Classified as Hazardous

Transcription

1 1. IDENTIFICATION GHS Product Identifier TWIN OXIDE SOLUTION PART B 0.7% Product Code TOSOLNPB0.7% Supplier Name Integra Water Treatment Solutions Address Unit B/195 Port Hacking Road, Miranda NSW 2228 Telephone (02) Fax (02) Emergency Contact Recommended Use Disinfectant component B additive. 2. HAZARD IDENTIFICATION GHS Classification of the substance or mixture Signal Word(s) Hazard Statement(s) Pictogram(s) according to the criteria of Safe Work Australia. Classified as non-dangerous Goods according to ADG Code 7 th edition. Classification: Eye Damage Category 1 Danger H318 Causes serious eye damage. H315 Causes skin irritation. Corrosion Prevention Response Storage Disposal P280 Wear protective gloves/protective clothing/eye protection/face protection. P310 Immediately call a POISON CENTER or doctor/physician. P302+ +P352 IF ON SKIN: Wash plenty of water. P305+ +P351+P338 IF IN EYES: Rinse cautiously water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Theree are no Precautionary-Storage phrases assigned. Theree are no Precautionary-Disposal phrases assigned. 3. COMPOSITION/INFORMATION ON INGREDIENTS Composition Ingredients Name Sodium Hydrogen Sulphate. Penta Potassium bis (peroxymonosulphate) bis (sulphate). Water CAS Proportion 1-10 % <1 % >90%

2 4. FIRST AID MEASURES Inhalation Ingestion Eye Contact First Aid Facilities Advice to Doctor If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist, seek medical attention. Do not induce vomiting. Wash out mouth thoroughly water. Seek immediate medical attention. Wash affected area thoroughly soap and water. If symptoms develop, seek medical attention. If in eyes, hold eyelids apart and flush the eye continuously running water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Seek immediate medical attention. Eyewash, safety shower and normal washroom facilities. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Unsuitable Extinguishing Media Hazard from Combustion Products Specific Hazards Precautions Foam, dry chemical, carbon dioxide. Water spray may be used to cool down heat-exposed containers. Water Under fire conditions, this product may emit toxic and/ /or irritating fumes, smoke and gases, including oxides of sulphur. Fire-fighteroperated in positive pressure mode and full protective clothing to prevent should wear Self-Contained Breathing Apparatus (SCBA) exposure to vapours or fumes. 6. ACCIDENTAL RELEASE MEASURES Emergency Procedures Clean-up & Disposal Increase ventilation. Evacuate all unprotected personnel. Wear sufficient respiratory protection and full protective clothing to prevent exposure. Sweep up material, avoiding dust generation or dampen spilled material water to avoid airborne dust, then transfer material to a suitable container. Wash surfaces well soap and water. Seal all wastes in labelled plastic containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs, inform the local water and waste management authorities in accordance local regulations. 7. HANDLING AND STORAGE Safe Handling Use only in a well-ventilated area. Keep containers sealed when not in use. Product is hygroscopic. Prevent the build-up of dust in the work atmosphere. Avoid inhalation of dust, and skin or eye contact. Maintain high standards of personal hygiene, i.e. washing hands prior to eating, drinking, smoking or using toilet facilities. Avoid exposure. Do not handle until all

3 Safe Storage safety precautions have been read and understood. Store in a cool, dry, well-ventilated area, out of direct sunlight and moisture. Store in suitable, labelled containers. Keep containers tightly closed. Store away from incompatible materials (acids, bases or combustible material). Provide acid-resistant floor. Do not use metallic container. Store in original container. Ensure that storage conditions comply applicable local and national regulations. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards Biological Limit Values Engineering Controls Respiratory Protection Eye Protection Hand Protection Body Protection No exposure standards have been established for this material. No biological limit allocated. This substance is hazardous and should be used a local exhaust ventilation system, drawing solid/dust away from workers breathing zone. If engineering controls are not effective in controlling airborne exposure, then an approved respirator a replaceable dust/particulate filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Safety goggles full-face shield should be worn. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform Australian/New Zealand Standard, AS/ANZ 1337 Eye Protectors for Industrial Applications. Wear gloves of impervious material, such as polychloroprene. Final choice of appropriate gloves will vary according to individual circumstances, i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS : Occupational Protective Gloves Selection, Use and Maintenance. Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear to slightly pale yellow liquid. Boiling Point Melting Point Decomposition Temperature Solubility in Water 820g/L at 20 C Specific Gravity 20 C ph Value 1-2 at 20 C (approximately 1%) Vapour Pressure Not Vapour Density (Air=1) Density Bulk Density Flash Point

4 Flammability Ignition Temperature Flammable Limits (Lower) Flammable Limits (Upper) 10. STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization Stable under normal conditions of storage and handling. Heat, moisture, dust accumulation. Acids, bases and incompatible materials. Violent inflammable reactions acetic acid anhydride and ethanol. In aqueous solution, evolves hydrogen metals. Mixtures calcium hypochlorite, starch and sodium carbonate explode under pressure. Thermal decomposition may result in the release of toxic and/or irritating fumes including oxides of sulphur. Willl not occur. 11. TOXICOLOGICAL INFORMATION Toxicology Information Inhalation Ingestion Eye Chronic Health Effects Sodium Hydrogensulphate (Cas No ) =Acute oral toxicity (rat): LD 50, 2490 mg/kg. Penta Potassium bis (peroxymonosulphate) bis (sulphate)(cas no ) =Acute oral toxity (rat): LD 50, 500 mg/kg. Inhalation may irritate the respiratory system. Ingestion of this product may irritate the gastric tract, causing nausea and vomiting. contact may cause mechanical irritation, resulting in redness and itching. Aqueous solutions have corrosive effects on skin and mucous membranes. Causes serious eye damage. Eye contact will cause stinging, blurring, tearing, severe pain and possible permanent corneal damage. Aqueous solutions have corrosive effects on eyes. No data available. 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence/Degradability Mobility Bioaccumulative Potential Other Adverse Effects Environmental Protection Harmful effect on water organisms expected due to ph shift. Daphnia magna (48 hrs) EC 50, 190 mg/l Inorganic product cannot be eliminated from the water by biological purification processes. No information available on mobility for this product. Soluble in water. When low concentrations are discharged correctly into adapted biological sewage treatment plants, interference the degradation activity of activated sludge is not likely. Prevent this material from entering waterways, drains and sewers.

5 13. DISPOSAL CONSIDERATIONS Method The disposal of the spilled or waste material must be done in accordance applicable local and national regulations. 14. TRANSPORT INFORMATION Transport Information Classified as non-dangerous goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail (7 th Edition). 15. REGULATORY INFORMATION Poisons Schedule Number Packaging and Labelling S5 As required by the ADG Code and Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). 16. OTHER INFORMATION Date Prepared Abbreviations Others 23 rd January 2018 NOHSC - National Occupational Health and Safety Commission SWA Safe Work Australia ADG Australian code for the Transport of Dangerous Goods by Road and Rail 7 th edition GHS Globally harmonised System of Classification and Labelling if Chemicals. LD 50 (Lethal Dose) Amount of ingested product that kills 50% of a test sample. EC 50 (Half Maximal Effective Concentration) Concentration of a drug that gives half-maximal response. This information summarizes our best knowledge of the health and safety hazard information of the product and how to safely handle and use the product in the workplace. Each user should read this SDS and consider this information in the context of how the product will be handled and used in the workplace including in conjunction other products....end OF SDS