CO2-Free Hydrogen Supply Chain

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2016 CSLF Technology Workshop CO2-Free Hydrogen Supply Chain October 5, 2016 0 Kawasaki Heavy Industries, Ltd.

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Contents 1. Circumstances Surrounding Energy 2. The Concept of Hydrogen Supply Chains 3. Hydrogen Infrastructure Technology 3

Contents 1. Circumstances Surrounding Energy 2. The Concept of Hydrogen Supply Chains 3. Hydrogen Infrastructure Technology 4

Hydrogen Use as a National Growth Strategy 1. Circumstances Surrounding Energy Cabinet decision of April 2014 for Strategic Energy Plan": Hydrogen use is described in detail for the first time The Ministry of Economy, Trade and Industry has formulated a hydrogen and fuel cell strategic road map, and specified "hydrogen production from the asyet unused resource " and "hydrogen power generation" 5

Strategic Road Map for Hydrogen/Fuel Cell Phase 1 Phase 2 Phase 3 FCV (Fuel Cell Vehicle) Hydrogen Infrastructure 2017 Industrial FC:On market Hydrogen power generation Large scale introduction of hydrogen 1. Circumstances Surrounding Energy Introduction of CO 2 -free hydrogen Around 2020 Hydrogen cost: Competitive as HV FCV: abt. 40,000, ST: abt. 160 place Around 2025 FCV cost: Competitive as HV FCV: abt. 200,000 ST: abt. 320 place Around 2030 FCV: abt. 800,000 Later in 2020s Hydrogen CIF cost introduced from overseas: 30Yen/Nm 3 Around 2030 Large-scale introduction of unused energy source hydrogen from overseas Large-scale hydrogen power generation Around 2040 Large-scale supply of CO2-free hydrogen (using CCS, domestic RE etc.) 6

Expansion of Hydrogen Demand From FCVs to the Power generation" Demand progresses in the order of 1. Circumstances Surrounding Energy Processing" "FCV" Power generation" Tokyo Olympics "Toward a Hydrogen Olympics" Regularization of hydrogen power generation Spread of FCVs Large-scale introduction of hydrogen Power generation uses Start of Fuel Cell Vehicle (FCV) sales Automotive uses Hydrogen demand of process uses 7

Contents 1. Circumstances Surrounding Energy 2. The Concept of Hydrogen Supply Chains 3. Hydrogen Infrastructure Technology 8

The Concept of CO 2 -free Hydrogen Chains Stably supplying energy while suppressing CO 2 emissions 2. Hydrogen supply Chains Resourcing country (Australia) Production of hydrogen at low costs from unused resources (brown coal) and/or abundant recyclable energy Brown coal CCS (CO 2 capture/storage) Affordable renewable energy Liquefaction/ loading CO 2 -free hydrogen Liquefied hydrogen cargo ships Liquefied hydrogen containers C JAXA Liquefied hydrogen storage tanks Utilizing country (Japan) Process uses Semiconductor and solar battery manufacture Oil refinement, desulfurization, etc. Transport equipment Hydrogen stations Fuel cell vehicles etc. Electrical generator Hydrogen gas turbines Hydrogen gas engines Fuel cells etc. Electrical power plants Combined Cycle power generators etc. Hydrogen production Hydrogen transport/storage Hydrogen use 9

Liquefied Hydrogen ~ Large-scale Transport Methods for Hydrogen ~ Characteristics of liquefied hydrogen Extremely low temperature (-253 degrees C) 1/800 the volume of hydrogen gas Transport medium of proven practical use in industry and as rocket fuel 2. Hydrogen supply Chains High purity = no need for refinement (can be supplied to fuel cells by evaporation alone) Largest liquefied hydrogen tanks in Japan (Tanegashima Rocket Base) LNG ship (large-scale energy transport) 10

What is brown coal? It is young coal, plentiful, and occurs widely around the world Water content is high at 50-60% Since it naturally ignites easily when dried, it is not suitable for transport, and it can only be used for on-site power generation 2. Hydrogen supply Chains Because it cannot be transported, overseas transaction is impossible and "unused resource" = reasonable" and "easy rights acquisition" only for mining rights Among the many hydrogen production methods, hydrogen production from brown coal is one of the most economical methods 11

