Phase Diagrams. A general overview
|
|
|
- Alan Daniels
- 5 years ago
- Views:
Transcription
1 Phase Diagrams A general overview Klaus Hack GTT-Technologies Hume Rothery Seminar Derby, Jan. 17th 2017
2 Contents Practical use of Phase Diagrams Binary Systems Ternary Systems Family of Phase Diagrams Multi-component isopleth sections Zero Phase Fraction lines Phase Diagrams with additional info
3 Practical cases of phase diagram applications
4 Precipitation Hardening in Noble Metal Alloy Systems dental prosthesis based on noble metal alloys gold band bridge (Etruscan) ca. 400 bc modern dental prosthesis with ceramics coating mechanical properties are crucial for the application of noble metal alloys as dental prosthesis
5 Precipitation Hardening in Noble Metal Alloy Systems Alloy compositions and Vickers hardness Au Pd Pt Ag Sn Ir Härte (HV) 81, , , , ,2 13,5 4-2,1 0,2 180
6 Precipitation Hardening in Noble Metal Alloy Systems micro graph for alloy 1: phase diagram near for alloy 1:
7 Precipitation Hardening in Noble Metal Alloy Systems micro graph for alloy 2: phase diagram near for alloy 2:
8 Reduction of Refractory Wear
9 Reduction of Refractory Wear
10 Reduction of Refractory Wear
11 Unary System
12 Example: Fe
13 Binary System
14 Example: Pb-Sn Liquid FCC_a1 FCC_a1 + Liquid Liquid + BCT_a5 BCT_a5 FCC_a1 + BCT_a5
15 Example: Pb-Sn Liquid FCC_a1 BCT_a5
16 Example: Pb-Sn
17 Example: Pb-Sn
18 T(K) GTT-Technologies Example: Pb-Sn (1-x) Pb + x Sn Phase composition LIQUID FCC_a1 400 BCT_a mole fract. Sn
19 Example: Pb-Sn
![T / [K] GTT-Technologies A more complex case: Fe-Ni 1800 BCC_A2 LIQUID 1500 1200 FCC_A1](/docs-images/82/86554217/images/20-2.jpg "900 T C BCC_A2 600 L12_FCC 300 0.2.4.6.8 1 molefraction Ni Chemical and magnetic ordering!")
20 T / [K] GTT-Technologies A more complex case: Fe-Ni 1800 BCC_A2 LIQUID FCC_A1 900 T C BCC_A2 600 L12_FCC molefraction Ni Chemical and magnetic ordering!
21 Printed Compilations Early compilations by M. Hansen, R.P. Elliott, F.A. Shunk, W.G. Moffat Succeeded by Massalski
22 Ternary System
23 Example: Fe-Co-Cr (isotherm)
24 Example: Fe-Co-Cr (isotherm)
25 Example: Fe-Co-Cr (isotherm)
26 Printed Compilations SGTE Landolt- Börnstein Volumes
27 Family of Phase Diagrams
28 N-Component System (A-B-C- -N) q i U i qi q j Extensive variables S V n A n B n N T -P µ A µ B µ N Corresponding potentials Gibbs-Duhem: du TdS PdV dn dq i i i i SdT VdP n d q d 0 i i i i Copyright by GTT 2016
29 Only three types of phase diagrams - Type 1 or Potential Diagrams: Two potentials, Φ i vs Φ j. - Type 2 or Mixed Diagrams: One potential and one ratio of conjugate extensive properties, Φ i vs Q Φ j/q Φ k. - Type 3 or Extensive Property Diagrams: Two ratios of conjugate extensive properties, Q Φ i/q Φ k vs Q Φ j/q Φ k Copyright by GTT 2016
30 Interrelationship of corresponding type 1, type 2, type 3 phase diagrams. (Φ 4, Φ 5,... are held constant; Φ 3 is unspecified) Pelton and Schmalzried, 1973 Copyright by GTT 2016
31 Type 3 Type 2 Type 2 Type 1 Phase diagram family for the binary system Fe-C, P=const. Copyright by GTT 2016
32 Isopleth sections and Zero Phase Fraction lines Copyright by GTT 2016
33 How to handle such a diagram?, rest Fe The method of Zero Phase Fraction lines John Morall et al., since 1984 Copyright by GTT 2016
34 A simple ternary with three terminal solutions A C B Copyright by GTT 2016
35 including tie-lines A C B Copyright by GTT 2016
36 including 10%-lines A C B Copyright by GTT 2016
37 showing zero-phase fraction lines A C B Copyright by GTT 2016
38 Some generalisations The inside-outside feature The crossover feature Copyright by GTT 2016
39 More generalisations The number of phases feature n n + 1 n + 1 n + 2 NOTE: n must NOT be ZERO! Copyright by GTT 2016
40 ZPF-lines are a set of phase boundaries, that mark the appearance of the same phase Copyright by GTT 2016
41 ZPF-lines start and end on coordinate axes or else form a closed loop Copyright by GTT 2016
42 Phase Diagrams with additional information Copyright by GTT 2016
43 T(C) GTT-Technologies The Fe-C diagram Fe - C 1 atm, C(s) iso-activities Liquid BCC_A Liquid + C_Graphit FCC_A FCC_A1 + C_Graphit BCC_A BCC_A2 + C_Graphit C/(Fe+C) (mol/mol)
