Page 1 of 7 Material Safety Data Sheet BIOCIDE 320 Infosafe No. : 1QK42 Version No. : 1. 0 Issued Date: 2/12/2011 Issued by: Quaker Chemical (Australasia) Pty. Limited 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name BIOCIDE 320 Product Code A21455095 Company Name Quaker Chemical (Australasia) Pty. Limited (ABN92 000 465 949) Address Building I, 22 Powers Road, SEVEN HILLS, NSW 2147 Emergency Tel. : 1800 022 037 (24H); New Zealand: 0800 154 666 (24H) Telephone/Fax Number Telephone: : +61 (02) 8336 8531(BH); New Zealand: +64 (09) 579 4100(BH) Fax number: : +61 (02) 8336 8538; New Zealand: +64 (09) 571 0542 Recommended Use Additive 2. HAZARD IDENTIFICATION Hazard Classification Classified as Hazardous according to criteria of National Occupational Health and Safety Commission (NOHSC),. Classified as Dangerous Goods according to the n Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) Risk Phrase(s) R22 Harmful if swallowed. R23 Toxic by inhalation. R43 May cause sensitization by skin contact. R52 Harmful to aquatic organisms. Safety Phrase(s) S23 Do not breathe gas/fumes/vapour/spray S28 After contact with skin, wash immediately with plenty of soap and water. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S24/25 Avoid contact with skin and eyes. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients
Page 2 of 7 Name CAS Proportion 2, 2', 2'' (Hexahydro 1, 3, 5 triazine 1, 3, 5 triyl) triethanol 4719 04 4 60 <90 % 141 43 5 1 <3 % Ingredients determined not to be hazardous To 100% 4. FIRST AID MEASURES Inhalation If inhaled, remove affected person from contaminated area. Keep at rest until recovered. Seek immediate medical attention. Ingestion Do not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention. Skin Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention. Eye If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed out completely. Seek medical attention. First Aid Facilities Eyewash and normal washroom facilities. Advice to Doctor Treat symptomatically. Other Information For advice in an emergency, contact a Poisons Information Centre or a doctor at once. (131 126) 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Water spray, dry chemical, foam, carbon dioxide. Hazards from Combustion Products Under fire conditions this product may emit toxic and/or irritating fumes and gases including formaldehyde, oxides of nitrogen, carbon monoxide and carbon dioxide. Specific Hazards Not flammable. Hazchem Code 2X Precautions in connection with Fire Fire fighters should wear Self Contained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat exposed containers. Fight fire from safe location. This product should be prevented from entering drains and watercourses. 6. ACCIDENTAL RELEASE MEASURES Emergency Procedures Wear appropriate personal protective equipment and clothing to prevent exposure. Extinguish or remove all sources of ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Spillage can be slippery. Place inert absorbent, non combustible material onto spillage. Use clean non sparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. 7. HANDLING AND STORAGE
Page 3 of 7 Precautions for Safe Handling Avoid inhalation of vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up of mists or vapours in the work atmosphere. Do not pressurise, cut, heat or weld containers as they may contain hazardous residues. Maintain high standards of personal hygiene i. e. washing hands prior to eating, drinking, smoking or using toilet facilities. Conditions for Safe Storage Store in a well ventilated area away from heat and sources of ignition, out of direct sunlight and moisture. Store away from incompatible materials such as materials that support combustion (oxidising materials). Store in suitable, labelled containers. Inspect periodically for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Ensure that storage conditions comply with applicable local and national regulations. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards Substance Regulations Exposure Duration Exposure Limit Units Notes TWA 3 ppm TWA 7. 5 mg/m3 STEL 6 ppm STEL 15 mg/m3 Biological Limit Values No biological limits allocated. Engineering Controls Provide sufficient ventilation to keep airborne levels below the exposure limits or as low as possible. Refer to relevant regulations for further information concerning ventilation requirements. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a flameproof exhaust ventilation system is required. Respiratory Protection If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable vapor/mist filter should be used. Refer to relevant regulations for further information concerning respiratory protective requirements. Reference should be made to n Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Eye Protection Safety glasses with side shields, chemical goggles or full face shield as appropriate should be used. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform to relevant regulations. Eye protection should conform with n/new Zealand Standard AS/NZS 1337 Eye Protectors for Industrial Applications. Hand Protection Wear gloves of impervious material. Final choice of appropriate gloves will vary according to individual circumstances i. e. methods of handling or according to risk assessments undertaken. Occupational protective gloves should conform to relevant regulations. Reference should be made to AS/NZS 2161. 1: Occupational protective gloves Selection, use and maintenance. Body Protection Suitable protective workwear, e. g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. 9. PHYSICAL AND CHEMICAL PROPERTIES
Page 4 of 7 Appearance Colourless to yellowish liquid Odour Amine odour Melting Point Boiling Point 110. 5 C (1013 hpa) Solubility in Water Completely miscible ph Value 10. 0 10. 8 (100 g/l, 20 C) Vapour Pressure 14. 8 hpa (20 C) Vapour Density (Air=1) Evaporation Rate Odour Threshold Octanol/Water Partition Coefficient log pow: 2 (24 C) Density 1. 100 1. 200 g/cm³ (20 C) Flash Point Flammability Not flammable Auto Ignition Temperature Flammable Limits Lower Flammable Limits Upper Kinematic Viscosity 260 520 mm2/s (20 C) Dynamic Viscosity 300 600 mpa. s (20 C) 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions of storage and handling. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible materials Acids. Hazardous Decomposition Products Under fire conditions this product may emit toxic and/or irritating fumes and gases including oxides of nitrogen, carbon monoxide and carbon dioxide. Hazardous Polymerization Will not occur.
