Date of issue: 23-11-2016 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : CLEAN-ICE 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture : Industrial use : For professional use only : Cleaning 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Ar-La Cleaning Products B.V. Burgemeester Cambier van Nootenstraat 8 3604 AK Maarssen - Nederland T 0031 (6) 51081247 info@arlaservices.nl - www.arlaservices.nl 1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Centre Hospitalier Universitaire de Constantine SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Avonley Road SE14 5ER London 0870 243 2241 Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture: SDS < 2015 : Show CLP information + DPD classification in section 2.1 Serious eye damage/eye irritation, Category 2 H319 Full text of H statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects Causes serious eye irritation. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : H319 - Causes serious eye irritation : P264 - Wash hands, forearms and face thoroughly after handling P280 - Wear protective gloves, protective clothing, eye protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 28-11-2016 EN (English) 1/6
2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC calcium chloride (CAS No) 10043-52-4 (EC no) 233-140-8 (EC index no) 017-013-00-2 Full text of R- and H-statements: see section 16 Classification according to Regulation (EC) No. 1272/2008 [CLP] 95-99,5 Xi; R36 Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow breathing of fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Obtain medical attention if pain, blinking or redness persist. Rinse immediately with plenty of water. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact : Eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. Avoid contact with eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. 28-11-2016 EN (English) 2/6
SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Ensure good ventilation of the work station. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Keep only in the original container in a cool, well ventilated place away from : Store in a dry place. Store in a closed container. : Strong acids. Strong bases. : Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: neoprene gloves. nitrile Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of inadequate ventilation wear respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : solid Colour : white. Odour : Odorless or almost odorless. Odour threshold ph ph solution : 9-10,5 g/100ml Relative evaporation rate (butylacetate=1) Melting point Freezing point : Boiling point : > 1600 C Flash point : Auto-ignition temperature : Decomposition temperature : > 772 C Flammability (solid, gas) : Non flammable Vapour pressure Relative vapour density at 20 C Relative density : Density : 1,85 g/cm³ Solubility : completely soluble in water. Log Pow Viscosity, kinematic : Viscosity, dynamic 28-11-2016 EN (English) 3/6
Explosive properties Oxidising properties Explosive limits : 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Direct sunlight. Overheating. Moisture. 10.5. Incompatible materials Strong bases. Strong acids. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. Vapours. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity calcium chloride (10043-52-4) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard 2301 mg/kg > 2000 mg/kg > 160 mg/m³ : Causes serious eye irritation. SECTION 12: Ecological information 12.1. Toxicity Ecology - general calcium chloride (10043-52-4) LC50 fish 1 EC50 Daphnia 1 : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 4630 mg/l 610 mg/l 21d 12.2. Persistence and degradability CLEAN-ICE Persistence and degradability. 12.3. Bioaccumulative potential CLEAN-ICE Bioaccumulative potential Not established. 28-11-2016 EN (English) 4/6
12.4. Mobility in soil CLEAN-ICE Ecology - soil No supplementary information available. 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Dispose in a safe manner in accordance with local/national regulations. ADR IMDG IATA ADN RID 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazards No supplementary information available 14.6. Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2. National regulations 28-11-2016 EN (English) 5/6
15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of R-, H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation R36 Irritating to eyes Xi Irritant SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 28-11-2016 EN (English) 6/6