Version 4 Revision Date 07/19/2013 Print Date 07/19/2013

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Product Use Description : Surface Additive Company : BYK USA Inc. 524 South Cherry Street Wallingford CT Prepared by : J.Nole, Safety; M.McCutcheon, Regulatory Telephone : (203) Visit our web site : address : ehs.byk.usa@altana.com Emergency telephone number : CHEMTREC / SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form Colour Odour : liquid : colourless : not significant OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Potential Health Effects Eyes Skin Ingestion Inhalation Other Acute Effects Chronic Exposure : Contact will probably cause irritation. : Contact will probably cause irritation. : Ingestion may irritate the digestive tract and cause same symptoms as inhalation. : High concentrations of vapors may be irritating to the respiratory tract. May cause CNS depression (drowsiness, loss of coordination and fatigue); narcosis. : Absorption of 2-Butoxyethanol may cause acute red blood cell damage and kidney effects. Inhalation of 2-Butoxyethanol has damaged the kidneys of laboratory animals. OSHA PEL-TWA for 2-butoxyethanol = 50 ppm (skin) : Absorption of 2-Butoxyethanol by inhalation and/or repeated skin contact may cause injury to liver, kidney and blood damage. 2-Butoxyethanol is considered fetotoxic; has caused toxic reproductive effects in laboratory animals at maternally toxic 1 / 12

2 doses. 2-Butoxyethanol had both positive and negative results in in vitro mutagenicity studies. In a 2 yr. cancer study, the NTP has determined 2- butoxyethanol has a potential to cause cancer (potentially carcinogenic to mice) but there is not enough evidence to list 2-butoxyethanol as a carcinogen. The relevance to humans is unknown. Prolonged exposure to respirable aerosols (mists) of polyalkylene glycol has caused lung damage in rats (90 days; 0.3 mg/m3). Inhalation (300 ppm)/ingestion (1600 mg/kg) dosages of Octamethylcyclotetrasiloxane has caused liver weight increases in laboratory animals. Liver weight changes via inhalation were reversible. A reproductive study (rats, inhalation: 700 ppm/70 days) showed a statistically significant reduction in mean litter size and implantation sites. The relevance of this data to humans is uncertain. Aggravated Medical Condition Primary Routes of Entry : May be aggravating to some skin conditions asthma-type conditions pre-existing liver and/or kidney disorders : Skin contact Skin absorption Inhalation Eyes Ingestion Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. ACGIH 2-Butoxyethanol Environmental Effects Environmental Effects : No information available. 2 / 12

3 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Solution of a polyether modified polydimethylsiloxane Hazardous components Component CAS-No. Weight percent 2-Butoxyethanol Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) Siloxane Polyglycol Octamethylcyclotetrasiloxane SECTION 4. FIRST AID MEASURES First aid procedures Inhalation Skin contact Eye contact : Remove to fresh air. Administer artificial respiration if necessary. Get medical aid as soon as possible. : Remove contaminated clothing. Wash thoroughly with soap and water. : Immediately flush with plenty of water for at least 20 minutes. Get medical aid. Ingestion : Do not induce vomiting; aspiration hazard. Dilute with 1-2 glasses of water. Get medical aid. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs. Notes to physician Risks : No information available. SECTION 5. FIREFIGHTING MEASURES Flammable properties 3 / 12

4 Flash point Ignition temperature Lower explosion limit Upper explosion limit Suitable extinguishing media Unsuitable extinguishing media Special protective equipment for firefighters Specific hazards during firefighting Hazardous decomposition products due to incomplete combustion. Further information : 63 C ( F) Method: 49 (Pensky-Martens) : 230 C ( F) Method: calculated : 1.10 %(V) : %(V) : Foam Carbon dioxide (CO2) Dry chemical : No information available. : In the event of fire, wear self-contained breathing apparatus. : Cool closed containers exposed to fire with water spray. Will not explode on mechanical impact. : Carbon oxides silicone compounds formaldehyde : Keep away from heat and sources of ignition. Keep away from oxidizing agents. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment Methods for cleaning up Additional advice : Eliminate all sources of ignition. Ventilate area if indoors. Wear self-contained breathing apparatus and full protective clothing. : Prevent spilled material from entering the ground, water and/or air by using appropriate containment methods. : Stop leak. Dike and contain spill. : Pump into salvage tanks and/or absorb with suitable material. Use sparkless shovels to remove material. : No further information is available. SECTION 7. HANDLING AND STORAGE Handling Handling : Harmful in contact with skin. Avoid contact with skin and eyes. 4 / 12

5 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Ensure all equipment is electrically grounded before beginning transfer operations. Containers should be grounded when being emptied. Vapours may travel to areas away from work site before igniting/flashing back to Vapour source.* Keep away from oxidizing agents. Keep container tightly closed. Handle as an industrial chemical. Storage Advice on common storage : Keep product and empty container away from heat and sources of ignition. Take precautionary measures against static discharges. Keep away from strong bases. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components CAS-No. Value Control Update Basis parameters 2-Butoxyethanol TWA 20 ppm ACGIH TWA 50 ppm 240 mg/m OSHA Z-1 TWA 5 ppm 24 mg/m NIOSH REL Engineering measures Engineering measures : Use with local exhaust ventilation. Personal protective equipment Eye protection : Safety Glasses Goggles Hand protection Skin and body protection : Impervious butyl rubber gloves : Choose body protection according to the amount and concentration of the dangerous substance at the work place. 5 / 12

