal Information: Landfill in compliance with all applicable Federal, state and local regulations.

6 Page: 6 of 6 14 TRANSPORT INFORMATION DOT Information: Regulated as a Hazardous Material. 15 REGULATORY INFORMATION LABELLING Hazard Codes: NFPA Health 1 NFPA Flammability 0 NFPA Reactivity 0 HMIS Health 1 HMIS Flammability 0 HMIS Reactivity 0 NATIONAL REGULATIONS SARA 311/312: Yes SARA 313: Yes Immediate Health: No Delayed Health: Yes Fire: No Sudden Pressure Release: No Reactive: No Other Regulation: Comprehensive Environmental Response and Liability Act of 1980 (CERCLA) Reportable Quantity: Toxic Substances Control Act (TSCA): Superfund Amendments and Reauthorization Act (SARA) Title Ill Information: This product is not subject to CERCLA reporting requirements, however, many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. Manufactured articles are not subject to TSCA. These products are manufactured with chemicals listed on the TSCA inventory. SARA 313 inherited from ingredient list. STATE/LOCAL REGULATIONS California Proposition 65: This product contains the following chemicals known to the State of California to cause cancer or reproductive harm: None 16 OTHER INFORMATION Comments: These products do not contains asbestos, however, the OSHA Asbestos Standard (29CFR ) Appendix F, "Work Practices and Engineering Controls for Automotive Brake and Clutch Inspection, Disassembly, Repair and Assembly", contains guidance on minimizing employee exposure during brake operations. Brake Parts, Inc. recommends that these work practices and engineering controls be implemented even when working with non-asbestos brakes. Additional Comments: Additional Limits: GM and State-'s were provided by General Motors.