Brian T. Makowski, a Joseph Lott, a Brent Valle, b Kenneth D. Singer b* and Christoph Weder a,c*

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Brian T. Makowski, a Joseph Lott, a Brent Valle, b Kenneth D. Singer b* and Christoph Weder a,c* a Department of Macromolecular Science and Engineering and b Department of Physics, Case Western Reserve University, Cleveland OH, 4416, USA. c Adolphe Merkle Institute and Fribourg Center for Nanomaterials, University of Fribourg, CH-1723 Marly 1, Switzerland, E-mail: kenneth.singer@case.edu, christoph.weder@unifr.ch Single Crystal X-ray Diffraction Procedure for Dye A3 The dye A3 was crystallized by dissolving in benzene, filling 1 inch of a glass Pasteur pipette which had previously been sealed with a Bunsen burner, then adding a layer of methanol (1 inch) and allowing diffusion into the benzene layer over time. Single-crystal diffraction study was done on a Bruker AXS SMART APEX II CCD diffractometer using monochromatic Mo Kα radiation with the omega scan technique. The unit cell was determined using SMART 1 and SAINT+. 2 Data collection for compound A3 was conducted at 1 K (-173.5 C). The structure was solved by the direct method and refined by full matrix least squares against F 2 with all reflections using SHELXTL. 3 Refinement of extinction coefficients was found to be insignificant. All non-hydrogen atoms were refined anisotropically. All hydrogen atoms were placed in standard calculated positions and all hydrogen atoms were refined with an isotropic displacement parameter 1.2 times that of the adjacent carbon. 1 Bruker Advanced X-ray Solutions. SMART for WNT/2 (Version 5.628); Bruker AXS Inc.: Madison, WI, 1997 22. 2 Bruker Advanced X-ray Solutions. SAINT (Version 6.45); Bruker AXS Inc.: Madison, WI, 1997 23. 3 Bruker Advanced X-ray Solutions. SHELXTL (Version 6.1); Bruker AXS Inc.: Madison, WI, 2.

Heat Flow (mw, exo up) Heat Flow (mw, exo up) Heat Flow (mw, exo up) Heat Flow (mw, exo up) Heat Flow (mw, exo up) Heat Flow (mw, exo up) Electronic Supplementary Material (ESI) for Journal of Materials Chemistry a) b) EHO-C8-RG 25 to 1 1K EHO-YB 1 2 5 15 1 5 first heating first cooling second heating second cooling -5-1 first heating first cooling second heating second cooling -5-1 c) -15 3 4 5 6 7 8 9 Temperature ( C) d) -15 4 6 8 1 12 14 16 Temperature (C) 2-2 -4-6 -8 first heating first cooling second heating second cooling 5 1 15 2 25 3 35 Temperature ( o C) e) f) 6 5 4 3 2 1-1 -2-3 first heating first cooling second heating second cooling -4 5 1 15 2 Temperature ( o C) 7 6 5 4 3 2 1-1 -2-3 -4-5 -6-7 first heating first cooling second heating second cooling 5 1 15 2 Temperature ( o C) 5 4 3 2 1-1 -2-3 -4-5 -6 5 1 15 2 Temperature ( o C) first heating first cooling second heating second cooling Figure S1. Differential scanning calorimetry (DSC) traces (heating rate 1 C/min) of a) A4, b) B2, c) C1, d) C2, e) D1, and f) D2.

Intensity (a.u.) Intensity (a.u.) Electronic Supplementary Material (ESI) for Journal of Materials Chemistry a) 1. PL of solid powder PL in chloroform ABS in chloroform.5 b). 25 3 35 4 45 5 55 6 65 7 1. PL of solid powder PL in chloroform ABS in chloroform.5. 3 35 4 45 5 55 6 65 7 75 Figure S2. UV-Vis absorbance and fluorescence spectra (excitation at 365 nm) of a CHCl 3 solution and solid powder of a) C1 and b) D2.

a) b) Figure S3. Crystal structures for a) A1 and b) A3.

Absorbance PL Intensity (counts) Absorbance PL Intensity (counts) Absorbance PL Intensity (counts) Electronic Supplementary Material (ESI) for Journal of Materials Chemistry a) b) 1.5 THF 4:6 THF:water 5 THF 4:6 THF:water 4 1. 3.5 2 1. 3 4 5 6 5 6 7 c) d) 2. 1.5 CHCl 3 1:9 CHCl 3 :MeOH 25 2 CHCl 3 1:9 CHCl 3 :MeOH 1. 15 1.5 5. 3 4 5 6 7 8 4 5 6 7 8 e) f) 2. 1.5 CHCl 3 1:9 CHCl 3 :MeOH 8 6 CHCl 3 1:9 CHCl 3 :MeOH 1. 4.5 2. 3 4 5 6 7 8 45 5 55 6 65 7 75 8 Figure S4. Excimer screening experiments for dyes A3 (a,b), B2 (c,d), and C2 (e,f). The absorbance (a,c,e) and PL spectra (b,d,f) in a good solvent and a good solvent:poor solvent mixture (labeled in the figure) were measured for each dye at the same concentration (~4-5x1-5 M).

