Revised edition: 01.12.2013 1. 1. 1. Version: 5.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Kremer Color Paste - Iron Oxide Black 1. 2. Article No.: 27500 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Chemical-technical industry Paint and varnish industry Printing inks Plastics industry. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. 2. 2. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: Signal word: See Section 12. This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Hazard designation: 2
Safety designation: Page 2 2. 3. 3. 3. 1. 3. 2. Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Iron oxide black pigment suspension. Contains Pigment Black 11. Aqueous dispersion. Hazardous Ingredients: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Supply fresh air and seek medical advice in case of complaints. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes. Consult physician. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth thoroughly with plenty of water and drink plenty of water. Consult a physician. Symptoms: No further information available. 4. 3. Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Foam, carbon dioxide (CO2), extinguishing powder, water jet. Unsuitable extinguishing media: Water with full jet. 5. 2. Special Hazards arising from the Substance or Mixture 3
5. 3. Special hazards: Advice for Firefighters Page 3 When heated or in case of fire: formation of hazard fumes possible. Protective equipment: Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid contamination of sewage system, open water ways and ground water. 6. 2. Personal precautions: Environmental Precautions Wear protective clothing. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (sand, earth, vermiculite or diatomaceous earth) and collect in appropriate containers for disposal. Protective clothing, see Section 8. No special measures necessary if properly handled. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Wash hands with soap and water. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Protect against frost. Keep containers tightly closed. Do not store above 50 C. No special measures necessary. Keep away from sources of ignition - do not smoke. 12; Non-combustible liquids Further Information: 4
7. 3. Specific End Use(s) Page 4 8. 8. 1. Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Polyethylene glycol, CAS 25322-68-3 TRGS 900 TLV: 1000 mg/m3 (inhalable fraction); 8 (II) Y: No teratogenic risk when the exposure limit values (ELV) and biological limit values (BLV) are adhered to. Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. None required under normal operating conditions. Avoid inhalation of vapors/fumes. Protective gloves (EN 374) Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Safety glasses (EN 166) Body protection: 9. 9. 1. Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: liquid Color: black 5
Odor: odorless Page 5 Odor threshold: ph-value: 7-9.5 Melting temperature: Boiling temperature: > 100 C (1013 hpa) Flash point: > 100 C 9. 2. Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: no information available no information available 2.1 g/cm3 (20 C) miscible no information available not determined not available not available no information available Viscosity, kinematic 6
Burning class: Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Flow time: < 90 s (20 C, DIN-cup 4 mm) Stable if used according to specifications. Protect from heat. Avoid heat. In case of fire or high temperatures: formation of carbon and nitrogen oxides, and other fumes. > 2000 mg/kg Non irritating Non-irritating to eyes Ingestion: 7
No information available Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. 13. 1. Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: No data available. No data available. No data available. No data available. No toxicity expected. Not applicable. 1, slightly hazardous Do not let run into surface waters, waste water or soil. In accordance with current regulations, product may be taken to a 8
Page 8 waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. Waste Code No.: 14. 14. 1. Transport Information UN Number ADR, IMDG, IATA 14. 2. UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. 14. 3. Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: 14. 4. Packaging Group ADR/RID: 14. 5. 14. 6. IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations. 14. 7. 14. 8. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information 9
Page 9 15. 15. 1. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water 15. 2. 15. 3. 16. Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information 5.2.5. (Classification I): < 5 % A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.