6 Respiratory protection Hygiene measures : Unless air monitoring demonstrates vapor/mist/dust levels are below the PEL/TLV wear a properly fitted respirator (NIOSH approved) or dust mask during exposure. : Clean long legged, long sleeved work clothes. Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour Odor Threshold Flash point Ignition temperature Lower explosion limit Upper explosion limit ph Freezing point Initial boiling point Vapour pressure Evapouration rate Density Bulk density Water solubility Partition coefficient: n- octanol/water Viscosity, kinematic : liquid : colourless : not significant : 63 C ( F) Method: 49 (Pensky-Martens) : 230 C ( F) Method: calculated : 1.10 %(V) : %(V) : 168 C ( F) : < hpa at 20 C (68.00 F) Method: calculated : g/cm3 at 20 C (68.00 F)Method: DIN EN ISO : not applicable : completely miscible : at 20 C (68.00 F) at 40 C ( F) Relative vapour density 6 / 12

7 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products Chemical stability : None known. : Strong oxidizing agents alkalis : None known. : Stable; polymerization will not occur SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity (Component) : Component: Butoxyethanol LD50 rat Dose: 530 mg/kg LD50 Dose: 520 mg/kg Component: Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) LD50 rat Dose: 2,500 mg/kg Component: - Polyglycol LD50 Component: Octamethylcyclotetrasiloxane LD50 rat Dose: 1,540 mg/kg Acute dermal toxicity (Component) : Component: Butoxyethanol LD50 Dose: 220 mg/kg LD50 Dose: 100 mg/kg Component: Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) LD50 Dose: mg/kg Component: - Polyglycol LD50 Component: Octamethylcyclotetrasiloxane 7 / 12

8 LD50 Dose: 754 mg/kg Acute inhalation toxicity (Component) : Component: Butoxyethanol LC50 rat Dose: 468 ppm Exposure time: 4 h Component: Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) LC50 Component: - Polyglycol LC50 Component: Octamethylcyclotetrasiloxane LC50 Skin irritation (Product) Skin irritation (Component) : Component: Butoxyethanol Result: Moderate skin irritation Component: Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) Result: slight irritation Component: - Polyglycol Result: slight irritation Component: Octamethylcyclotetrasiloxane Result: slight irritation Eye irritation (Product) Eye irritation(component) : Component: Butoxyethanol Result: Eye irritation Component: Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) 8 / 12

9 Result: Mild eye irritation Component: - Polyglycol Result: Mild eye irritation Component: Octamethylcyclotetrasiloxane Result: Mild eye irritation Sensitisation (Product) SECTION 12. ECOLOGICAL INFORMATION Additional ecological information (Product) : There is for this product. SECTION 13. DISPOSAL CONSIDERATIONS Further information : Dispose of in accordance with applicable local/municipal, state/provincial and federal regulations. SECTION 14. TRANSPORT INFORMATION Container sizes: 55 gallon drums, 5 or 6-gallon pails, 2oz/16oz samples) DOT Not dangerous goods IATA Not dangerous goods IMDG_US Not dangerous goods SECTION 15. REGULATORY INFORMATION HMIS Classification : Health hazard: 2 Chronic Health Hazard: * Flammability: 2 Reactivity: 0 PPI:B National Fire Protection : IIIA 9 / 12

10 Association (NFPA) Class Emergency Planning Community Right-To-Know (EPCRA) SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. If listed below, this product contains toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. SARA 313 Components : 2-Butoxyethanol % SARA 311/312 Hazards : Acute Health Hazard Chronic Health Hazard Fire Hazard Toxic Substances Control Act (TSCA) TSCA Status : We certify that all of the components of this product are either listed on the TSCA Inventory or are not subject to the notification requirements per 40 CFR (h). Section 4 / 12(b) : Not applicable Clean Air Act & Related Information Non-volatile (Wt) : % Method: 22 (10min/150 C) DIN EN ISO 3251 Non-volatile information is not a specification. Hazardous Air Pollutants If not listed above, this product does not contain HAPs at 1% or 0.1% or greater. Refer to Section 3 for HAP weight percentage. Resource Conservation and Recovery Act EPA Hazardous Waste Code(s) : Not applicable. State Laws Massachusetts Right To Know Components : 2-Butoxyethanol / 12

11 Pennsylvania Right To Know Components New Jersey Right To Know Components New Jersey Trade Secret Registry Number for the product (NJ TSRN) California Prop. 65 Components : 2-Butoxyethanol Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) Siloxane - Polyglycol - : 2-Butoxyethanol Oxirane, Me, polymer with oxirane monobutyl ether (polyalkylene glycol) Siloxane - Polyglycol - : : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Does not contain heavy metals (according to formulation) except CONEG Heavy Metal: We certify that this product does not contain Lead, Mercury, Cadmium or hexavalent chromium in the sum concentration of 100 ppm by weight or greater. Canadian Environmental Protection Act Domestic Substances List DSL Status : We certify that all of the components of this product are listed on the DSL. WHMIS Classification : B3 D1A D2A D2B SECTION 16. OTHER INFORMATION Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the 11 / 12

12 specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 12 / 12