Table S1. Crystal data and structure refinement for A3. Identification code Empirical formula brianmakowski1_m C42 H52 N2 O4 Formula weight 648.86 Temperature Wavelength 1(2) K.7173 A Crystal system, space group Triclinic, P-1 Unit cell dimensions a=5.7621(11) A alpha=93.949(2) deg. b=9.2731(17) A beta=93.856(2) deg. c=16.516(3) A gamma=92.524(2) deg. Volume 877.4(3) A^3 Z, Calculated density 1, 1.228 Mg/m^3 Absorption coefficient.78 mm^-1 F() 35 Crystal size Theta range for data collection Limiting indices.47 x.23 x.1 mm 2.2 to 27.71 deg. -7<=h<=7, -11<=k<=12, -21<=l<=21 Reflections collected / unique 1514 / 419 [R(int) =.275] Completeness to theta = 27.71 97.6 % Absorption correction Multi-scan Max. and min. transmission.9922 and.9641 Refinement method Full-matrix least-squares on F^2 Data / restraints / parameters 419 / / 22 Goodness-of-fit on F^2 1.37 Final R indices [I>2sigma(I)] R1 =.719, wr2 =.1891 R indices (all data) R1 =.96, wr2 =.234

Largest diff. peak and hole 1.138 and -.531 e.a^-3 Table S2. Atomic coordinates (x 1 4 ) and equivalent isotropic displacement parameters (Å 2 x 1 3 ) for A3. U(eq) is defined as one third of the trace of the orthogonalized Uij tensor. x y z U(eq) O(2) -581(3) -231(2) 172(1) 23(1) O(1) 5639(3) 538(2) 7291(1) 3(1) C(8) 492(5) 1975(2) 7158(2) 3(1) C(5) 671(5) 265(3) 6656(2) 36(1) C(4) 662(6) 1859(3) 5811(2) 43(1) C(6) 6361(6) 4277(3) 6625(2) 45(1) C(2) 8445(5) 1529(3) 4485(2) 4(1) C(3) 8552(6) 2352(3) 5297(2) 43(1) C(7) 4116(7) 4731(3) 6212(2) 55(1) C(1) 1373(5) 211(3) 3968(2) 43(1) C(12) 1346(4) -2429(2) 8328(1) 18(1) C(13) 3361(4) -2816(2) 796(1) 2(1) C(1) 2154(4) 49(2) 81(1) 23(1) C(14) 4747(4) -187(2) 7624(1) 23(1) C(9) 4152(4) -368(2) 764(1) 22(1) C(11) 778(4) -983(2) 8336(1) 22(1) C(15) -97(4) -3537(2) 8693(1) 18(1) C(16) -1831(4) -3236(2) 9179(1) 19(1) C(17) -344(4) -4166(2) 9585(1) 18(1) C(18) -3365(4) -5675(2) 9554(1) 19(1) C(19) -591(4) -354(2) 146(1) 18(1) C(21) 53(4) -56(2) 8491(1) 21(1) N(1) 115(4) -6157(2) 8316(1) 29(1) C(2) -6827(4) -1331(2) 15(1) 23(1)