44 Hematite T(C) GTT-Technologies The Fe-O diagram Fe - O 1 atm, O2(g) isobars (atm) e-9 1e-8 1e-7 1e-10 1e-6 liq metal + liq slag BCC_a2 + liq slag FCC_a1 + Wustite 1e e-3 1e-5 1e-6 1e e e-8 1e-6 1e-2 1e-9 1e-3 1e-5 1e e-15 1e-20 BCC_a2 + Wustite 1e-20 1e-15 1e-25 1e BCC_a2 + Magnetite O/(Fe+O) (mol/mol)
45 Summary Phase diagrams are of technological importance, both in materials development and application Public sources of Phase Diagrams provide information on binary and ternary systems CALPHAD type calculations are not restricted in no. of components but require new method of reading ZPF lines Isobars or isoactivity lines can be added
The Phase Diagram module
The module Use the module to generate various types of phase diagrams for systems containing stoichiometric phases as well as solution phases, and any number of system components. The module accesses the
ADAMIS. Alloy Database for Micro-Solders. Ag Al Sn. ADAMIS Solder. Materials Design Technology Co.,Ltd. 2-5 Odenmacho, Nihonbashi, Chuo-ku
ADAMIS Alloy Database for Micro-Solders Zn Ag Al Sn Sb ADAMIS Solder Au Bi Pb Ni In Cu Materials Design Technology Co.,Ltd. 2-5 Odenmacho, Nihonbashi, Chuo-ku Tokyo 103-0011 JAPAN Copyright Materials Design
State of the thermodynamic database for the BOFdePhos project
State of the thermodynamic database for the BOFdePhos project K. Hack, T. Jantzen, GTT-Technologies, Herzogenrath GTT Users Meeting, July 2015, Herzogenrath Contents Old LD converter model database Necessary
Phase Diagrams. Phases
Phase Diagrams Reading: Callister Ch. 10 What is a phase? What is the equilibrium i state t when different elements are mixed? What phase diagrams tell us. How phases evolve with temperature and composition
Addition of TiO 2 to the HotVeGas Oxide database
Addition of TiO 2 to the HotVeGas Oxide database, Herzogenrath GTT Users Meeting, 28.06-30.06.2017 Herzogenrath Tatjana Jantzen, Klaus Hack Contents of presentation Introduction Binary systems Solid solution
Chapter 10. Phase Diagrams
Chapter 10 Phase Diagrams Chapter 10 Terminology and Unary System Phase Diagrams Issues to Address... When we combine two elements... what equilibrium state do we get? In particular, if we specify... --a
Thermodynamic Reassessment of the Cu-Ni-Sn System. Adela Zemanova, Ales Kroupa
Thermodynamic Reassessment of the Cu-Ni-Sn System Adela Zemanova, Ales Kroupa Institute of Physics of Materials, AS CR, Brno, Czech Republic Outline of the talk Introduction Unification of models Examples
Phase Transformation in Materials
2015 Fall Phase Transformation in Materials 09. 23. 2015 Eun Soo Park Office: 33-313 Telephone: 880-7221 Email: espark@snu.ac.kr Office hours: by an appointment 1 - Equilibrium in Heterogeneous Systems
PHASE DIAGRAMS UNDERSTANDING BASICS THE. Edited. F.C. Campbell. Materials Park, Ohio The Materials Information Society.
PHASE DIAGRAMS UNDERSTANDING THE BASICS Edited by F.C. Campbell The Materials Information Society ASM International Materials Park, Ohio 44073-0002 www.asm i nternational.org Phase Diagrams Understanding
Addition of MeS and MnO x to the GTT Oxide database
Addition of MeS and MnO x to the GTT Oxide database GTT-Workshop, 3-5. Juli 2013, Herzogenrath Klaus Hack, Tatjana Jantzen Contents of presentation Introduction Addition of MeS Addition of MnO x Conclusions
[CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK]
![[CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK]](/thumbs/79/79522651.jpg "[CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK] [CLICK]")
A major principle of materials science is that PROPERTIES are related to STRUCTURE. A material s structure is only partly described by reporting the composition. You must also report the phases, composition
Addition of ZnO to the HotVeGas Oxide database
Addition of ZnO to the HotVeGas Oxide database GTT-Workshop, 1-3. Juli 2015, Herzogenrath Klaus Hack, Tatjana Jantzen Contents of presentation Introduction Solid solution phases Ternary systems Conclusions
The Stabilities of phase
The Stabilities of phase What is a phase? A phase is a form of matter that is uniform throughout in chemical composition and physical state Example Fig 1. White phosphorus Fig 2.Black phosphorus Fig 3.
