Ashland Composite Polymers. ENGUARD Bonding Pastes. Joining Composites 1/19

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1 Joining Composites 1/19

2 Content 1. Joining with bonding pastes 2. Bonding Paste Characteristics 3. Types of bonding pastes 4. Application methods 5. Application by market segment 6. Working practices 7. Mechanical Strength 8. Design of joints 9. Safe journey 2/19

3 Joining with Bonding Pastes Bonding pastes and adhesives have many advantages of special interest to the composite industry. They spread loads over large areas unlike bolts, screws and rivets which concentrate loads at small points. ENGUARD bonding pastes are specially designed for different areas in the marine, building / sanitary, tanks & silos and transport industry. 3/19

4 Characteristics 1 Gel Time Time when bonding paste starts to gel. NOTICE: Parts must be joined before bonding paste starts to gel. Hardening time Time when work can continue on part. NOTICE: Final bonding strenght after 72 hours at room temperature or higher. Viscosity From low viscosity, low thixotropy products to high viscosity, high thixotropy products 4/19

5 Characteristics 2 Density Depending on use density of bonding paste variates from 0,7-1,5. Catalyst indicator Indicates by changing color when catalyst is added to bonding paste. Containing glass fiber Some bonding pastes contain glass fiber to give better structural strenght when thicker bond / gap is used. Linear shrinkage Clearly lower than standard resin values 5/19

6 Type of Bonding Pastes Joining Sandwich Bonding Filling Casting 6/19

7 Application Methods 7/19

8 Application by Market Segment 1 Filling (Insert fixation) Joining Sandwich 8/19

9 Application by Market Segment 2 Joining Filling (Insert fixation) Sandwich 9/19

10 Joining of Boat Hull and Deck 10/19

11 Working Practices 1 Make sure that the ENGUARD material is at room temperature before use. 2 Working temperature should be C. 3 Surfaces should be clean, grease-free (sanded if needed) and dry before applying ENGUARD bonding paste. 4 Add 1,0-2,5% MEKP catalyst and mix properly (see individual product data sheet). 5 ENGUARD bonding paste can be used on surfaces such as polyester laminates, polyurethane- and PVC foams, wood and balsa. 6 Adhesion should be tested first on those surfaces which are not mentioned in point 5. 7 Do not use mechanical forces on bonded parts within 3 days. 8 Close up the packaging immediately after use. 11/19

12 Tensile strength (ASTM C297) 1 Bonding pastes were tested according to ASTM C297 standard Five specimen Size 25*25*5 (BoP thick.) Steel jigs Tensile Strength of ENGUARD Bonding pastes is more than12 MPa which clearly exceeds good design practices of composite structures. Adhesive Bondig paste 12/19

13 Tensile strength (ASTM C297) 2 13/19

14 Shear strength (Ashland method) 1 Test specimen Size 25*25 ~5 mm Shear strength of ENGUARD Bonding pastes is more than15 MPa which exceeds good design practices of composite structures. 14/19

15 Shear strength (Ashland method) 2 15/19

16 Compression test Compression values of ENGUARD Bonding pastes exceeds 100 MPa when the test piece is 5 mm. 16/19

17 Joining / Fixing ENGUARD Bonding Paste Stock in ANCE area Spring 2004 Gel MEKP- Catalyst Containing Hardening Typical bond/gap Linear Product Colour Density Viscosity time 50 indicator glass fibers time thickness shrinkage Availability min % hours mm % Marine Building/Sanitary Tanks & Silos Transport TH 06 Neutral 0, ,3-3 <1 POL TH 72 Neutral 1, , ,5 FIN/POL/SWE TH 725 White 1, ,3-3 1,5-2 FIN/SWE TH 730 White 1, ,3-3 1,5-2 FIN/POL TH 75 Neutral 1, ,5 FIN/POL/SWE TH 751 Neutral 1, ,5 SWE TH 80 White 1, < 0,5 FIN TH 90 Neutral 1, ,3-3 < 0,5 POL TH 6000 Neutral 1, ,3-3 1,5-2 FIN/SWE Sandwich core bonding Fillers / Casting Paste TH 72 Neutral 1, , ,5 FIN/POL/SWE TH 75 Neutral 1, ,5 FIN/POL/SWE TH 725 White 1, ,3-3 1,5-2 FIN/SWE TH 751 Neutral 1, ,5 SWE TH 90 Neutral 1, ,3-3 < 0,5 POL TH 76 White 0, ,3-3 1,5-2 FIN TH 06 Neutral 0, ,3-3 <1 POL TH 72 Neutral 1, , ,5 FIN/POL/SWE TH 76 White 0, ,3-3 1,5-2 FIN 1 = low viscosity 2 = low viscosity, low thixotrophy 3 = high viscosity, thixotropy 4 = high viscosity, high thixotropy 17/19

18 Designing Joints Conventional mechanical joining methods such as bolting, riveting and welding are very good at carrying tensile and peel type loads but bonding pastes perform best when loaded in compression and shear. Both joining methods certainly have their advantages and appropriate aplications but those unique to adhesive bonding are good reasons to consider joining with bonding pastes. Do Do Do Do Do compression & shear compression compression & shear compression & shear compression & others Don t Don t Don t Don t Don t peel tension & shear tension peel, tension & shear tension & shear tension & others 18/19

19 Safe Journey! 19/19

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