LIFE CYCLE ASSESSMENT OF A BIOREACTOR AND AN ENGINEERED LANDFILL FOR MUNICIPAL SOLID WASTE TREATMENT

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LIFE CYCLE ASSESSMENT OF A BIOREACTOR AND AN ENGINEERED LANDFILL FOR MUNICIPAL SOLID WASTE TREATMENT Waste Management 2003 Jean-François Ménard, Renée Michaud, Julie-Anne Chayer, Pascal Lesage, Louise Deschênes, Réjean Samson September 2003 InLCA-LCM 2003 - Seattle

Context! Landfilling is the most common means of disposal for Municipal Solid Waste (MSW) in Canada.! Today, landfilling is done in engineered landfills equipped with leachate and landfill gas collection and treatment systems.! However, this technique presents some shortcomings since it:! Requires a large area;! Generates emissions over several years (possibly more than a century).! A new landfill technology, the bioreactor, addresses these problems by accelerating the degradation of the organic fraction. This reduces the time necessary to stabilize the landfilled waste and increase the site s capacity.

Presentation outline 1. Goal & scope 2. Life Cycle Inventory (LCI) 3. Life Cycle Impact Assessment (LCIA) 4. Conclusions

1- Goal & scope Goal: To evaluate, using an LCA, the potential environmental impacts associated with two types of landfills used for MSW: " The engineered landfill (EL); " The bioreactor.

1- Goal & scope Function: BUT To stabilize an amount of MSW Landfill gas can be collected and used to produce energy (electricity or heat) in the case of the bioreactor. This production must be added to the primary function so as to maintain the functional equivalence of the compared systems.

1- Goal & scope Functional unit: The stabilization of 600 000 tonnes of MSW and the production of 2.56 x 10 8 MJ of electricity and 7.81 x 10 8 MJ of heat. These amounts correspond to: " The landfilling of 300 000 tonnes of MSW per year over 2 years; " The maximum amount of energy that can be recuperated from the landfill gas generated by the bioreactor.

1- Goal & scope System boundaries and life cycle stages

2- LCI System description Bottom liner Leachate collection Leachate treatment EL Aeration pond Release in receiving body of water Geosynthetic clay liner (GCL) Geomembrane Geonet Geotextile Gravel drainage bed HDPE pipes Bioreactor Recirculation in horizontal trenches Landfill gas collection Vertical wells Horizontal trenches Landfill gas treatment Final cover layer Supplementary energy production Flare Sand Geomembrane Organic soil Natural gas electrical power station Natural gas industrial boiler Internal combustion engine (ICE) Modified boiler

2- LCI Main assumptions! Waste density in cell: 800 kg/m 3 for the EL; 1000 kg/m 3 for the Bioreactor.! Post-closure monitoring period = 30 years.! Landfill gas production = fraction of Biochemical Methane Potential (BMP) which varies from: 40 to 70% of the BMP for the EL; 60 to 90% of the BMP for the Bioreactor.! CO 2 from the waste = biogenic not counted as greenhouse gas.! Residual fraction of BMP converted into an environmental credit (CO 2 sequestered in the landfilled waste).! Bioreactor: waste brought to field capacity at closure.! Temporal boundary corresponds to waste stabilization time to produce 95% of calculated landfill gas volume.

2- LCI Main assumptions Temporal boundary 5E+7 Temporal boundary - Bioreactor Temporal boundary - EL 4E+7 3E+7 2E+7 1E+7 Landfill gas production [m3] 0E+0 0 10 20 30 40 50 60 Time [years] 70 80 90 100 Closure End of post-closure monitoring period

2- LCI Main assumptions Leachate Precipitations (m/m 2 /year) EL 1 Bioreactor Evapotranspiration losses (%) Run-off losses (%) From 0 to 1 year From 1 to 2 years After 2 years Final cover efficiency (%) From 0 to 1 year From 1 to 2 years From 2 to 32 years After 32 years Bottom layer efficiency (%) From 0 to 32 years After 32 years Landfill gas Collection system efficiency (%) From 0 to 1 year From 1 to 2 years From 2 to 32 years After 32 years 0 50 80 0 60 5 10 20 0 50 99-0.01 per year 99,99-0.01 per year 0 75 90

2- LCI Excluded processes! Pumps for leachate collection;! Collection and disposal of leachate treatment sludge (EL);! Compressors for landfill gas collection;! Dehydrators and pipeline for treatment and transport of landfill gas (Bioreactor).

2- LCI Data sources Unit process Non-road equipment Truck transport Material production Leachate and landfill gas associated emissions Data source NONROAD model (U.S. EPA/Office of Transportation and Air Quality) Joint EMEP/CORINAIR Atmospheric Emission Inventory Guidebook 3rd edition (EEA, 2001) Commercial generic LCI databases in Simapro 5 software (IDEMAT and Franklin) Life Cycle Inventory of a Modern Municipal Solid Waste Landfill (ECOBALANCE, 2002)! The North-American Franklin database was privileged. The unit processes from the European database were modified so as to better represent the energy production and transport processes.