Australian brown coal 2. Hydrogen supply Chains Brown coal power plants Latrobe Valley Brown coal mining site (open cut) There is a brown coal layer to the horizon One layer is up to 250 meters below the surface There are also layers further down (Here, there is brown coal equivalent to Japanese total energy generation for 240 years) 12

CCS/CO 2 Storage Sites 2. Hydrogen supply Chains (CCS: CO 2 Capture and Storage) MELBOURNE Brown Coal Mine (Latrobe Valley) ORBOST BAIRNSDALE MORWELL SALE 80 km WELSHPOOL The Commonwealth and Victorian governments are promoting the "CarbonNet" CCS Project Large-scale CO 2 collection capacity Source: CO2CRC http://www.co2crc.com.au/publications /brochures.html 13

CO 2 -free Hydrogen Commercial Chain Feasibility Study Brown coal 2. Hydrogen supply Chains Fuel Cell Vehicle (FCV) Hydrogen production Liquefaction Storage/Loading Transport Unloading Cogeneration and energy equipment Power plants CCS Uses of renewable energy generation Propulsion, power generation and operation by hydrogen Hydrogen source: Australian brown coal Byproduct CO 2 processing: On-site storage CO 2 free Amount of hydrogen production (use): 770 t/day, Equivalent to fuel for 3 million FCVs or 1 GW of thermal power generation 14

Commercial Chain FS Results 2. Hydrogen supply Chains Hydrogen cost (CIF) [Scale] 2.6 Hydrogen cargo ships 29.8 yen/nm 3 3 million FCVs 3.2 Freight base 9.8 0.5 8.5 Hydrogen liquefaction Hydrogen pipelines Hydrogen production Japanese technologies and products or Equivalent to one 1 GW hydrogen power plant FCV 2.9 CCS 2.3 Brown coal fuel Hydrogen power plant 15

Power Generation Cost Comparison Although more expensive than fossil fuel generation, among CO 2 -free energies, it is cheaper and more stable than renewable energy and usable in large amounts Power generation cost [Yen/kWh] 40 30 20 10 0 10.3 Nuclear energy 13.4 LNG 20.0 CCS + 12.9 Coal 28.9 Oil Fixed purchase price From April 2015, for 20 years Hydrogen Wind power Solar power Reference: "Power Generation Cost Work Group Verification Report 2030 Model Plant, May 2015" 16 23.8 31.3 2. Hydrogen supply Chains 16

Contents 1. Circumstances Surrounding Energy 2. The Concept of Hydrogen Supply Chains 3. Hydrogen Infrastructure Technology 17

3. Hydrogen Infrastructure Technology Hydrogen Infrastructure Technology Development Production Brown coal hydrogen production Drying, pulverizing, and other lignite processing technology Today's introduction JAXA Liquefied hydrogen cargo ships LNG ship technology Transport Storage Loading system Ultra-low temperature sealing system technology Liquefied hydrogen tanks Ultra-low temperature technology Liquefied hydrogen container Ultra-low temperature technology Use Compressed hydrogen trailer Composite material-related technology Hydrogen gas turbines Stable, clean combustion technology 18

Liquefied Hydrogen Storage Hydrogen production 3. Hydrogen Infrastructure Technology Transport/Storage Hydrogen use Liquefied hydrogen storage tanks JAXA Models Liquefied hydrogen storage tank specifications Storage capacity 540 m 3 Design pressure Design temperature Thermal insulation method Spherical double-hull tank 0.686 MPa + Vacuum -253 C Vacuum pearlite thermal insulation 19

Land Transport of Liquefied Hydrogen Liquefied hydrogen transport container Hydrogen production Models Liquid hydrogen transport container specifications Internal volume 45.6 m 3 Unladen weight Hydrogen load capacity Thermal insulation method Accessories 3. Hydrogen Infrastructure Technology Transport/Storage ISO 40 ft container 22.3 ton 2.8 ton Hydrogen use Vacuum lamination thermal insulation Pressure evaporator 20

