Multilayer Polyethylene Films For Food Service Packaging Applications FlexPackCon 2017

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Multilayer Polyethylene Films For Food Service Packaging Applications FlexPackCon 2017 October 2017 Dan Falla NOVA Chemicals 1

Multilayer Polyethylene Films for Food Service Packaging The advent of more complex multilayer blown film co-extrusion lines and the development of a high barrier high density polyethylene resin (B.HDPE) has facilitated many new options in food packaging. In this presentation, we will discuss: Trends in extrusion equipment The protein food market segment Changes in food service poultry packaging BONFIRE SM Multilayer Property Predictor for packaging film design 2

Film Extrusion Equipment Trends *North America Blown Film New and Current Equipment 2016-2030 *Based on 5,000-6,000 blown film lines in existence in 2016. Source: internal / external 3

Film Extrusion Equipment Sales / Trends Multilayer Blown Film Lines Trend Long-term Outlook Source: internal / external 4

Market Assessment Methodology Data Sources and Analysis Process External Market Research - Market studies, conferences, tradeshows, and publications Internal research Primary Market Research - Industry expert interviews Analysis and focus area identification 5

Protein Food Market Protein Market Segment Assessment U.S. red meat and poultry production Billion pounds 2015 USDA Data Chickens grown for eating (rather than laying eggs) are called broilers. Contrary to some myths, growth-enhancing additives such as hormones or steroids are not used in chicken. 6

Value Chain Courtesy of the U.S. Poultry & Egg Association 7

Market Overview Poultry 83% Chicken 15% Turkey 2% Other Main focus is on domestic market 8 About 8.5 billion broilers are produced in the US each year; the average broiler weighs about 6 pounds. If we went back to raising chickens the way we did in 1925, chickens' mortality rate would increase 490%, and the poultry industry's environmental footprint would be increased threefold.

Market Overview Retail and Foodservice 70 to 80% Fresh 20 to 30% Frozen About 25,000 family farmers have production contracts. Approximately 95% of chickens are produced on these farms. More than 40 billion pounds of chicken product was marketed, measured on a ready-to-cook basis. 9

Market Overview Foodservice Packaging Ice Pack box Bulk Bag in box Gas Flushed CVP bags VFFS bags 70% to 80% Fresh (inc crust frozen 20 to 30% Frozen The United States has the largest broiler chicken industry in the world, and about 19 percent of production was exported to other countries in 2015. Americans consume more chicken than anyone else in the world more than 90 pounds per capita in 2015. 10

Commercial Food Service Packaging Analysis Poultry Category Secondary Package Format Primary Package Format Packaging Film Structure Chicken Parts - 3 layer coex Pouch HDPE/PE/-Talc Chicken Parts - 7 layer coex Pouch PA/EVA/Nylon/EVOH/Nylon/PE/PE-Si Chicken Parts 3 layer coex Outer Bag - - C8-/LDPE/c8-9 layer barrier coex Inner Pouch PA/EVA/EVA/PA/EVOH/PA/PE-tie/PE/LDPE-Si 11

Cost Savings from Downgauging: Poultry Bag Cost 1990 1996 C8 C8 HDPE C8 s HDPE C8 s Barrier HDPE C8 4.0 mil 3.25 mil 3.0 mil 2.75 mil 2.75 mil 9.0 /msi 8.0 /msi 2000 2010 2017 s B.HDPE B.HDPE C8 7.6 /msi 7.4 /msi 7.1 /msi Desired Properties Medium oxygen barrier Seal-through contamination Dart and puncture resistance Burn-through resistance VFFS capability 12

Resin Grades The following resins are referred to in the next slides: Name Grade Melt Index g/10 min Density g/cc C8 SCLAIR FP120-C 1.0 0.920 HDPE SCLAIR 19C 1.0 0.958 s SURPASS FPs016-C 0.7 0.916 B.HDPE SURPASS HPs167-AB 1.2 0.967 13

Engineered Structure: I-Beam Effect (3 mil film) Stiffness HDPE s HDPE s HDPE HDPE s B.HDPE B.HDPE OTR 184 cc/100in2/day 68 cc/100in2/day 67 cc/100in2/day 23 cc/100in2/day WVTR 0.43 g/100in2/day 0.16 g/100in2/day 0.16 g/100in2/day 0.06 g/100in2/day 1% Secant 175 Mpa 568 Mpa 567 Mpa 723 Mpa http://commons.wikimedia.org/wiki/file:be am_mode_2.gif MD Tear 1260g 241g 171g 140g Bending Stiffness 6.5N-um 11.0N-um 13.6 N-um 15.9 N-um Stiffer films feel thicker than softer films. Also, downguaging of films can be limited by film stiffness due to packing systems. Separation of HDPE will result in higher film stiffness: I- Beam Effect. 14

