Rapid Set One Pass is an all purpose, durable, fast-setting joint compound & gyprock wall repair material. Company Name
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1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name Rapid Set One Pass Other Means of Drywall Repair Material Identification Other Names - Product Use Rapid Set One Pass is an all purpose, durable, fast-setting joint compound & gyprock wall repair material. Company Name CTS Rapid Set Cement Pty Ltd Address Cann Street Guildford NSW 2161 Telephone Number Emergency Telephone HAZARDS IDENTIFICATION Classification of the Substance or Mixture Exclamation mark H315 - Causes skin irritation Skin Corrosion/Irritation - Warning - Hazard Category 2 H319 - Causes serious eye irritation H335 - May cause respiratory irritation H317 - May cause an allergic skin reaction Serious Eye Damage/Irritation - Warning - Hazard Category 2A STOT (Single Exposure) - Warning - Hazard Category 3 Sensitisation Skin - Warning - Hazard Category 1 GHS Label Elements Including Precautionary Statements Prevention Avoid breathing dusts. Wear eye protection/face protection. In case of inadequate ventilation wear respiratory protection. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves. Contaminated work clothing should not be allowed out of the workplace. Response IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. 12/07/2012 1/7
2 IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical attention. Take off contaminated clothing and wash before reuse. Storage Store in a well-ventilated place. Disposal Dispose of contents/container in accordance with local and state government regulations. Other hazards which do not result in classification Repeated exposure may cause skin dryness or cracking. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Characterisation Mixture Ingredient CAS No Concentration Calcium oxide % Silica ( silicon dioxide) % Aluminium oxide (Al 2 O 3 ) % Sulfur trioxide % Cement, portland % Iron oxide (FeO) % Magnesium oxide (MgO) % Sodium oxide (Na 2 O) This product may contain traces of hexavalent chromium, which is a known human carcinogen. 4. FIRST AID MEASURES Inhalation Ingestion Skin Eyes If inhaled, remove to fresh air. Seek medical attention if symptoms persist. Drink plenty of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Seek immediate medical attention. In case of skin contact, immediately remove contaminated clothing and wash affected areas with water and soap. Seek medical attention if symptoms persist. Launder contaminated clothing before reuse. In case of eye contact, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Hazardous Combustion Products Special Protective For major fires call the Fire Brigade. Ensure that an escape path is available from any fire. Water spray, carbon dioxide, foam and dry powder. Wear Safe Work Australia approved self-contained breathing 12/07/2012 2/7
3 Equipment and Precautions for Fire Fighters Unusual Fire or Explosion Hazards Hazchem Code apparatus with positive pressure and full protective clothing. None known. Not allocated 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Environmental Precautions Methods and Materials for Containment and Cleaning Up Wear Safe Work Australia full protective clothing. Evacuate all nonessential personnel from affected area. Do not breathe dust. Ensure adequate ventilation. Do not allow product to enter drains or water courses. Vacuum the spill. Avoid generating dust. Place into containers for reuse or disposal. 7. HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage Use of safe work practices are recommended to avoid eye or skin contact and inhalation of dust. Prevent generating dust. Provide adequate ventilation. Food, beverages and tobacco products should not be stored or consumed where this material is in use. Always wash hands before smoking, eating, drinking or using the toilet. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing and other protective equipment before storage or re-use. Provide eyewash fountains and safety showers in close proximity to points of potential exposure. Store in the original packaging in a cool, dry, and well ventilated area. Keep away from strong oxidizing agents, acids, ammonium and salts. Avoid unintentional contact with water. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters - Exposure Standards (Safe Work Australia) Engineering Controls Calcium oxide: TWA: - ppm / 2 mg/m 3 STEL: - ppm / - mg/m 3 Fumed silica (respirable dust): TWA: - ppm / 2 mg/m 3 STEL: - ppm / - mg/m 3 Aluminium oxide: TWA: - ppm / 10 mg/m 3 STEL: - ppm / - mg/m 3 Maintain air concentration below occupational exposure standards, using engineering controls. Personal Protective Equipment (PPE) 12/07/2012 3/7