Solidification: basics and beyond Equilibrium and nonequilibrium solidification
Solidification: basics and beyond Equilibrium and nonequilibrium solidification Prof. Dmitry Eskin BCAST NETCENG, 2015 1 Types of solidification reactions Equilibrium solidification 2 Gibbs phase rule
315: Phase Equilibria and Diffusion in Materials
315: Phase Equilibria and Diffusion in Materials Professor Thomas O. Mason October 4, 2017 Contents Contents 1 1 Catalog Description 2 2 Course Outcomes 3 3 315: Phase Equilibria and Diffusion in Materials
Introduction to the phase diagram Uses and limitations of phase diagrams Classification of phase diagrams Construction of phase diagrams
Prof. A.K.M.B. Rashid Department of MME BUET, Dhaka Concept of alloying Classification of alloys Introduction to the phase diagram Uses and limitations of phase diagrams Classification of phase diagrams
COMPUTED PHASE EQUILIBRIA IN IRON-BASE TERNARY ALLOYS
COMPUTED PHASE EQUILIBRIA IN IRON-BASE TERNARY ALLOYS by K.C. HARI KUMAR APPLIED MECHANICS DEPARTMENT Thesis submitted in fulfilment of the requirements of the Degree of DOCTOR OF PHILOSOPHY be vt, to
Chapter 11: Phase Diagrams
Chapter 11: Phase Diagrams ISSUES TO ADDRESS... When we combine two elements... what is the resulting equilibrium state? In particular, if we specify... -- the composition (e.g., wt% Cu - wt% Ni), and
FactSage Past, Present and Future. Christopher W. Bale
actsage Past, Present and uture Christopher W. Bale CRCT Centre for Research in Computational Thermochemistry, Dept. of Chemical Engineering, École Polytechnique de Montréal - presented at the TMS Annual
The Boundary Theory of Phase Diagrams and Its Application
Muyu Zhao Lizhu Song Xiaobao Fan The Boundary Theory of Phase Diagrams and Its Application Rules for Phase Diagram Construction with Phase Regions and Their Boundaries Muyu Zhao Lizhu Song Xiaobao Fan
Chapter 9: Phase Diagrams
Chapter 9: Phase Diagrams When we combine two elements... what equilibrium state do we get? In particular, if we specify... --a composition (e.g., wt% Cu - wt% Ni), and --a temperature (T ) then... How
Phase diagrams wt% of carbon in Fe microstructure of a lead tin alloy of eutectic composition
Phase diagrams 0.44 wt% of carbon in Fe microstructure of a lead tin alloy of eutectic composition Primer Materials For Science Teaching Spring 2018 28.6.2018 What is a phase? A phase may be defined as
Gibbs Phase Rule. 1 phase field: F = = 2 Change T and C independently in phase field
P + F = C + 2 Gibbs Phase Rule P: # of phases F: Degrees of freedom C: # of components Normally, pressure = 1 atm P + F = C + 1 or F = C - P + 1 Apply to eutectic phase diagram 1 phase field: F = 2 1 +
Thermodynamics and Phase Diagram of the Ni-Sb-Sn System
Thermodynamics and Phase Diagram of the Ni-Sb-Sn System Ratikanta Mishra & Herbert Ipser Department of Inorganic Chemistry / Materials Chemistry, University of Vienna, Austria Traditional Solder Materials
Cu-Ag phase diagram Brazil s map
Phase Diagrams [9] Cu-Ag phase diagram Brazil s map 1> Some important definitions Component - chemically recognizable species (Fe and C in carbon steel, H2O and NaCl in salted water). A binary alloy contains
Phase Transformation in Materials
2016 Fall Phase Transformation in Materials 09. 28. 2016 Eun Soo Park Office: 33-313 Telephone: 880-7221 Email: espark@snu.ac.kr Office hours: by an appointment 1 Equilibrium in Heterogeneous Systems In
CHAPTER 9: PHASE DIAGRAMS
