Revised edition: 13.02.2015 1. 1. 1. Version: 5 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Kremer Color Paste - Ultramarine Blue (new) 1. 2. Article No.: 27705 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Pigment for the coloration of plastics, paper, food packaging, inks, paint, cosmetics. Industrial application. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Not applicable. 2
2. 3. 3. 3. 1. 3. 2. Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Pigment Blue 29, C.I. 77007 Page 2 Like with all mineral powders, long-term contact can cause respiratory problems. Contact with acids releases hydrogen sulfide, an easily flammable and very toxic gas. This risk is greatly reduced with this acid resistant grade. Hazardous Ingredients: Sodium aluminium sulfo silicate; REACH Reg. No. 01-2119488928-13-0002 50% CAS-Nr: 57455-37-5 EINECS-Nr: 309-928-3 EC-Nr: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Take affected person to fresh air. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water for at least 15 minutes. Consult physician. 4. 2. After ingestion: The product is not toxic. Most important Symptoms and Effects, both Acute and Delayed Symptoms: No further information available. 4. 3. Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. All extinguishing agents suitable. Unsuitable extinguishing media: 3
None known. 5. 2. Special Hazards arising from the Substance or Mixture Page 3 5. 3. Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of carbon dioxide and sulfur dioxide. Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Wear protective clothing. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid formation and deposition of dust. Provide adequate ventilation. Provide adequate ventilation. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Further Information: Store in tightly sealed containers in a cool and well ventilated location. No special measures necessary. Do not store together with: acids and inflammable products. 4
7. 3. Specific End Use(s) Page 4 8. 8. 1. Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): No values available. No values available. 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Dust mask recommended when very dusty (with particle filter FFP1). Not required Protective glove material: Eye protection: Body protection: Safety glasses (EN 166) Protective clothing. 9. 9. 1. Environmental precautions: Do not allow entering sewerage system. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: paste Color: blue Odor: none Odor threshold: 5
ph-value: 8-10 Page 5 9. 2. Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: not available not available not flammable not easily flammable no information available no information available 1.32-1.45 g/cm3 miscible no information available 400 C (750 F) Product does not present an explosion hazard. not oxidizing not determined Solvent content: 6
Solid content: Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Loss of sulphur above 400 C. This product is extremely stable up to 350 C. Reacts with acids: development of hydrogen sulfide. Protect from heat. > 400 C Acids Hydrogen sulfide in case of contact with strong acids. Sulphur dioxide in case of fire. Carbon dioxide in case of fire. > 4000 mg/kg (rat) not determined Non irritating (rabbit) No information available Sensitization: 7
No sensitizing effects known. Page 7 Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Not mutagenic. 12. 12. 1. Additional toxicological information: Ecological Information Aquatic Toxicity 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: no information available No bioaccumulation. Not hazardous. Ultramarines are synthetic products, similar to the natural rock Lapislazuli. They are extremely stable, except in acid environment which releases sulphur hydrogen. Not considered to be environmentally harmful. AOX Value: 8
13. Disposal Considerations 13. 1. Waste Treatment Methods Page 8 Product: Dispose of according to official national and local regulations. Ultramarines cannot be disposed of were contact with acids is possible. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. 14. 4. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IATA: 14. 5. Environmental Hazards None 9
14. 6. 14. 7. 14. 8. 15. 15. 1. Special Precautions for User none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Page 9 Not classified as a dangerous good under transport regulations. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous Local regulations on chemical accidents: Employment restrictions: 15. 2. 15. 3. 16. Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Keep away from acids. A Chemical Safety Assessment is not necessary for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.