Page 1 Revised edition: 06.07.2015 Version: 1 1. 1. 1. Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Magnesium Oxide Article No.: 64132 1. 2. Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Uses advised against: 1. 3. Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Tel./Fax.: Internet: EMail: Mon-Droguiste.Com 39 Bis Rue Du Moulin Rouge Tel +33 (0)3 25 41 04 05, Fax +33 (0)3 25 41 06 16 www.mon-droguiste.com contact@mon-droguiste.com Importer: 1. 4. 2. 2. 1. Emergency No. Emergency No.: ORFILA : 01 45 42 59 59 - SAMU : 15 - Pompiers : 18 - Médecins de garde : 15 Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: 2. 2. Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: 2. 3. Other Hazards Composition/Information on Ingredients 2
3. 3. 1. Substance 3. 2. Mixture Page 2 Chemical Characterization: Magnesium oxide. CAS No. 1309-48-4, EINECS 215-171-9 Hazardous Ingredients: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air. If required give artificial respiration. Keep patient warm. Wash off with plenty of water and soap. If irritation continues consult a physician. Seek medical attention if irritation persists. Rinse open eyes with plenty of water for at least 15 minutes. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water. Immediately get medical help. Symptoms: No further information available. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Product itself does not burn. Use extinguishing media for surrounding fire. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. Special hazards: No special hazards. 5. 3. Advice for Firefighters 3
Protective equipment: Page 3 Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Wear protective clothing. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up No special measures required. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable container for disposal. Rinse spill area. Avoid dust formation. Protective clothing, see Section 8. The usual precautionary measures are to be adhered to when handling chemicals. Avoid formation and deposition of dust. Provide adequate ventilation. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Change contaminated clothing. Wash hands after work. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a dry and well ventilated location. Keep away from heat sources. Keep product away from humidity and carbon dioxide. Store product in closed containers. Product is not flammable. Do not store together with: acids and interhalogens (e.g. bromine pentafluoride, chlorine trifluoride). Storage class (VCI): 7. 3. Further Information: Specific End Use(s) Further information: 4
Page 4 8. 8. 1. Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Parameters to be controlled: ACGTH TLV (USA): 10 mg/m3 (general dust limit) TWA / EH40 (GB): 10 mg/m3; TWA / MAC (NL): 10 mg/m3 Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Facilities storing or utilizing this material should be equipped with an eyewash and shower facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Wash hands before breaks and after work. Do not eat, drink or smoke during work. Dust mask recommended when very dusty (with particle filter P1 or FFP1). Protective gloves (EN 374) Protective glove material: Eye protection: Body protection: Tightly fitting safety goggles (EN 166). Protective clothing. 9. 9. 1. Environmental precautions: No special measures required. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: powder Color: white Odor: odorless Odor threshold: ph-value: 5
Melting temperature: 2500-2800 C Page 5 Boiling temperature: 3600 C Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: not available not flammable no information available no information available 3.57 g/cm3 practically insoluble no information available not determined no information available 9. 2. Bulk density: Further Information Solubility in solvents: Insoluble in diluted acids. Not soluble in alcohol. Viscosity, kinematic Burning class: Solvent content: Solid content: 6
Particle size: Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Stable if used according to specifications. Stable if used according to specifications. Vigorous reactions with interhalogens (e.g. bromine pentafluoride, chlorine trifluoride). Avoid humidity and air. Absorbs CO2 from the air. Strong acids. None if stored and handled according to specifications. 3870 mg/kg (m), 3990 mg/kg (f) TCLo (human): 400 mg/m3 No information available May irritate eyes. Irritates the respiratory tract. Can irritate the upper respiratory tract. Inhalation can cause metal fumes fever. No information available Mutagenicity: 7
No data available. Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. 13. 1. Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): No data available. Not assessed by the IARC. No data available. No toxicity expected. Methods for the evaluation of the biological degradability are not applicable for inorganic substances. 1, slightly hazardous The product is an inorganic material and thus does not cause a biological oxygen depletion. Dispose of according to official national and local regulations. Uncleaned packaging: Dispose of according to official local regulations. 8
Page 8 Waste Code No.: 14. 14. 1. Transport Information UN Number ADR, IMDG, IATA 14. 2. UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. 14. 3. Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: 14. 4. Packaging Group ADR/RID: 14. 5. 14. 6. IMDG: IATA: Environmental Hazards Special Precautions for User Not classified as environmentally hazardous. Not classified as a dangerous good under transport regulations. 14. 7. 14. 8. 15. 15. 1. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (self-assessment) Local regulations on chemical accidents: 9
Employment restrictions: Page 9 15. 2. 15. 3. 16. Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information EINECS (215-171-9), TSCA (US), AICS (AUS), DSL (CA), ENCS (JP) 1-465, KECI (KR) KE-22728, PICCS (PH), IECS (CN), NZIoC (NZ) This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.