OTR cc/100in2/day Oxygen Transmission Rate SURPASS HPs167-AB Barrier HDPE Blends 700 600 500 400 300 y = 0.0499e 0.3955x R² = 0.979 200 100 0 100% B.HDPE 90% B.HDPE 70% B.HDPE 50% B.HDPE 30% B.HDPE 15% B.HDPE 100% 1MI, 0.920g/cc C8 15

MVTR g/100in2/day Moisture Barrier Transmission Rate SURPASS HPs167-AB Barrier HDPE Blends 0.9 0.8 0.7 0.6 0.5 0.4 y = 0.0499e 0.3955x R² = 0.979 0.3 0.2 0.1 0 100% B.HDPE 90% B.HDPE 70% B.HDPE 50% B.HDPE 30% B.HDPE 15% B.HDPE 100% 1MI, 0.920g/cc C8 16

BONFIRE sm Multilayer Property Predictor 17

BONFIRE sm Multilayer Property Predictor 18

Engineered Poultry Film Using BONFIRE sm Multilayer Property Predictor (3 mil film) s s s s HDPE B. HDPE B. + HDPE 10% B. HDPE + 20% B. HDPE + 30% B. HDPE B. + HDPE 10% B. HDPE + 20% B. HDPE B. HDPE + 20% + 30% OTR 67 cc/100in2/day 23.8 cc/100in2/day 26.4 cc/100in2/day 28.8 cc/100in2/day WVTR 0.16 g/100in2/day 0.06 g/100in2/day 0.06 g/100in2/day 0.07 g/100in2/day 1% Secant 564 Mpa 668 Mpa 612 Mpa 584 Mpa Cost cents/msi Bending Stiffness 7.5 8.1 8.0 7.9 11 N-um 15.1N-um 13.6 N-um 13.2 N-um The above values are from the BONFIRE SM Multilayer Property Predictor tool, the first in a series of planned calculators and models in support of application development in the food packaging and other flexible film markets. 19

Engineered Poultry Film Using BONFIRE sm Multilayer Property Predictor Tool 3.0 mil 2.75 mil s HDPE s B. HDPE + 30% B. HDPE + 30% B. HDPE + 20% OTR 67 cc/100in2/day 31 cc/100in2/day WVTR 0.16 g/100in2/day 0.08 g/100in2/day 1% Secant 564 Mpa 584 Mpa Cost cents/msi Bending Stiffness 7.5 7.3 11 N-um 10.5 N-um The above values show how you can adjust the desired film properties / thickness and cost using the BONFIRE Multilayer Property Predictor tool. 20

Designed Film for VFFS Poultry package s B. HDPE + 30% B. HDPE + 30% Desired Properties Desired Properties Medium oxygen barrier Maximum Shelf life Seal-through contamination Reduced Leakers Dart and puncture resistance Burn-through resistance Bending Stiffness Package Integrity Packaging speed VFFS speed 21

Conclusions Poultry is the fastest growing segment of the protein market Distribution is roughly split between food service and retail Food service segment is seeing increased use of Vertical Form Fill and Seal to package parts Engineered films using a Barrier HDPE are ideal for a stiffer, downgauged film while maintaining shelf life requirements. The BONFIRE sm Multilayer Property Predictor allows customers to quickly simulate the properties of potential multilayer films. 22

Come work with us! Shrink Tunnel Horizontal FFS Vertical FFS 9 Layer Blown Film Line Testing Labs Virtual Design Tools Adhesive Laminator Thermoformer Centre for Performance Applications, Calgary, Alberta, Canada 23

novachemicals.com 2016 NOVA Chemicals - All rights reserved. The information contained herein is provided for general reference purposes only. By providing the information contained herein, NOVA Chemicals makes no guaranty or warranty and does not assume any liability, with respect to the accuracy or completeness of such information, or product results in any specific instance, and hereby expressly disclaims any implied warranties of merchantability or fitness for a particular purpose or any other warranties or representations whatsoever, expressed or implied. Nothing contained herein shall be construed as a license to use the products of NOVA Chemicals in any manner that would infringe any patent. Nothing herein shall be copied, reproduced, distributed or otherwise used without the express written permission of NOVA Chemicals. BONFIRE SM is a service mark of NOVA Chemicals Corporation SCLAIR and SURPASS are registered trademarks of NOVA Chemicals Corporation in Canada and of NOVA Chemicals (International) S.A. elsewhere; authorized use/utilisation autorisée. National Chicken Council logo is a registered trademark of National Chicken Council, Incorporated NOVA Chemicals' logo is a registered trademark of NOVA Brands Ltd.; authorized use/utilisation autorisée. Responsible Care is a registered trademark of the Chemistry Industry Association of Canada (CIAC).