Overland Transport of High Pressure Hydrogen 3. Hydrogen Infrastructure Technology Hydrogen production Transport/Storage Hydrogen use Compressed hydrogen transport trailer with high-pressure composite container (first in Japan) Transports enough hydrogen for 52 FCVs Compressed hydrogen transport trailer specifications 45 MPa class composite container specifications 2012 NEDO collaborative research project Cooperation: The Research Association of Hydrogen Supply/Utilization Technology (HySUT) JX Nippon Oil & Energy Total length* 10,260 mm Total length 3,025 mm Total width 2,500 mm Diameter 436 mm Total height 3,500 mm Weight 220 kg Weight* 19,310 kg Pressure 45 MPa Number of containers loaded 24 Internal volume 300 L Hydrogen load capacity 260 kg Container type Type 3 *Minus tractor 21

Liquefied Hydrogen Cargo Ships Hydrogen production 3. Hydrogen Infrastructure Technology Transport/Storage Hydrogen use World's first liquefied hydrogen cargo ship: toward realization Cargo tank Pilot ship Special dome structure for maintaining vacuum Stainless steel vacuum thermal insulation double hull High thermal insulation supporting structure December 2013 Basic certification obtained from Nippon Kaiji Kyokai September 2016 Interim recommendations on safety requirements were approved at IMO CCC3 held in London *IGC code: International regulations relating to the structure and equipment of vessels for transporting bulk shipments of liquefied gas IMO: International Maritime Organization CCS3:the 3 rd Carriage of Cargoes and Containers 22

Hydrogen Gas Turbine Power Generation Hydrogen production 3. Hydrogen Infrastructure Technology Transport/Storage Hydrogen use Development of hydrogen gas turbines Independently developed hydrogen burner that suppresses NO x creation and realizes stable combustion Freely switchable between natural gas and hydrogen density Combustion chamber is key hardware Natural gas 100% 60% 20% 0% Hydrogen burner 0% 40% 80% 100% Hydrogen 23

Development of Hydrogen Project 3. Hydrogen Infrastructure Technology Technologies also in the possession of this company 2014 Strategic Energy Plan" 2020 Tokyo Olympics 2030 Pilot demonstration Commercial chain LNG technology JAXA Liquefied hydrogen technology 24

Pilot Demonstration 3. Hydrogen Infrastructure Technology Brown coal gasification technology On-shore base for liquefied hydrogen technology for loading/unloading between ships Marine transport technology for large volumes of liquefied hydrogen Technology demonstration of feasibility in fiscal 2020 when the Tokyo Olympics is held 25

Selection of NEDO Projects 3. Hydrogen Infrastructure Technology Select NEDO's promotion services relating to hydrogen supply chain and hydrogen cogeneration demonstration Hydrogen supply chain: Kawasaki Heavy Industries, Ltd. (organizer), Iwatani Corporation, J-Power Implement press conference hosted by NEDO 26

Established Technical Research Association Name of TRA: CO2-free Hydrogen Energy Supply-chain Technical Research Association (Abbreviation: HySTRA) Established date: February in 2016 Member: KHI, Iwatani Corporation, Shell Japan, J-Power President: Eiichi Harada(Executive Officer, KHI) 3. Hydrogen Infrastructure Technology 27

The Significance and Utility of CO 2 -free Hydrogen Chains In conclusion 1 2 Stability of supply Brown coal: World-wide distribution, enormous reserves Currently has no price, acquisition of independent rights is easy Contribution to energy security (240 years worth in Australia alone) Environmental No CO 2 emissions during use (only water is emitted) "Ultimate clean energy" 3 Improvement of industrial competitiveness Energy security for Japanese technology and products Related industries will grow due to spread of hydrogen Suppression of national resource outflow Contribution to growth strategies Development toward infrastructure export 28

Thank you for listening Kawasaki, working as one for the good of the planet Kawasaki Heavy Industries, Ltd. Corporate Technology Division 1-14-5, Kaigan, Minato-ku, Tokyo 105-8315 Tel: 03-3435-2259 Fax: 03-3435-2081 http://www.khi.co.jp 29