Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Preparation Date: 22-Jul-2010 Revision Date: 28-Jun-2017 Revision Number: 4 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name Item#: Recommended use Supplier Emergency Telephone Number CAN6108 Laundry Detergent DeLaval Inc. 150-B Jameson Drive Peterborough, Ontario, K9J 0B9 Tel: (705) (613) (Canutec) 2. HAZARDS IDENTIFICATION Emergency Overview Irritating to skin May cause sensitization by skin contact Irritating to eyes Potential Health Effects Principal Routes of Exposure Major effects of exposure Eyes Skin Ingestion Inhalation Eye contact Skin contact Inhalation Ingestion Causes serious eye damage. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May be harmful if swallowed. May cause irritation of respiratory tract. Avoid repeated exposure Potential Environmental Effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 12 for additional Ecological information. Page 1 / 6

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight % carbonate D-Limonene dodecylbenzenesulfonate tripolyphosphate anhydrous metasilicate Alcohols, C9-11, ethoxylated poly(oxy-1,2-ethanediyl),alpha-undecyl-ome ga-hydroxy FIRST AID MEASURES Eye contact Skin contact Ingestion Inhalation Protection of First-aiders In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Rinse mouth. Do not induce vomiting. Call a physician or Poison Control Centre immediately. Move to fresh air. If symptoms persist, call a physician. Use personal protective equipment. 5. FIRE-FIGHTING MEASURES Fire Hazard Suitable Extinguishing Media Hazardous Combustion Products Specific hazards arising from the chemical Protective Equipment and Precautions for Firefighters No information available. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment: Water, Water spray, Carbon dioxide (CO2), Dry powder, Foam. No information available Heating or fire can release toxic gas. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health hazards 1 Flammability 0 Instability 0 Page 2 / 6

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental Precautions Methods for cleaning up Use personal protective equipment. Avoid contact with the skin and the eyes. Avoid dust formation. Material can create slippery conditions. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Do not flush into surface water or sanitary sewer system. Sweep up and shovel into suitable containers for disposal. Soak up with inert absorbent material. Pick up and transfer to properly labelled containers. After cleaning, flush away traces with water. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Handling Storage Incompatible Materials Ensure adequate ventilation. Wear personal protective equipment. Remove and wash contaminated clothing before re-use. Avoid contact with skin and eyes. Keep container tightly closed. Keep container tightly closed in a dry and well-ventilated place. Keep in a bunded area. Keep containers tightly closed in a cool, well-ventilated place. Keep away from possible contact with incompatible substances. Acids, strong oxidizing agents, light metals (e.g. aluminum, copper, brass, zinc galvanized). 8. EPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls Personal Protective Equipment Eye/face Protection Skin Protection Respiratory Protection Ensure adequate ventilation, especially in confined areas. None under normal use. Safety glasses with side-shields, Goggles. Wear protective gloves/clothing. No special protective equipment required. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Page 3 / 6

4 Appearance White Physical state Powder Odor Orange peel Specific Gravity 1 ph 10.5 Freezing Point/Range Not applicable Flash Point Not applicable Boiling Point/Range Not applicable Water Solubility completely soluble 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Chemical Stability Incompatible Materials Hazardous decomposition products Possibility of hazardous reactions Stable under recommended storage conditions. Acids, strong oxidizing agents, light metals (e.g. aluminum, copper, brass, zinc galvanized). Thermal decomposition can lead to release of irritating gases and vapours. Stable under recommended storage conditions. 11. TOICOLOGICAL INFORMATION Chemical name LD50 Oral LD50 Dermal LC50 Inhalation carbonate = 4090 mg/kg ( Rat ) = 2300 mg/m 3 ( Rat ) 2 h D-Limonene = 4400 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) dodecylbenzenesulfonate = 500 mg/kg ( Rat ) = 438 mg/kg ( Rat ) tripolyphosphate = 3100 mg/kg ( Rat ) > 7940 mg/kg ( Rabbit ) anhydrous metasilicate = 600 mg/kg ( Rat ) Alcohols, C9-11, ethoxylated = 1400 mg/kg ( Rat ) = 1378 > 2 g/kg ( Rabbit ) mg/kg ( Rat ) Chronic Toxicity Carcinogenicity Chemical name ACGIH IARC NTP OSHA D-Limonene Group 3 IARC (International Agency for Research on Cancer) Group 3 - Not classifiable Page 4 / 6

5 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Chemical name carbonate D-Limonene dodecylbenzenesulfonate Algae/aquatic plants 242: 120 h 300: 96 h Nitzschia mg/l Lepomis EC50 macrochirus mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 static LC50 = 33mg/kg (96h) 10.8: 96 h Oncorhynchus mykiss mg/l LC50 static Fish Microtox Waterflea 265: 48 h Daphnia magna mg/l EC50 tripolyphosphate anhydrous 1650: 48 h Leuciscus idus mg/l LC50 metasilicate EC50= 207 mg/l LC50= 210mg/l 216: 96 h Daphnia magna mg/l EC50 Persistence and degradability Expected to be biodegradable. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Contaminated Packaging Dispose of in accordance with local regulations. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION TDG Not regulated Page 5 / 6

6 15. REGULATORY INFORMATION All of the components in the product are on the following Inventory lists: No information available, China (IECSC), Philippines (PICCS). Chemical name DSL NDSL TSCA EINECS ELINCS ENCS CHINA KECL PICCS AICS carbonate KE D-Limonene KE dodecylbenzenesulf onate KE tripolyphosphate anhydrous metasilicate Alcohols, C9-11, ethoxylated WHMIS Hazard Class D2A Very toxic materials KE KE KE This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Preparation Date: Revision Date: 22-Jul Jul-2017 Revision Note: No information available Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. Page 6 / 6