CHAPTER 9: PHASE DIAGRAMS ISSUES TO ADDRESS... When we combine two elements... what equilibrium state do we get? In particular, if we specify... --a composition (e.g., wt%cu - wt%ni), and --a temperature
Database. Sept , 2014, Aachen, Germany. Thermo-Calc Anwendertreffen
Database Sept. 11-12, 2014, Aachen, Germany Thermo-Calc Anwendertreffen Thermodynamic and kinetic databases New Databases, June 2014 TCAL3 TCMG3 TCSLD2 TCSI1 TCNI7 MOBNI3 TCAL3.0 TCAL3.0 TCAL1.0 2011.05
Two Components System
Two Components System Three independent variables: T, P, compositions In general, constant pressure (fixed parameter). P+F=C+1 Simple Eutectic System The binary eutectic phase diagram explains the chemical
Activities of Cu, Fe and Ni in Cu-Fe-Ni-S mattes
WRIGHT, S., JAHANSHAHI, S. and SUN, S. Activities of Cu, Fe and Ni in Cu-Fe-Ni-S mattes. VII International Conference on Molten Slags Fluxes and Salts, The South African Institute of Mining and Metallurgy,
the Phase Diagrams Today s Topics
MME 291: Lecture 03 Introduction to the Phase Diagrams Prof. A.K.M.B. Rashid Department of MME BUET, Dhaka Today s Topics Concept of alloying Classification of alloys Introduction to the phase diagram
Chapter 13: Properties and Applications of Metals
Chapter 13: Properties and Applications of Metals ISSUES TO ADDRESS... How are metal alloys classified and what are their common applications? What are the microstructure and general characteristics of
in Ni-base superalloys
Prof. Dr. Gerhard Inden Max-Planck-Institut für Eisenforschung Düsseldorf B enrichments at the γ / M23C6 interface in Ni-base superalloys Thermo-Calc Anwendertreffen 8. - 9. September 2011 Experimental
PHASE EQUILIBRIUM P + F = C + 2
PHASE EQUILIBRIUM Component: is either pure metal and/or compound of which an alloy is composed. They refer to the independent chemical species that comprise the system. Solid Solution: It consists of
Phase Relations and Activities in the Fe-Ni-As and Fe-Ni-Sb Systems at 1423 K
Materials Transactions, Vol. 44, No. 12 (2003) pp. 2654 to 2658 #2003 The Japan Institute of Metals Phase Relations and Activities in the -- and --b ystems at 1423 K eandro Voisin*, Mitsuhisa Hino and
Phase Diagrams of Pure Substances Predicts the stable phase as a function of P total and T. Example: water can exist in solid, liquid and vapor
PHASE DIAGRAMS Phase a chemically and structurally homogenous region of a material. Region of uniform physical and chemical characteristics. Phase boundaries separate two distinct phases. A single phase
Atomic Transport & Phase Transformations Lecture 7
Atomic Transport & Phase Transformations Lecture 7 PD Dr. Nikolay Zotov zotov@imw.uni-stuttgart.de Lecture I-7 Outline Limited solubility in the solid state Effect of the maximum temperature of the miscibility
The Science and Engineering of Materials, 4 th ed Donald R. Askeland Pradeep P. Phulé. Chapter 8 Solid Solutions and Phase Equilibrium
The Science and Engineering of Materials, 4 th ed Donald R. Askeland Pradeep P. Phulé Chapter 8 Solid Solutions and Phase Equilibrium Objectives of Chapter 8 The goal of this chapter is to describe the
Marketplaces and Interoperability - Data Creation, Curation and Exploitation. The View of a Software Owner
Marketplaces and Interoperability - Data Creation, Curation and Exploitation The View of a Software Owner 1. Background - Introduction to Thermo-Calc 2. Our Data - Creation - Curation - Exploitation 3.