4 Respiratory Protection Eye/Face Protection Skin Protection Thermal Hazards Wear a Safe Work Australia approved respirator equipped with particulate cartridges when working in dusty or poorly ventilated areas or if occupational exposure standards are exceeded. See Australian Standards AS/NZS 1715 and 1716 for more information. Safety glasses with top and side shields or goggles. See Australian Standards AS/NZS 1336 and 1337 for more information. Impervious gloves, protective clothing and boots. See Australian Standards AS/NZS 2161, and for more information. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Grey or white powder Odour Odourless Solubility in Water Slight Melting Point Initial Boiling Point / Range Flash Point (Closed Cup) Non-combustible Evaporation Rate None Lower Flammability or Explosive Limit Upper Flammability or Explosive Limit Vapour Pressure None Vapour Density (Air=1) None Relative Density (Specific Gravity) 3.1 Auto-ignition Temperature Decomposition Temperature No information available Evaporation Rate 10. STABILITY AND REACTIVITY Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable at ambient temperature and under normal conditions of use. No hazardous reactions known. Contact with water. None known. None known. 11. TOXICOLOGICAL INFORMATION Toxicity Calcium oxide: Irritating to respiratory system and skin. May cause serious damage to eyes. Symptoms include cough, shortness of breath, headache, nausea and vomiting. Silica ( silicon dioxide): Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. 12/07/2012 4/7
5 Sulfur trioxide : Oral LD50 (rat) = 2140 mg/kg Inhalation LD50 (rat) = 510 mg/m 3 Inhalation LD50 (mouse) = 320 mg/m 3 Draize test - Eye (rabbit) = 250 µg - Severe; Sulfur trioxide reacts violently with water forming sulfuric acid. Causes eye and skin burns. Causes digestive and respiratory tract burns. May be fatal if inhaled. Workers chronically exposed to sulfuric acid mists may show various lesions of the skin, tracheobronchitis, stomatitis, conjunctivitis, or gastritis. Occupational exposure to strong inorganic acid mists containing sulfuric acid is carcinogenic to humans. Iron oxide (FeO): May be harmful if swallowed, inhaled or absorbed through skin. May cause skin and eye irritation. Overdose of iron compounds may have a corrosive effect on the gastrointestinal tract. Symptoms include diarrhoea, vomiting, nausea and abdominal pain. Further complications may develop leading to acute liver necrosis. Sodium oxide (Na 2 O): Causes severe burns. Reacts violently with water. Acute Health Effects Routes of Exposure Inhalation: Ingestion: Eye: Skin: May cause respiratory tract, nose, throat, and lung irritation and inflammation. May be caustic to mucous membranes. May severely irritate eyes. May develop inflammation of the cornea. May irritate skin causing drying, redness, rash, and blistering. When mixed with water, a high alkali material is produced which can cause severe skin burns. Individuals may develop allergic dermatitis. Skin Corrosion/Irritation Serious Eye Damage/Irritation Respiratory or Skin Sensitisation Germ Cell Mutagenicity Carcinogenicity Reproductive Toxicity Specific Target Organ Toxicity (STOT) - Single Exposure Specific Target Organ Toxicity (STOT) - Repeated Exposure Aspiration Hazard Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction. Not expected to be a hazard. Silica, amorphous is classified by IARC as a Group 3 - Not classifiable as to its carcinogenicity to humans. Not expected to be a hazard. May cause respiratory irritation. Not expected to be a hazard. Not expected to be an aspiration hazard. 12/07/2012 5/7
6 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and Degradibility Bioaccumulative Potential Mobility in Soil Calcium oxide: LC 50 (Cyprinus carpio) = 1070 mg/l 96h 13. DISPOSAL CONSIDERATIONS Disposal methods and containers Special precautions for landfill or incineration Dispose according to applicable local and state government regulations. Please consult your state Land Waste Management Authority for more information. 14. TRANSPORT INFORMATION Not classified as a dangerous good according to the Australian Code for the Transport of Dangerous goods by road or rail (ADG 7). UN Number Proper Shipping Name Dangerous Goods Class Subsidiary Risk Hazchem Code Packing Group Special Provisions Limited Quantities Packagings & IBCs - Packing Instruction Packagings & IBCs - Special Packing Provisions Portable Tanks & Bulk Containers Instructions Portable Tanks & Bulk Containers Spec Provisions SEA TRANSPORT IMDG UN Number Proper Shipping Name Dangerous Goods Class Packing Group EMS Number AIR TRANSPORT ICAO / IATA UN Number Proper Shipping Name Dangerous Goods Class Packing Group 12/07/2012 6/7
7 15. REGULATORY INFORMATION Calcium oxide, silica ( silicon dioxide), aluminium oxide (Al 2 O 3 ), sulfur trioxide, cement, portland, iron oxide (FeO), magnesium oxide (MgO) and sodium oxide (Na 2 O) are listed in the Australian Inventory of Chemical Substances (AICS). 16. OTHER INFORMATION Last Revision of MSDS Rev 1.0 (12/07/2012) Prepared by MSDS.COM.AU Pty Ltd Abbreviations Used GHS Globally Harmonised System of Classification and Labeling of Chemicals IARC: International Agency for Research on Cancer STEL: Short term exposure limit TWA: Time weighted average Emergency Contacts CTS Rapid Set Cement Pty Ltd CTS Rapid Set Cement Pty Ltd Emergency Number Police and Fire Brigade Poisons Information Centre The information contained in this material safety data sheet is provided in good faith and is believed to be accurate at the date of issuance CTS Rapid Set Cement Pty Ltd makes no representation of the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or damage related to the supply or use of the information in this material safety data sheet. MSDS.COM.AU Pty Ltd is not in a position to warrant the accuracy of the data herein. The user is cautioned to make their own determinations as to the suitability of the information provided to the particular circumstances in which the product is used. This MSDS is prepared in accord with the Safe Work Australia document Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals. 12/07/2012 7/7
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