Commercial Application of BGL Gasifiers M. Olschar, H. Hirschfelder, W. F. Staab, A. R. Williams (GL)

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Commercial Application of BGL Gasifiers M. Olschar, H. Hirschfelder, W. F. Staab, A. R. Williams (GL) 4th International Freiberg Conference on IGCC & XtL Technologies, 3-5th May, 2010, Dresden, Germany

Current Projects Something you ll find only in the BGL gasifier 2

Current Projects Something you ll find only in the BGL gasifier 3

Development The improved slagging version of the existing Lurgi Gasifier was jointly developed with British Gas from 1974 onwards in Westfield/Scotland to: - have a reactor to produce non-leachable vitreous slag rather than dry ash - improve specific reactor throughput - increase fines content acceptable in feed - reduce steam consumption and consequent gas condensate production - recycle tars/oils to extinction - increase CO/H 2 -yields The BGL achieved these goals, proved successfully its reliability and demonstrated its flexibility by testing a wide range of coals. First commercial plant at Schwarze Pumpe, Germany, in 2000, using broad range of feedstock including waste Technology now jointly owned by Envirotherm GmbH and GL Noble Denton 4

Key Benefits Operational Extensive development history (Lurgi: 75% of worldwide coal gasification experience) High cold gas efficiency between 82% and 93% / high specific throughput Low oxygen consumption (ca. 0.5-0.6 kg / kg Coal) Low steam consumption (ca. 0.3-0.4 kg / kg Coal) Lower aqueous liquor production Fuel flexibility (nearly all coal types and other types of fuels (e.g. waste) can be processed) Excellent load following capabilities Modularity (spare/reliability) Slag as by-product is non-leachable (vitrified) and can be utilized (road work) Capital/Investment Simple gasifier design (no exotic materials, no sophisticated heat exchangers) Smaller air separation unit (ASU) due to low oxygen requirements 0 m 5

Process Applications (overview) Input Gasification Additional Processing Conversion Products Air Separation Unit CO2 IGCC Power Oxygen Methanol Synthesis Chemicals/ Gasoline Coal BGL Gasifier Shift Reactor Gas Clean Up Methanation Synthetic natural gas Alternative Feedstock Fischer Tropsch Synthesis Fuels Ammonia Synthesis Fertilizers Typical BGL Gas Composition for bituminous coal H 2 33 % CO 56 % CO 2 4 % CH 4 7 % BGL Process has clear investment and operational advantages in a wide range of application. According to gas composition BGL is well suited to SNG production because of its high efficiency and the presence of CH 4 in product gas 6

Current Activities - SHED Client Location of facility Application Feedstock Features South Heart Energy Development, LLC (SHED) (Joint venture between Great Northern Power Development, L.P. (GNPD) and Allied Syngas Corporation (ASC)) South Heart, North Dakota, US SNG production (approx. 2.7 million Nm³/d) and utilization of CO 2 for enhanced oil recovery (EOR) Briquetted lignite (14,000 t/d coal as received) Seven (7) + zero (0) BGL gasifiers 7

Current Activities - Hulunbeier Client Location of facility Yuntianhua United Commerce Co., Ltd. Kunming, Yunnan, PRC Hulunbeier New Gold Chemical Co., Ltd., Hailaer, Hulunbeier, Inner Mongolia, PRC Hulunbeier, Inner Mongolia, PRC Application Syngas for the production of 500,000 t/year Ammonia (800,000 t/year Urea) Feedstock Features Scope of Supply Domestic dried and briquetted lignite Two (2) + one (1) BGL gasifiers (40 barg operating pressure) Synthesis gas production 119.000 Nm³/h Process Design Package for gasification and gas liquor separation Process performance guarantees Plant erection and commissioning assistance Start-up Second half of 2010 Project challenges Fasttrack Project Process Design Package completed end 2008 Construction only during summer months possible (winter temperatures approaching -45 C) 8

Current Activities - Hulunbeier Plant model 9

Current Activities - Hulunbeier Gasifier Reactor during Manufacturing Process 10

Current Activities - Hulunbeier Gasifier Reactor Transport over more than 1,000 km Distance 11

Current Activities - Hulunbeier View of the Site (2009) Gasifier Structure 12

Current Activities - Yituo Client China Yituo Group Co. Ltd., Luoyang, Henan Province, PRC Location of Facility Luoyang, Henan Province, PRC Application Fuel gas Feedstock Local hard coal Features One (1) + one (1) BGL gasifiers Gas production 43.000 Nm³/h Start-up Beginning of 2011 Scope of Supply PDP for gasification, gas cooling and gas liquor separation Process performance guarantees Plant erection and commissioning assistance 13

Current Activities - Shriram Client Shriram EPC Ltd., Chennai, India Location of Facility Haldia, West Bengal, India Application Syngas for the production of synthetic ammonia Feedstock High ash domestic hard coal (132 t/h, 3,200 t/d) Features Two (2) BGL gasifiers, one relocated from Germany, second gasifier built identically to relocated one Raw gas production 150.000 Nm³/h Scope of Supply Relocation and reengineering as far as required for gasification, gas cooling, gas liquor separation and phenol recovery Basic engineering for new BGL Plant erection and commissioning assistance on request Start-up 3rd/4th Quarter of 2011 14

Current Activities - Shriram Dismantling of the Former SVZ BGL Gasifier for Relocation 15

Current Activities - Shriram Dismantling of the Former SVZ BGL Gasifier for Relocation 16

Outlook PreFEED Study for Coal-to-Liquid (CtL) plant using BGL technology currently in progress for American client Considerably growing interest in BGL technology for SNG production in Asia Increased demand in gasification of low grade coal Growing interest in substitution of gasifiers in existing plants or in already planned projects with BGL technology Less small scale but more large scale projects 17

Summary Unique gasifier design offers major advantages including high fuel flexibility and low consumption of steam and oxygen BGL technology for all gasification routes applicable Currently 7 gasifiers are in construction or in detailed design phase Projects for production of fertilizers, SNG, fuel gas and CtL Start up of first multiple BGL gasifiers plant in second half of 2010 18

Contact 58 m (190 ft) Envirotherm GmbH Ruhrallee 185 D 45136 Essen info@envirotherm.de www.envirotherm.de Tel: +49 / 201 / 6346 400 0 m 20 m (66 ft) 19