Revised edition: 15.01.2014 1. 1. 1. Version: 3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Iron Oxide Black 320, brownish 1. 2. Article No.: 48440 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent (pigment and dyes), inorganic. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. 2. 3. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Dust may be produced when working with this material, which can 2
Page 2 cause a mechanical irritation of eyes, nose and respiratory tract. 3. 3. 1. 3. 2. Composition/Information on Ingredients Substance Mixture Chemical Characterization: Pigment Black 11 (77499), Fe3O4 Information on Components / Hazardous Ingredients: Triiron tetraoxide, REACH Reg. No. 01-2119457646-28-0000 100 % CAS-Nr: 1317-61-9 EINECS-Nr: 215-277-5 EC-Nr: Additional information: 4. 4. 1. First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: After ingestion: Take affected persons out into the fresh air. Supply fresh air and keep patient calm. If breathing is difficult call a physician. Keep respiratory tract clear. In case of unconsciousness place patient stable in side position for transportation. Wash off with water. Remove contact lens. Rinse open eyes with plenty of water (10-15 min). Should irritation continue, seek medical advice. No special measures required. 4. 2. Most important Symptoms and Effects, both Acute and Delayed Symptoms: No further information available. Effects: 4. 3. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Treat symptomatically. 5. 5. 1. Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Foam, carbon dioxide (CO2), extinguishing powder, water spray. Unsuitable extinguishing media: None known. 3
5. 2. Special Hazards arising from the Substance or Mixture Page 3 5. 3. Special hazards: Advice for Firefighters Protective equipment: No special hazards. Wear self-contained respiratory protective device and full protective gear. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing. Keep spectators away. Ensure adequate ventilation. Floor may be slippery; use care to avoid falling. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Clean up mechanically. Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. In case of emergency, see Section 1. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. No special measures required. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store dry and in the original tightly sealed containers. Keep container tightly closed. No special measures necessary. 4
13; Non combustible solids Page 4 7. 3. 8. 8. 1. Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Ensure adequate ventilation, especially in confined areas. Facilities storing or utilizing this material should be equipped with an eyewash and shower facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Remove contaminated clothing. Wash hands after work. Keep away from foodstuffs, beverages and feed. Dust mask. Protective gloves Protective glove material: Eye protection: Body protection: Safety glasses with protective shields (EN 166). Protective clothing. 9. 9. 1. Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: powder Color: black Odor: odorless Odor threshold: 5
ph-value: 4-8 (5 %) Page 5 Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: > 1000 C (1832 F) This product is a non-volatile solid. no information available no information available This product is a non-volatile solid. Density: 9. 2. Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: insoluble no information available No data available. Product does not present an explosion hazard. 300-1000 kg/m3 Solvent content: 6
Solid content: Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: No further information. The product is stable. None if handled and stored according to specifications. Avoid temperatures above 80 C: product can become instable and oxidize. Under unfavourable condtions, the additionally caused heat can lead to ignition of combustible materials nearby. Therefore, do not store the product near sources of heat. None if stored and handled according to specifications. > 2000 mg/kg (rat) Non irritating Non-irritating to eyes Exposure to high ambient dust levels can cause irritation of the eyes. Chronic effects : Repeated or prolonged inhalation of dust can cause a chronic irritation of the respiratory tract. Ingestion: 7
No information available Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. Sensitization: Mutagenicity: Reproductive toxicity: Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: By analogy with a product of similar composition. No data available. No data available. Methods for the evaluation of the biological degradability are not applicable for inorganic substances. Not applicable. Not hazardous. No special effects or hazards known. AOX Value: 8
No data available. 13. Disposal Considerations 13. 1. Waste Treatment Methods Page 8 Product: If product cannot be reused or recycled, it has to be disposed of according to current local regulations. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. 14. 4. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IATA: 14. 5. Environmental Hazards None 9
14. 6. 14. 7. 14. 8. 15. 15. 1. Special Precautions for User Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Page 9 Not classified as a dangerous good under transport regulations. Do not store together with foodstuffs. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous (German Regulation, Assessment by list) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles: 15. 2. 15. 3. 16. Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. Seveso II Directive: this product is not regulated under this directive. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.