Table S3. Bond length (Å) and angles (deg.) for A3. O(2)-C(19) 1.363(2) O(2)-C(2) 1.423(2) O(1)-C(9) 1.357(3) O(1)-C(8) 1.44(3) C(8)-C(5) 1.53(3) C(8)-H(8A).99 C(8)-H(8B).99 C(5)-C(4) 1.528(4) C(5)-C(6) 1.534(4) C(5)-H(5) 1. C(4)-C(3) 1.519(4) C(4)-H(4A).99 C(4)-H(4B).99 C(6)-C(7) 1.511(5) C(6)-H(6A).99 C(6)-H(6B).99 C(2)-C(3) 1.492(4) C(2)-C(1) 1.516(4) C(2)-H(2A).99 C(2)-H(2B).99 C(3)-H(3A).99 C(3)-H(3B).99 C(7)-H(7A).98 C(7)-H(7B).98 C(7)-H(7C).98 C(1)-H(1A).98 C(1)-H(1B).98 C(1)-H(1C).98 C(12)-C(11) 1.394(3) C(12)-C(13) 1.396(3) C(12)-C(15) 1.479(3) C(13)-C(14) 1.373(3) C(13)-H(13).95 C(1)-C(11) 1.384(3) C(1)-C(9) 1.389(3) C(1)-H(1).95 C(14)-C(9) 1.391(3) C(14)-H(14).95 C(11)-H(11).95 C(15)-C(16) 1.35(3) C(15)-C(21) 1.442(3) C(16)-C(17) 1.452(3) C(16)-H(16).95 C(17)-C(18) 1.398(3) C(17)-C(19) 1.411(3) C(18)-C(19)#1 1.377(3) C(18)-H(18).95 C(19)-C(18)#1 1.377(3) C(21)-N(1) 1.143(3) C(2)-H(2A).98 C(2)-H(2B).98 C(2)-H(2C).98

C(19)-O(2)-C(2) 117.79(16) C(9)-O(1)-C(8) 118.9(18) O(1)-C(8)-C(5) 16.66(19) O(1)-C(8)-H(8A) 11.4 C(5)-C(8)-H(8A) 11.4 O(1)-C(8)-H(8B) 11.4 C(5)-C(8)-H(8B) 11.4 H(8A)-C(8)-H(8B) 18.6 C(8)-C(5)-C(4) 11.2(2) C(8)-C(5)-C(6) 11.4(2) C(4)-C(5)-C(6) 112.7(2) C(8)-C(5)-H(5) 17.8 C(4)-C(5)-H(5) 17.8 C(6)-C(5)-H(5) 17.8 C(3)-C(4)-C(5) 113.8(2) C(3)-C(4)-H(4A) 18.8 C(5)-C(4)-H(4A) 18.8 C(3)-C(4)-H(4B) 18.8 C(5)-C(4)-H(4B) 18.8 H(4A)-C(4)-H(4B) 17.7 C(7)-C(6)-C(5) 117.6(3) C(7)-C(6)-H(6A) 17.9 C(5)-C(6)-H(6A) 17.9 C(7)-C(6)-H(6B) 17.9 C(5)-C(6)-H(6B) 17.9 H(6A)-C(6)-H(6B) 17.2 C(3)-C(2)-C(1) 112.5(3) C(3)-C(2)-H(2A) 19.1 C(1)-C(2)-H(2A) 19.1 C(3)-C(2)-H(2B) 19.1 C(1)-C(2)-H(2B) 19.1 H(2A)-C(2)-H(2B) 17.8 C(2)-C(3)-C(4) 112.2(3) C(2)-C(3)-H(3A) 19.2 C(4)-C(3)-H(3A) 19.2 C(2)-C(3)-H(3B) 19.2 C(4)-C(3)-H(3B) 19.2 H(3A)-C(3)-H(3B) 17.9 C(6)-C(7)-H(7A) 19.5 C(6)-C(7)-H(7B) 19.5 H(7A)-C(7)-H(7B) 19.5 C(6)-C(7)-H(7C) 19.5 H(7A)-C(7)-H(7C) 19.5 H(7B)-C(7)-H(7C) 19.5 C(2)-C(1)-H(1A) 19.5 C(2)-C(1)-H(1B) 19.5 H(1A)-C(1)-H(1B) 19.5 C(2)-C(1)-H(1C) 19.5 H(1A)-C(1)-H(1C) 19.5 H(1B)-C(1)-H(1C) 19.5 C(11)-C(12)-C(13) 117.57(19) C(11)-C(12)-C(15) 122.42(18) C(13)-C(12)-C(15) 12.2(18) C(14)-C(13)-C(12) 121.3(2) C(14)-C(13)-H(13) 119.4 C(12)-C(13)-H(13) 119.4 C(11)-C(1)-C(9) 119.14(19)