2- LCI Inventory results Inputs Mass (kg) Geosysnthetic clay liner Geomembrane Geonet Geotextile HDPE pipes PVC pipes Vitrified steel tank Aluminum dome Reinforced concrete base Gravel Bentonite Sand Organic soil Diesel TOTAL Added water Energy (MJ) Equipments Electricity Heat TOTAL Truck transport (tonne.km) EL 2.57E+5 2.23E+5 3.52E+5 2.89E+4 2.65E+5 4.86E+2 6.32E+7 1.58E+4 6.44E+7 1.34E+7 3.13E+5 1.42E+8 2.60E+6 2.56E+8 7.81E+8 1.04E+9 7.26E+6 Bioreactor 2.03E+5 1.82E+5 3.00E+5 2.57E+4 6.04E+4 3.40E+4 1.91E+3 3.00E+5 6.03E+7 5.38E+7 1.12E+7 2.68E+5 1.26E+8 2.73E+8 2.15E+6 1.50E+8 4.55E+8 6.07E+8 6.43E+6

2- LCI Inventory results Elementary flows Emissions to air Total emissions Total emissions w/o biogenic CO 2 Sequestered CO 2 Emissions to water Solid waste Inputs/Outputs (kg) Raw materials (w/o added water) EL 2.20E+8 1.59E+8 1.06E+8-5.96E+7 2.51E+6 4.42E+6 Bioreactor 1.75E+8 1.50E+8 6.15E+7-3.31E+7 1.41E+6 2.44E+6

3- LCIA! EDIP (Environmental Design of Industrial Products) method developed in 1996 by the Danish EPA;! Recognized as one of the best LCIA methods and largely used (Sorensen, 2002);! Follows SETAC and ISO 14042 guidelines. Environmental impact Global warming (GWP) Stratospheric ozone depletion (ODP) Acidification (AP) Nutrient enrichment (NP) Photochemical ozone creation (POCP) Ecotoxicity Water, acute (ETWA) Water, chronic (ETWC) Soil, chronic (ETSC) Human toxicity Air (HTA) Water (HTW) Soil (HTS) Indicator g CO 2 eq. g CFC 11 eq. g SO 2 eq. g NO 3 eq. g C 2 H 4 eq. m 3 water /g m 3 water /g m 3 soil /g m 3 air /g m 3 water/g m 3 soil /g Scale Global Global Regional Regional Regional Local Local

3- LCIA Relative contributions of the life cycle stages EL! Volatilization of chlorinated organic compounds (CCl 4 ) in aeration pond! Release of treated leachate (NH 3, NO 3 ) in receiving body of water Relative contribution (%) 100% 80% 60% 40% 20% 0% 100% 80% 60% 40% 20% 0% GWP ODP AP NP POCP ETWA ETWC ETSC HTA HTW HTS GWP ODP AP NP POCP ETWA ETWC ETSC HTA HTW HTS 4.2 4.1 3.2 3.1 2.3 2.2 1.3 1.2 1.1 Bioreactor Relative contribution (%) 4.2 4.1 3.2 3.1 2.2 2.1 1.2 1.1

3- LCIA Compared emissions with associated impacts 140% Emissions (kg) Landfill gas Treated (Collected) Emitted Total w/o biogenic CO 2 Treated Emitted Total Energy Production Leachate EL 3.40E+7 2.46E+7 5.86E+7 2.97E+5 5.98E+6 6.27E+6 9.51E+7 2.53E+4 8.30E+7 7.64E+6 9.07E+7 4.53E+5 1.85E+6 2.31E+6 5.53E+7 7.65E-2 120% 100% Landfill gas emissions Emitted (Generated): CH 4 CO 2 H 2 S BTEX Chlorinated compounds Treated: CO 2 CO NO 2 PM SO 2 HCl 80% 60% 40% 20% 0% GWP EL ODP EL AP EL NP EL POCP EL ETWA EL ETWC EL ETSC EL HTA EL HTW EL HTS EL Energy Production emissions: Air: CO2 CCl4 SOX NOX CO Formaldehyde Cd Pb Hg Water: Cd Cyanide Leachate emissions: NH3 NO3

4- Conclusions! EL uses 26% more raw materials than the Bioreactor (not considering added water).! EL generates 82% more solid wastes than the Bioreactor.! EL generates, on average, 91% more potential environmental impacts than the Bioreactor.! Impacts are associated with supplementary energy production (56% for EL and 58% for Bioreactor) and with landfill gas treatment and emissions (40% for EL and 39% for Bioreactor).! Energetic valorization of landfill gas (reduces energy added to the system) and faster stabilization of waste (reduces emitted landfill gas) are reasons of the Bioreactor s better environmental performance. HOWEVER! Sensitivity analysis on post-closure monitoring period length shows that it is an important parameter in the study and can greatly affect the study s conclusions.

4- Conclusions Recommendations! Quantify:! Energy needs of excluded equipment since landfill gas and leachate volumes are greater for the Bioreactor.! Include in study:! Leachate treatment sludge management (EL);! Added water (Bioreactor).! Evaluate:! Influence of other parameters (bottom layer, final cover and leachate and landfill gas collection system efficiencies).! Expand:! System boundaries to include other MSW management activities (source reduction, recycling, composting and incineration).

Acknowledgements! Environment Canada! Intersan Inc.

QUESTIONS?

Functionally equivalent systems