Curie temperature of nickel. B. Legendre & M. Sghaier. Journal of Thermal Analysis and Calorimetry An International Forum for Thermal Studies
Curie temperature of nickel B. Legendre & M. Sghaier Journal of Thermal Analysis and Calorimetry An International Forum for Thermal Studies ISSN 1388-6150 Volume 105 Number 1 J Therm Anal Calorim (2011)
Phase Diagrams, Solid Solutions, Phase Strengthening, Phase Transformations
Phase Diagrams, Solid Solutions, Phase Strengthening, Phase Transformations Components and Phases Components: The elements or compounds that are mixed initially (Al and Cu). Phases: A phase is a homogenous,
Recent Developments of Software and Databases
Recent Developments of Software and Databases Aachen, Sept 1-2, 2016 Introduction 2015 Introduction 1000 Introduction 64 Introduction 46 Introduction Introduction 35 Outline - What we do About the company
Advanced features of Equilib
Advanced features of Equilib The Equilib module has many advanced features which are described here. Table of Contents Section 1 Table of Contents Section 2 Target Phases [F],[P],[S] Section 2.1 [F] -
D. Jendrzejczyk-Handzlik a. W. Gierlotka a,b. K. Fitzner a
COMPLEX MEASUREMENTS OF Au-Sb-Sn Sn SYSTEM D. Jendrzejczyk-Handzlik a W. Gierlotka a,b K. Fitzner a a AGH University of Science and Technology in Krakow, Faculty of Non-Ferrrous Metals, Mickiewicza Ave
Ternary Phase Diagrams
Phase Diagrams Understanding the Basics F.C. Campbell, editor Copyright 2012 ASM International All rights reserved www.asminternational.org Chapter 10 Ternary Phase Diagrams Ternary systems are those having
Phase separation in (Hf,Ti,Zr)NiSn by DFT/Calphad coupling
Phase separation in (Hf,Ti,Zr)NiSn by DFT/Calphad coupling A. Berche, J.C. Tédenacand P. Jund ICGM, CNRS, UMR 5253 Université de Montpellier 2 Half-Heusler phases (Hf,Ti,Zr)NiSn Among the studied materials
TERNARY PHASE DIAGRAMS
TERNARY PHASE DIAGRAMS An Introduction Guna Selvaduray San Jose State University Credit for Phase Diagram Drawings: Richard Brindos Credit for scanning the phase diagrams: Brenden Croom G. Selvaduray -
CHAPTER 10 PHASE DIAGRAMS PROBLEM SOLUTIONS
CHAPTER 10 PHASE DIAGRAMS PROBLEM SOLUTIONS Solubility Limit 10.1 Consider the sugar water phase diagram of Figure 10.1. (a) How much sugar will dissolve in 1000 g of water at 80 C (176 F)? (b) If the
New Materials from Mathematics Real and Imagined
New Materials from Mathematics Real and Imagined Richard James University of Minnesota Thanks: John Ball, Kaushik Bhattacharya, Jun Cui, Traian Dumitrica, Stefan Müller, Ichiro Takeuchi, Rob Tickle, Manfred
Keywords: Au-Bi-Sb system; phase diagram; DTA; EDX. 1 University of Belgrade, Technical Faculty, VJ 12, Bor, Serbia
Experimental study and thermodynamic calculation of Au-Bi-Sb system phase equilibria Dragan Manasijević 1,a, Duško Minić 2, Dragana Živković 1, Živan Živković 1 1 University of Belgrade, Technical Faculty,
Chapter 10: Phase Diagrams
hapter 10: Phase Diagrams Show figures 10-1 and 10-3, and discuss the difference between a component and a phase. A component is a distinct chemical entity, such as u, Ni, NiO or MgO. A phase is a chemically
Basics of Calphad modelling. Bengt Hallstedt Institute for Materials Applications in Mechanical Engineering, RWTH Aachen University, Aachen, Germany
Basics of Calphad modelling Bengt Hallstedt Institute for Materials Applications in Mechanical Engineering, RWTH Aachen University, Aachen, Germany Contents The Calphad method The SGTE unary (element)
CHAPTER 9: PHASE DIAGRAMS
CHAPTER 9: PHASE DIAGRAMS ISSUES TO ADDRESS... When we combine two elements... what equilibrium state do we get? In particular, if we specify... --a composition (e.g., wt%cu - wt%ni), and --a temperature
Influence of physical-chemical processing and operating environments on. Systems of interest: Ceramics Multi-layer coatings Corrosion Reactor systems
Institute t for Materials Science DGM-Committee Thermodynamics, Kinetics and Phase Relations in Materials Hans Jürgen Seifert (TU Bergakademie Freiberg) Damian M. Cupid A platform for the interdisciplinary
The Intermetallic System
The Intermetallic System Cu-Ni Ni-Sn H. Flandorfer, C. Schmetterer and H. Ipser University of Vienna Department of Inorganic Chemistry / Materials Chemistry Outline Why working on Cu-Ni-Sn Literature information
Thermodynamic Calculation of Interfacial Tension between Liquid Iron Alloys and Molten Slag. Toshihiro Tanaka Osaka University, Japan.
