Revised edition: 23.06.2015 1. 1. 1. Version: 4.7 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Pearl Luster XIRALLIC Diamond Silver 1. 2. Article No.: 50080 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 Safety Phrases: This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. S22: Do not breathe dust. 2. 2. Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Signal word: Hazard designation: Safety designation: P260a Do not breathe dust. 2
Page 2 Hazardous components for labelling: 2. 3. Other Hazards No special hazards known. 3. 3. 1. 3. 2. Composition/Information on Ingredients Substance Mixture Chemical Characterization: Al2O3 laminated with titanium dioxide, tin oxide and additives. Hazardous Ingredients: Tin oxide (Xi; R37) 1-10 % CAS-Nr: 18282-10-5 EINECS-Nr: 242-159-0 EC-Nr: Additional information: 4. 4. 1. First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: After ingestion: Take affected persons out into the fresh air. Supply fresh air. Consult physician if symptoms persist. Wash off with water. Rinse eyes with water. Drink plenty of water. Get medical help in case of discomfort. 4. 2. Most important Symptoms and Effects, both Acute and Delayed Symptoms: Effects: No further information available. No further information available. 4. 3. Indication of any Immediate Medical Attention and special Treatment needed Treatment: 5. 5. 1. Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Unsuitable extinguishing media: Use extinguishing media for surrounding fire. None known. 5. 2. Special Hazards arising from the Substance or Mixture Special hazards: 3
5. 3. Advice for Firefighters Page 3 In case of fire: hazardous vapors may be released. Protective equipment: Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Do not inhale dust. Evacuate the danger area, observe emergency procedures, consult an expert. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable container for disposal. Rinse spill area. Avoid dust formation. Dispose of contaminated material according to Section 13. Avoid formation of dust. Do not inhale dust. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities No further measures, see Section 8. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry room. No special measures necessary. No special measures necessary. 10-13 7. 3. Further Information: Specific End Use(s) Further information: See Section 1.2.; no other uses provided 4
8. Exposure Controls/Personal Protection 8. 1. Parameters to be Controlled Page 4 Parameters to be controlled (DE): Parameters to be controlled (EC): TRGS 900 TLV: 1.25 mg/m3 air-borne fraction (general dust limit) TLV: 10 mg/m3 inhalable fraction (general dust limit) Peak limit category II (2) Aluminium oxide (CAS 1344-28-1): AGW (TRGS 900): 1.25 mg/m3 (airborne dust), 10 mgl/m3 (inhalable dust); 2(II) Titanium dioxide (CAS 13463-67-7): TLV (TRGS 900): 1.25 mg/m3 (airborne dust), 10 ml/m3 (inhalable dust); 2(II) Category II: substances with a resorptive effect. Tin dioxide (CAS 18282-10-5): TLV (TRGS 900): 2 mg/m3 (inhalable fraction; as Sn) Tin dioxide, CAS 18282-10-5; ECTLV: 2 mg/m3 (Time weighted average; as Sn) Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Technical protective measures have priority to personal protective measures. Personal Protection General protective measures: Respiratory protection: Hand protection: Wash hands before breaks and after work. Dust mask recommended when very dusty (with particle filter P1). Not required Protective glove material: Eye protection: Safety glasses (EN 166) Body protection: 9. 9. 1. Environmental precautions: No special measures required. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: powder Color: silver-gray 5
Odor: odorless Page 5 9. 2. Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information 6-9 (100 g/l H2O, 20 C) not available not available not available no information available no information available 3.8-4.0 g/cm3 (20 C) practically insoluble no information available not available Product is not explosive. 210-250 kg/m3 Solubility in solvents: 6
Viscosity, kinematic Page 6 Burning class: Solvent content: Solid content: Particle size: 5-30 µm 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Stable if used according to specifications. Stable at room temperature. No further information available. None known. No information available Ingestion: 7
No information available Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: No quantitative toxicological data available for this product. Avoid inhalation of dust. Even inert dusts can impair the function of the respiratory system. The contents of the preparation do not comply with the criteria for the classification as PBT or vpvb. Not hazardous. When used properly, no ecological problems expected. AOX Value: 8
13. Disposal Considerations 13. 1. Waste Treatment Methods Page 8 Product: Dispose of according to official national and local regulations. Do not mix with other waste. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. 14. 4. 14. 5. 14. 6. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. None Not classified as a dangerous good under transport regulations. 9
Page 9 14. 7. 14. 8. 15. 15. 1. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous 15. 2. 15. 3. 16. Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. EC SVHC-List: This product does not contain a substance in the candidate list for substances of very high concern above the legal limit value (> 0.1 % (w/w) REACH Regulation (EC) 1907/2006, Article 57). Regulation (EC) 1005/2009 - Substances that Deplete the Ozone Layer: not regulated / Regulation (EC) 850/2004 - Persistent organic pollutants and amending Directive 79/117/EEC: not regulated Regulation (EC) 689/2008 concerning the export and import of dangerous chemicals: not regulated This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.