CO 2 Capture Project Phase 3 Demonstration Phase Update

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CO 2 Capture Project Phase 3 Demonstration Phase Update Speaker: Karl Gerdes (Chevron) Mark Crombie (BP) CCP3 Program Manager Scott Imbus (Chevron) Storage (SMV) Team Lead Ivano Miracca (eni) Capture Team Lead 26 MAY 2011

CO 2 Capture Project The CO 2 Capture Project (CCP) The CO 2 Capture Project (CCP) is an award-winning partnership of seven major energy companies working to advance the technologies that will underpin the deployment of industrial-scale CO 2 Capture and Storage (CCS) Phase 1 2001-2004 completed Technology Screening/Proof of Concept Phase 2 2004-2009 completed Intensive Development Phase 3 2009-2013 On going Demonstration Funded by a number of sources over the years, including: Full or Associate membership of the partnership Government grants In-kind contributions Current members: BP (Program Operator), Chevron, ConocoPhillips, Eni, Petrobras, Shell & Suncor and associate member EPRI

CCP Program Objectives In order to help make CCS a practical reality and utilised in many different industries and applications around the world, the CCP aims to accomplish the following goals: Increase technical and cost knowledge associated with CO 2 capture technologies and confirm that geological storage of CO 2 is a secure and viable means of reducing greenhouse gas emissions Reduce CO 2 capture costs by 20-30% by supporting the development of improved technologies Quantify remaining assurance issues surrounding geological storage of CO 2 through site assessments, field surveys and numerical approaches; and rapid dissemination of results to stakeholder groups Validate cost-effectiveness of monitoring developments with design and testing of emerging and integrated systems Cooperate with interested parties to share information about both capture and storage demonstrations

CCP3 Technical Teams The project is planned & executed through five technical teams: Capture aims to reduce the cost of CO 2 capture from a range of combustion sources in refining, in-situ extraction of bitumen and natural gas power generation. Communications informs stakeholders about the CCP program. Government / Industry / NGO s / General Public Economics assesses the financial impacts of new technical developments. Policy reviews government incentives and activities in place. Storage Storage Monitoring and Verification (SMV) to build understanding and develop methods for safely storing and monitoring CO 2 in the subsurface.

Capture Team key projects Economic evaluation State of the art post-combustion capture technology A detailed study by Foster Wheeler on capture of CO 2 from Once-Thru Steam Generators, Combined Cycle Gas Turbines and Refinery Heaters, FCC s and Reformers using an MHI solvent Technology demonstration Oxy-fired Once Through Steam Generators (OTSG) 50 MMBTU/hr OTSG retrofit Praxair Oxy-fired FCC Pilot Plant Demonstration Vacuum Gasoil & Atmospheric Residue Feeds Petrobras Development projects Capture of CO 2 from refinery heaters using oxy-fired technology-burner testing. Emergent solvent testing for Post-combustion at EERC. Novel adsorption process assessment with InvenTyS A number of projects are in contract negotiation and will be publicly announced at the appropriate time, including developments for Membrane-Enhanced Water Gas Shift, Ionic Liquid Capture Solvents, & Chemical Looping Combustion.

OTSG - Review of project and objectives Three Phase Project: Phase I (complete): Develop design basis and cost estimates for test and commercial scale OTSG Phase II (2011-12): Demo oxy-fuel combustion on 50 MMBTU/hr test boiler Phase III (2012+): Demo oxy-fuel combustion, compression and purification on test boiler Overall Objective: To demonstrate that oxy-fuel combustion is a safe, reliable and cost-effective technology for CO 2 capture from once-through steam generators Funding Partners: Cenovus Energy (host site), CO2 Capture Project, Devon, Praxair Inc, Statoil ASA, MEG Energy and Climate Change Emissions Management Corp (CCEMC) Technology Providers: Praxair Inc industrial gas & combustion technology Image courtesy of Cenovus 6

FCC - Review of project and objectives The Fluid Catalytic Cracking (FCC) unit is often the largest single source of CO 2 emissions in a refinery. Air is used to continuously regenerate the catalyst by burning off deposited coke. In the oxy-combustion mode, air is replaced by pure oxygen, which must be diluted with recycled CO 2 to maintain thermal balance and catalyst fluidization. The testing unit has a capacity of processing up to 33 bbl/d of hydrocarbon feed (1 ton/d of CO2). Tests are now taking place, with a planned duration of two months. Image courtesy of Petrobras The project s main goals are to: Test start-up and shut-down procedures Maintain stable operation of the FCC unit in oxy-combustion mode Test different operational conditions and process configurations Obtain reliable data for scale-up Image courtesy of Petrobras 7

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