Thermodynamic Calculation of Interfacial Tension between Liquid Iron Alloys and Molten Slag Toshihiro Tanaka Osaka University, Japan. Thermodynamic Databases Surface Properties of of Alloys, Salts Salts
Recent Developments in FactSage Thermochemical Software and Databases
Recent Developments in FactSage Thermochemical Software and Databases Christopher. W. Bale,* E. Bélisle*, P. Chartrand*, S.A. Decterov*, G. Eriksson**, A. Gheribi*, K. Hack**, I.-H. Jung*, J. Melançon*,
Chapter 11: Applications and Processing of Metal Alloys
Chapter 11: Applications and Processing of Metal Alloys ISSUES TO ADDRESS... How are metal alloys classified and what are their common applications? What are some of the common fabrication techniques for
New software for Simulations of Metal-Slag Interactions. ACCESS Workshop/Users-Meeting September 25, 2007 Thermo-Calc Software, Stockholm, Sweden
Computational Thermodynamics and Kinetics New software for Simulations of Metal-Slag Interactions ACCESS Workshop/Users-Meeting September 25, 2007, Stockholm, Sweden http://www.thermocalc.com Phone: +46-8-545
Material Properties and Phase Diagrams
PY2M20 Material Properties and Phase Diagrams ecture 5 P. Stamenov, PhD School of Physics, TCD PY2M20-5 Phase Diagrams - Introduction How much can be done with pure elemental compounds? How many combinations
166 COST 531 Atlas of phase diagrams
166 COST 531 Atlas of phase diagrams Ag Cu Ni system Measurements on the Ag Cu Ni system were first reported by de Cesaris [13deC] who provided a plot of the liquidus surface and some solidus points. The
Chapter 11: Phase Diagrams. Phase Equilibria: Solubility Limit
Temperature ( C) Water ugar 217/1/4 Chapter 11: Phase Diagrams IUE TO ADDRE... When we combine two elements... what is the resulting equilibrium state? In particular, if we specify... -- the composition
27 Co Ni Fe Cu Ag Ru Pd Rh Pt Os Ir 192.
UW VERSIONA CHEM152,Sp11 1A 1 H 1.008 3 Li 6.941 11 Na 22.99 2A 4 Be 9.012 UsefulConstants: R=8.314J/mol.K=0.08206liter.atm/mol.K Avogadro snumber:n a =6.022x10 23 molecules/mol Boltzmann sconstant:k=1.38x10
Fe-Fe 3 C phase diagram is given on the last page of the exam. Multiple choices (2.5 points each):
Materials Science and Engineering Department MSE 200, Exam #3 ID number First letter of your last name: Name: No notes, books, or information stored in calculator memories may be used. Cheating will be
Thermo-Calc Graphical Mode Examples
Thermo-Calc Graphical Mode Examples 1 1 Introduction These examples are for the graphical mode of Thermo-Calc; there is a separate set of examples for the console mode. The examples are stored without
Development of Microstructure in Eutectic Alloys
CHAPTER 10 PHASE DIAGRAMS PROBLEM SOLUTIONS Development of Microstructure in Eutectic Alloys 10.16 Briefly explain why, upon solidification, an alloy of eutectic composition forms a microstructure consisting
Database name: TCS Si-based alloys Database Database acronym: TCSI
TCSI1 - TCS Ultrapure Silicon Database Database name: TCS Si-based alloys Database Database acronym: TCSI Database owner: Thermo-Calc Software AB Database version: 1.2 TCSI is a thermodynamic database
Lecture 3: Solutions: Activities and. Phase Diagrams
Lecture 3: Solutions: Activities and Lecture plan: Phase Diagrams 21-09-2010 Gibbs phase rule vapour composition two-component phase diagrams phase diagrams in material science: microstructures in isomorphous
CHM101 SECOND EXAM 162. Chemistry 101 SECOND Exam (162) Name: Date: 30/4/2017
Chemistry 101 SECOND Exam (162) Name: Date: 30/4/2017 Student no. Section: Useful Information:Gas Constant R= 0.08206 L.atm/K.mol, Specific heat of H 2 O=4.18 J/g. C 1 atm. = 760 mmhg. H 1 He 2 1.000 4
Alloy Design Basics and Advanced
phase distribution (log wt.%) phase distribution (log wt.%) phase distribution (log wt.%) Alloy Design Basics and Advanced Mg-Sn alloy Mg-Sn + Si alloy Mg-Sn + Si + Sb alloy 2.0 -Mg 2.0 -Mg 2.0 -Mg Liquid
of Metal Alloys This is just an extension of the previous chapter Hardenability of Steels: The Jominy Test
Chapter 11 Applications and Processing of Metal Alloys This is just an extension of the previous chapter Hardenability of Steels: The Jominy Test As usual, everything is standardized! After the Jominy
System at 1600 C. Activities in CaO-SiOz-Ci{}x Slag. Ncao,dµcao + Ns;o, dµs;o, + Nc,o dµc,o MOLTEN SLAGS, FLUXES AND SALTS '97 CONFERENCE - 69
oxides containing system for better understanding the thermodynamic behavior of AOD slags. Activities in CaO-SiOz-Ci{}x Slag System at 1600 C 2. CALCULATION METHOD Yanping Xiao and Lauri Holappa Laboratory
Release Notes: Thermo-Calc Software Package Version 2018b
: Thermo-Calc Software Package Version 2018b 2018 Foundation of Computational Thermodynamics: Solna, Sweden Contents Release Notes Software Development Kits (SDKs) 2 TC-Python API 2 New Features: Scheil
but T m (Sn0.62Pb0.38) = 183 C, so this is a common soldering alloy.
