Revised edition: 18.02.2016 1. 1. 1. Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Triton X-100 Page 1 1. 2. Article No.: 78030 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Laboratory chemical 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H302 Cat.: 4 H318 Cat.: 1 H411 Cat.: 2 Classification according to EC Regulation No. 67/548 or No. 1999/45 Harmful (Xn) R22 Irritating (Xi) R41 Acute toxicity (oral), hazard category 4 Serious eye damage, hazard category 1 Chronic aquatic toxicity, category 2 Harmful if swallowed. Causes serious eye damage. Toxic to aquatic life with long lasting effects. Harmful if swallowed. Risk of serious damage to eyes. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: 2
Page 2 GHS05-2 GHS07 GHS09 Signal word: Hazard designation: Safety designation: H302 H318 H411 P264 P273 P280 P301+P312 P305+P351+P338 P310 Danger Harmful if swallowed. Causes serious eye damage. Toxic to aquatic life with long lasting effects. Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves/ clothing/ eye/ face protection. If swallowed: Call a poison center or physician if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. Immediately call a poison center or physician. 2. 3. 3. 3. 1. 3. 2. Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Hazardous Ingredients: Triton X 100 CAS-Nr: 9002-93-1 EINECS-Nr: EC-Nr: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: Intoxication symptoms may occur after several hours, therefore a 48 hour medical observation is necessary. Immediately get medical help. After inhalation: 3
Supply fresh air. Consult physician if symptoms persist. Page 3 After skin contact: After eye contact: Consult a physician immediately. Remove contaminated clothing immediately. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Immediately get medical help. Symptoms: No further information available. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Use extinguishing media for surrounding fire. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. 5. 3. Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of carbon monoxide and dioxide. Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Contaminated extinguishing water and debris should be disposed of according to local regulations. Reduce escaping fumes with water. 6. 2. Personal precautions: Environmental Precautions Avoid contact with skin, eyes and clothing. Environmental precautions: Prevent contamination of soils, drains and surface water. 4
6. 3. Methods and Material for Containment and Cleaning Up Page 4 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (e.g. Chemizorb ) and dispose accordingly. Clean remains. For information for safe handling see Section 7. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. No special measures required. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Take off contaminated clothing immediately. 7. 3. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Further Information: Specific End Use(s) Keep product shut away or kept in a manner so as to ensure that only qualified persons may have access. Container must be opened under a local exhaust system. Keep container tightly closed. Product is not combustible. 10-13 Storage temperature: 15-25 C 8. 8. 1. Further information: Exposure Controls/Personal Protection Parameters to be Controlled None known Parameters to be controlled (DE): Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: 8. 2. Exposure Controls 5
Technical protective measures: Personal Protection Provide adequate ventilation/exhaust system. Page 5 General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Avoid contact with eyes. Not required. Protective gloves (EN 374) Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. The glove material must be sufficiently impermeable and resistant against the product. Tightly fitting safety goggles (EN 166). Protective clothing. 9. 9. 1. Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent from getting into the soil, surface water and sewage system. Form: Color: Odor: Odor threshold: ph-value: Melting temperature: liquid yellowish weak, characteristic 6-8 (10 g/l; 20 C) not determined Boiling temperature: 200 C Flash point: 251 C Evaporation rate: Flammability (solid, gas): not applicable Upper explosion limit: not determined 6
Lower explosion limit: not determined Page 6 Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: 0.01 hpa 1.07 g/cm3 (20 C) completely miscible no information available not applicable No data available. not determined Product does not present an explosion hazard. no information available 9. 2. Bulk density: Further Information 10. 10.1. 10.2. 10.3. 10.4. Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: No further information. Stable if used according to specifications. Stable if used according to specifications. Unknown. No further information available. 7
Thermal decomposition: 10.5. Imcompatible Materials None known. 10.6. Hazardous Decomposition Products None known. 10.7. Further Information 11. Toxicological Information 11. 1. Information on Toxicological Effects Page 7 Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: 1900-5000 mg/kg (rat) > 3000 mg/kg (rabbit) Primary effects 12. 12. 1. Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity No information available Causes serious eye damage. No irritant effect known. No information available No sensitizing effects known. No mutagenic effects known. No data available. No data available. Single exposure: no information available. Repeated exposure: no information available. Aspiration hazard: not applicable Fish toxicity: 8
LC50: 4-8.9 mg/l (96h, fish) Page 8 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. 13. 1. 14. 14. 1. 14. 2. Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name EC50: 18-26 mg/l (Aquatic Invertebrata) No data available. Not applicable. 2 (German Regulation) (Assessment by list): hazardous. Danger to drinking water even if small quantities leak into the ground. Do not let product enter waterways or sewage system. Dispose of according to official national and local regulations. Do not let product enter water systems. Must not be disposed together with household garbage. Dispose of according to official local regulations. Suggested cleaning agent: water. Detergent can be added if necessary. ADR/RID: 9
Page 9 No hazardous goods according to ADR (land transportation). 14. 3. 14. 4. IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to IMDG. not applicable not applicable not applicable 14. 5. 14. 6. 14. 7. 14. 8. 15. 15. 1. IATA: Environmental Hazards Environmentally hazardous substance, liquid; Marine Pollutant Special Precautions for User none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 2, hazardous for water 15. 2. Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment EC SVHC-List (REACH Regulation (EC) 1907/2006, Article 57): Triton X 100 (CAS No. 9002-93-1) A Chemical Safety Assessment has not been carried out for this product. 10
15. 3. 16. Further Information Other Information Page 10 Directive 2012/18/EU (Seveso III): product is not listed (Appendix I) Seveso Category E2: Hazardous to the aquatic environment This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.