Revised edition: 17.02.2016 1. 1. 1. Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Mica Graphite 1. 2. Article No.: 53250 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: 2. 3. Hazardous components for labelling: Other Hazards Composition/Information on Ingredients 2
3. 3. 1. Substance 3. 2. Mixture Page 2 Chemical Characterization: Natural graphite, CAS No. 999999-99-4 (natural occuring substance) 4. 4. 1. Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Exempted from the mandatory REACH Registration (Annex V No. 7) Seek medical attention in case of complaints. Supply fresh air. Consult physician if symptoms persist. Give artificial respiration in case breathing is not regular or if it has stopped. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Drink plenty of water. Get medical help in case of discomfort. Symptoms: No further information available. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Foam, carbon dioxide (CO2), water, dry sand. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. Special hazards: In case of fire: formation of carbon monoxide and dioxide. 5. 3. Advice for Firefighters 3
Protective equipment: Page 3 Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up No special measures required. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Clean up mechanically. Avoid dust formation. For information for safe handling see Section 7. Avoid formation of dust. Do not inhale dust. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not inhale dust. Wash hands before breaks and at the end of work. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a dry and cool room. Protect against heat and direct sunlight. No special measures necessary. Do not store together with: oxidants, halogenated compounds, fluorine, potassium and potassium oxide. Storage class (VCI): 7. 3. 8. 8. 1. Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled General dust limit Parameters to be controlled (DE): 4
Parameters to be controlled: Page 4 Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Personal Protection General protective measures: Respiratory protection: Hand protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Dust mask recommended when very dusty (with particle filter P1). Not required Protective glove material: Eye protection: Body protection: Recommended in case of extreme dust formation (EN 166). No special protection required. 9. 9. 1. Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: solid Color: gray, black Odor: odorless Odor threshold: No information available. ph-value: Melting temperature: not determined Boiling temperature: Flash point: not flammable Evaporation rate: 5
Flammability (solid, gas): Page 5 Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: no information available no information available No information available. not available insoluble no information available not determined No data available. not explosive no information available 9. 2. Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: No further information. 10. Stability and Reactivity 10.1. Reactivity Stable if used according to specifications. 6
10.2. 10.3. 10.4. Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Stable if used according to specifications. Page 6 None if handled and stored according to specifications. 10.5. 10.6. 10.7. 11. 11. 1. Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Avoid direct sunlight and heat. None known. In the event of fire: see chapter 5. No toxicity expected. No irritant effect known. No irritant effect known. No irritant effect known. No irritant effect known. No sensitizing effects known. No data available. No data available. This product is not considered to be a carcinogen by IARC,ACGIH, NTP or OSHA. Teratogenicity: No information available. 7
Specific target organ toxicity (STOT): No data available. Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. 13. 1. 14. 14. 1. 14. 2. Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name Crystalline natrual graphite is a chemically inert product, with no impact on the environment. No information available. The product is not hazardous to the aquatic system. Product is not water soluble. Not applicable. Not hazardous. Dispose of according to official national and local regulations. Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. ADR/RID: No hazardous goods according to ADR (land transportation). 8
IMDG/IATA: No hazardous goods according to IMDG. 14. 3. Transport Hazard Classes Page 8 ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: 14. 4. Hazard no.: Packaging Group ADR/RID: IMDG: 14. 5. 14. 6. 14. 7. 14. 8. 15. 15. 1. IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous 15. 2. 15. 3. 16. Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Exempted from the mandatory REACH Registration (Annex V No. 7) This product should be stored, handled and used in accordance 9
Page 9 with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.