T m (Sn) = 232 C, T m (Pb) = 327 C but T m (Sn0.62Pb0.38) = 183 C, so this is a common soldering alloy. T m (Au) = 1064 C, T m (Si) = 2550 C but T m (Au0.97Si0.03) = 363 C, so thin layer of gold is used
Modeling Diffusion: Flux
Modeling Diffusion: Flux Flux (#/area/time): J = 1 A dm dt Directional Quantity y Jy kg atoms m 2 or s m 2 s Jx Jz x z Flux can be measured for: --vacancies and interstitials --host (A) atoms --impurity
Li Mass = 7 amu Melting point C Density 0.53 g/cm 3 Color: silvery
Blackline Master B02: Mendeleev s Element Cards H Mass = 1 amu Melting point -259 0 C Density 0.0909 g/cm 3 Color: colorless Li Mass = 7 amu Melting point 180.5 0 C Density 0.53 g/cm 3 Be Mass = 9 amu
Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Phase Diagram
SE104 Structural Materials Phase Diagram Dr. Yu Qiao Department of Structural Engineering, UCSD Introduction Phase: A region in a material that differs in structure and function from other regions. Phase
STUDY OF ELEMENT FINGERPRINTING IN GOLD DORÉ BY GLOW DISCHARGE MASS SPECTROMETRY
STUDY OF ELEMENT FINGERPRINTING IN GOLD DORÉ BY GLOW DISCHARGE MASS SPECTROMETRY MICHAEL W. HINDS, Ph.D. 1 ELEMENT FINGERPRINTING In 1994, John Whatling* used laser ablation inductively coupled mass spectrometry
Slide 1. Slide 2. Slide 3. Chapter 10: Solid Solutions and Phase Equilibrium. Learning Objectives. Introduction
Slide 1 Chapter 10: Solid Solutions and Phase Equilibrium 10-1 Slide 2 Learning Objectives 1. Phases and the phase diagram 2. Solubility and solid solutions 3. Conditions for unlimited solid solubility
CHAPTER9. Phase Diagrams Equilibrium Microstructural Development
CHAPTER9 Phase Diagrams Equilibrium Microstructural Development The microstructure of a slowly cooled eutectic soft solder ( 38 wt%pb wt % Sn) consists of a lamellar structure of tin-rich solid solution
Introduction to phase diagrams
ASM Phase Diagram Database Diagram No. 901229 Department of Physics and Astronomy Introduction to phase diagrams William Meier Physics 590B Fall 2018 Outline Part 1 Introduction and basics Part 2 Fundamental
Alloys and Solid Solutions
Alloys and Solid Solutions Chemistry 123 Spring 2008 Dr. Woodward Solutions Solid Solution 14 Carat Gold Liquid Solution Vodka Gaseous Solution Air Solution = A homogeneous mixture 1 Alloys An alloy is
26 Phase Diagram For Binary Alloys. Contents 2.1. INTRODUCTION SYSTEM, PHASES, STRUCTURAL CONSTITUENTS AND EQUILIBRIUM...
26 Contents 2.1. INTRODUCTION... 27 2.2. SYSTEM, PHASES, STRUCTURAL CONSTITUENTS AND EQUILIBRIUM... 28 2.3. PHASE DIARGAM... 29 2.4. PHASE RULE (GIBBS RULE)... 31 2.5. TIME-TEMPERATURE COOLING CURVE...