Page 5 of 7 11. TOXICOLOGICAL INFORMATION Toxicology Information Toxicity data for material given below. Inhalation Toxic by inhalation. Inhalation of product vapours may cause irritation of the nose, throat and respiratory system. Ingestion Harmful if swallowed. Ingestion of this product may cause irritation to the mouth, throat, oesophagus and stomach with symptoms of nausea, abdominal discomfort, vomiting and diarrhoea. Skin May be irritating to skin. May cause an allergic skin reaction The symptoms may include redness, itching and swelling. Eye May be irritating to eyes. The symptoms may include redness, itching and swelling. Chronic Effects Chronic exposure may have adverse effects on the central nervous system, liver and kidneys. Acute Toxicity Oral LD50 ( Oral, Rat):1000 mg/kg Acute Toxicity Dermal LD50 (Dermal, Rabbit):>4000 mg/kg Acute Toxicity Inhalation LC50 (Inhalation, Rat): 0. 37 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Persistence / Degradability Readily biodegradable COD (Chemical Oxygen Demand):1120 mg O2/g BOD (Biochemical Oxygen Demand):800 mg O2/g Mobility Bioaccumulative Potential Not expected to be bioaccumulative Environmental Protection Prevent this material entering waterways, drains and sewers. Acute Toxicity Fish LC50 (96h): 10 100 mg/l Acute Toxicity Daphnia EC50 (48h ): 10 100 mg/l Acute Toxicity Bacteria EC20 (0. 5h): >100 mg/l 13. DISPOSAL CONSIDERATIONS Disposal considerations The disposal of the spilled or waste material must be done in accordance with applicable local and national regulations. 14. TRANSPORT INFORMATION Transport Information This material is classified as Dangerous Goods Division 6. 1 Toxic Substance Dangerous Goods are incompatible in a placard load with any of the following: Class 1: Explosives
Page 6 of 7 Class 3 Flammable Liquids are incompatible in a placard load with any of the following: Division 5. 1 Oxidizing Substances and Division 5. 2 Organic Peroxides, if the Class 6 material is a fire risk substance Class 8: Corrosive Substances (if the dangerous goods are cyanides and the Class 8 dangerous goods are acids) And are incompatible with food and food packaging in any quantity. U. N. Number 2810 Proper Shipping Name TOXIC LIQUID, ORGANIC, N. O. S. (Contains 2, 2', 2" (Hexahydro 1, 3, 5, triazine 1, 3, 5 triyl)triethanol) DG Class 6. 1 Packing Group II Hazchem Code 2X Packaging Method 3. 8. 6. 1RT7, RT8 IERG Number 36 IATA/ICAO Packing Group None Allocated IMDG Pack. Group None Allocated 15. REGULATORY INFORMATION Regulatory information Classified as Hazardous according to criteria of National Occupational Health and Safety Commission (NOHSC),. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Poisons Schedule Not Scheduled Hazard Category Toxic,, Dangerous for the environment, Sensitising (AICS) All components of this product are listed on the Inventory or exempted. 16. OTHER INFORMATION Date of preparation or last revision of MSDS SDS Reviewed: December 2011 Supersedes: May 2010 Contact Person/Point Mario Moreno Technical Services Manager Quaker Chemical Australasia Pty. Limited PHONE: (02) 8336 8531 For specialist advice in emergencies: 1800 022 037; New Zealand 0800 154 666. IMPORTANT ADVICE: This MSDS summarises at the date of issue our best knowledge of the health and safety hazard information of the product, and in particular how to safely handle and use the product in the workplace. Since Quaker Chemical (Australasia) Pty Limited cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle and use the product in the workplace. If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
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