C(11)-C(1)-H(1) 12.4 C(9)-C(1)-H(1) 12.4 C(13)-C(14)-C(9) 12.2(2) C(13)-C(14)-H(14) 119.9 C(9)-C(14)-H(14) 119.9 O(1)-C(9)-C(1) 124.7(2) O(1)-C(9)-C(14) 115.46(19) C(1)-C(9)-C(14) 119.81(19) C(1)-C(11)-C(12) 122.(2) C(1)-C(11)-H(11) 119. C(12)-C(11)-H(11) 119. C(16)-C(15)-C(21) 121.5(19) C(16)-C(15)-C(12) 124.21(18) C(21)-C(15)-C(12) 114.29(17) C(15)-C(16)-C(17) 131.75(19) C(15)-C(16)-H(16) 114.1 C(17)-C(16)-H(16) 114.1 C(18)-C(17)-C(19) 117.48(19) C(18)-C(17)-C(16) 124.65(18) C(19)-C(17)-C(16) 117.87(18) C(19)#1-C(18)-C(17) 121.79(19) C(19)#1-C(18)-H(18) 119.1 C(17)-C(18)-H(18) 119.1 O(2)-C(19)-C(18)#1 122.98(18) O(2)-C(19)-C(17) 116.29(18) C(18)#1-C(19)-C(17) 12.72(18) N(1)-C(21)-C(15) 178.2(2) O(2)-C(2)-H(2A) 19.5 O(2)-C(2)-H(2B) 19.5 H(2A)-C(2)-H(2B) 19.5 O(2)-C(2)-H(2C) 19.5 H(2A)-C(2)-H(2C) 19.5 H(2B)-C(2)-H(2C) 19.5 Symmetry transformations used to generate equivalent atoms: #1 -x-1,-y-1,-z+2

Table S4. Anisotropic displacement parameters (Å 2 x1 3 ) for A3. The anisotropic displacement factor exponent takes the form: -2π 2 [h 2 a* 2 U11 +... + 2 h k a* b* U12 ]. U11 U22 U33 U23 U13 U12 O(2) 3(1) 1(1) 31(1) 2(1) 16(1) 3(1) O(1) 32(1) 19(1) 42(1) 7(1) 18(1) -1(1) C(8) 36(1) 19(1) 36(1) 3(1) 14(1) 4(1) C(5) 41(2) 25(1) 45(2) 5(1) 19(1) 1(1) C(4) 57(2) 3(1) 44(2) 6(1) 16(1) 2(1) C(6) 63(2) 24(1) 53(2) 6(1) 3(2) 5(1) C(2) 37(2) 35(1) 48(2) 1(1) 8(1) 4(1) C(3) 59(2) 3(1) 44(2) 6(1) 17(1) 7(1) C(7) 95(3) 29(2) 41(2) 2(1) 12(2) 9(2) C(1) 42(2) 51(2) 36(2) 3(1) 7(1) 1(1) C(12) 21(1) 14(1) 19(1) 1(1) 3(1) 1(1) C(13) 23(1) 15(1) 24(1) 2(1) 6(1) 2(1) C(1) 3(1) 13(1) 26(1) 2(1) 7(1) 2(1) C(14) 22(1) 21(1) 28(1) 3(1) 8(1) 2(1) C(9) 24(1) 19(1) 25(1) 3(1) 6(1) -3(1) C(11) 24(1) 17(1) 26(1) 2(1) 8(1) 4(1) C(15) 22(1) 13(1) 2(1) 1(1) 3(1) 1(1) C(16) 22(1) 13(1) 22(1) 2(1) 4(1) 2(1) C(17) 21(1) 15(1) 18(1) 3(1) 4(1) 2(1) C(18) 22(1) 14(1) 22(1) 1(1) 7(1) 4(1) C(19) 24(1) 11(1) 21(1) 2(1) 5(1) 2(1) C(21) 24(1) 17(1) 23(1) 3(1) 9(1) (1) N(1) 34(1) 17(1) 38(1) 1(1) 16(1) 2(1) C(2) 3(1) 12(1) 29(1) -1(1) 13(1) 4(1)

Table S5. Hydrogen coordinates (x 1 4 ) and isotropic displacement parameters (Å 2 x 1 3 ) for A3. x y z U(eq) H(8A) 4852 2549 7683 35 H(8B) 3359 1934 6865 35 H(5) 8274 253 6931 44 H(4A) 6722 89 5873 51 H(4B) 51 27 5521 51 H(6A) 6486 4716 7191 54 H(6B) 7668 47 6345 54 H(2A) 692 1661 4193 47 H(2B) 856 485 4564 47 H(3A) 843 3395 5219 52 H(3B) 178 2223 5589 52 H(7A) 3976 4335 5645 82 H(7B) 4122 579 623 82 H(7C) 2795 4364 6495 82 H(1A) 1235 335 3871 64 H(1B) 1242 1432 3446 64 H(1C) 11888 1876 4252 64 H(13) 3782-3796 7941 24 H(1) 1739 13 818 27 H(14) 6118-292 738 28 H(11) -595-697 8578 26 H(16) -264-2232 9273 23 H(18) -2243-6147 9248 23 H(2A) -8369-1677 126 35 H(2B) -6638-283 1464 35 H(2C) -6675-1552 1173 35

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