Phase diagrams are diagrammatic representations of the phases present in a
Chapter 4 What is a binary phase diagram? Phase diagrams are diagrammatic representations of the phases present in a system under specified equilibrium conditions, most often composition, temperature and
Lecture 7: Solid State Reactions Phase Diagrams and Mixing
Lecture 7: Solid State Reactions Phase Diagrams and Mixing Prof Ken Durose, Univ of Liverpool Text book for this lecture: Callister Materials Science and Engineering Learning objectives 1.Solid state reactions
COMPUTER SIMULATION OF THE EQUILIBRIUM RELATIONS ASSOCIATED WITH THE PRODUCTION OF MANGANESE FERROALLOYS
COMPUTER SIMULATION OF THE EQUILIBRIUM RELATIONS ASSOCIATED WITH THE PRODUCTION OF MANGANESE FERROALLOYS K. Tang 1 and S. E. Olsen 2 1 SINTEF Material Technology, N-7465 Trondheim, Norway. E-mail: kai.tang@sintef.no
Phase diagrams (cont.) and the Fe-C system
Phase diagrams (cont.) and the Fe-C system Solidification: Pro-eutectic vs Eutectic Pro-eutectic solidification Ideal liquid, uniform distribution Solid Pb(Sn) () nucleates Solubility limit leads to Sn
Thermodynamic Properties of Inorganic Materials
Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W. Martienssen Group IV: Physical Chemistry Volume 19 Thermodynamic Properties of Inorganic
Thermo-Calc Console Mode Examples Guide. Thermo-Calc Version 2018a
Thermo-Calc Console Mode Examples Guide Thermo-Calc Version 2018a About the Thermo-Calc Console Mode Examples There are many examples to examine and to help you learn Thermo-Calc in Console Mode. OPENING
Chapter 9 Phase Diagrams. Dr. Feras Fraige
Chapter 9 Phase Diagrams Dr. Feras Fraige Chapter Outline Definitions and basic concepts Phases and microstructure Binary isomorphous systems (complete solid solubility) Binary eutectic systems (limited
Solid Solutioning in CoCrFeNiMx (M= 4d transition metals) High-Entropy Alloys
Solid Solutioning in CoCrFeNiMx (M= 4d transition metals) High-Entropy Alloys Sheng Guo Department of Industrial and Materials Science Chalmers University of Technology, Gothenburg, Sweden 21 September
Applications of computational thermodynamics using Open Calphad, a free software
Applications of computational thermodynamics using Open Calphad, a free software Bo Sundman, Ursula R Kattner, Mauro Palumbo and Suzana G Fries INSTN CEA Saclay, France; NIST USA; SISSA Trieste, Italy;
Experimental investigation and thermodynamic modelling of ZrO 2 -based systems
Experimental investigation and thermodynamic modelling of ZrO 2 -based systems O.B. Fabrichnaya,G.B. Savinykh, G. Schreiber H.J. Seifert Institute for Materials Science, Technical University of Freiberg,
Modelling of long-term phase stability in Ni-based superalloys based on thermodynamic and kinetic CALPHAD calculations
Modelling of long-term phase stability in Ni-based superalloys based on thermodynamic and kinetic CALPHAD calculations R. Rettig, R. F. Singer Institute of Science and Technology of Metals (WTM) DFG-Research
Chapter 11. Directions of phase boundaries
Selleby and Hillert September 2007 Additional problems to the book Phase Equilibria, Phase Diagrams and Phase Transformation, to be solved with Thermo-Calc Chapter 11. Directions of phase boundaries Problem
Schedule of Accreditation issued by United Kingdom Accreditation Service 2 Pine Trees, Chertsey Lane, Staines-upon-Thames, TW18 3HR, UK
Unit 10 Victory Park Victory Road Derby Derbyshire DE24 8ZF ontact: Mr ndy Harrison Tel: +44 (0)1332 275700 E-Mail: andy.harrison@intertek.com Website: www.ndtservices.co.uk Laboratory locations: below
ENGR 151: Materials of Engineering LECTURE #15: PHASE DIAGRAMS
ENGR 151: Materials of Engineering LECTURE #15: PHASE DIAGRAMS TENSILE TESTING VIDEO https://www.youtube.com/watch?v=-qukvzo2jse PROPERTIES OF ISOMORPHOUS ALLOYS Solid solution strengthening For Ni-Cu
Schedule of Accreditation issued by United Kingdom Accreditation Service 2 Pine Trees, Chertsey Lane, Staines-upon-Thames, TW18 3HR, UK
Unit 10 Victory Park Victory Road Derby Derbyshire DE24 8ZF ontact: Mr G Tomlinson Tel: +44 (0)1332 275700 Fax: +44 (0)1332 275729 E-Mail: graham.tomlinson@ndtservices.co.uk Website: www.ndtservices.co.uk
Technological Aspects of Metal Nanopowders
PHYSICS and CHEMISTRY of NANOMATERIALS, lecture 6 Alexander A. Gromov gromov@tpu.ru Chair of Silicates and Nanomaterials, Faculty of Chemical Technology, Tomsk Polytechnic University, RUSSIA Technological
TERNARY Bi-Cu-Ni ALLOYS THERMODYNAMICS, CHARACTERIZATION, MECHANICAL AND ELECTRICAL PROPERTIES
Metallurgical and Materials Engineering Association of Metallurgical Engineers of Serbia AMES Scientific paper UDC: 661.887.018.5 TERNARY Bi-Cu-Ni ALLOYS THERMODYNAMICS, CHARACTERIZATION, MECHANICAL AND