SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code 9822 Recommended use Recommended restrictions ne known. FLUORIDE, 100 ppm STANDARD SOLUTION Manufacturer/Importer/Supplier/Distributor information professional, scientific and technical activities: other professional, scientific and technical activities Company name Address GFS Chemicals, Inc. P.O. Box 245 Powell OH 43065 US Telephone Phone 740-881-5501 Toll Free 800-858-9682 Fax 740-881-5989 Website www.gfschemicals.com E-mail service@gfschemicals.com Emergency phone number 2. Hazard(s) identification Physical hazards Health hazards OSHA hazard(s) Emergency Assistance Chemtrec 800-424-9300 t classified. t classified. t classified. hazards resulting from the material as supplied. Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) symbol. Wear protective gloves/protective clothing/eye protection/face protection. If exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. t classified. 3. Composition/information on ingredients Mixtures Hazardous components Chemical name CAS number % SODIUM FLUORIDE 7681-49-4 <0.1 n-hazardous components Chemical name CAS number % WATER 7732-18-5 >99.9 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Revision date: Issue date: vember-21-2013 1 / 6
Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Rinse skin with water/shower. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Get medical attention if symptoms occur. Provide general supportive measures and treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. IF exposed or concerned: Get medical advice/attention. Suitable extinguishing media Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Use extinguishing agent suitable for type of surrounding fire. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters ne known. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up t applicable. Wear suitable protective equipment. Keep unnecessary personnel away. Local authorities should be advised if significant spillages cannot be contained. Keep people away from and upwind of spill/leak. Ensure adequate ventilation. Wear appropriate personal protective equipment. This product is miscible in water. Stop the flow of material, if this is without risk. Small quantities may be flushed to drains with plenty of water. Never return spills in original containers for re-use. For waste disposal, see section 13 of the MSDS. Environmental precautions special environmental precautions required. 7. Handling and storage Precautions for safe handling Avoid contact during pregnancy/while nursing. Use personal protective equipment as required. Avoid prolonged exposure. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits Store locked up. Store in a cool, dry place out of direct sunlight. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type PEL US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type US. ACGIH Threshold Limit s Components 2.5 mg/m3 Form TWA 2.5 mg/m3 Dust. Type TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type Biological limit values TWA 2.5 mg/m3 biological exposure limits noted for the ingredient(s). 2.5 mg/m3 Revision date: Issue date: vember-21-2013 2 / 6
Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Wear safety glasses with side shields (or goggles). Wear protective gloves. rmal work clothing (long sleeved shirts and long pants) is recommended. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Avoid contact with skin. Avoid contact with eyes. When using, do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. Clear. Liquid. Aqueous solution. Colorless. Odorless. Melting point/freezing point 32 F (0 C) estimated Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) > 212 F (> 100 C) t applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor density Relative density Solubility(ies) Partition coefficient (n-octanol/water) Miscible. Auto-ignition temperature Decomposition temperature Viscosity Other information Density Percent volatile > 99.9 % Specific gravity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions 1.00 g/cm3 estimated 1.00 estimated Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Revision date: Issue date: vember-21-2013 3 / 6
Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information ne under normal conditions. ne known. Hydrogen fluoride. Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Based on available data, the classification criteria are not met. Species FLUORIDE, 100 ppm STANDARD SOLUTION (CAS Mixture) Acute Oral Other Components Acute Oral Other Species * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Test Results 9030 mg/kg 8360 mg/kg 4020 mg/kg 59000 mg/kg, estimated Test Results 46 mg/kg 44.3 mg/kg 51.6 mg/kg 32 mg/kg 23 mg/kg 17.2 mg/kg 24 mg/kg 11.8 mg/kg May be irritating to eyes. May be irritating to the skin. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Suspected of damaging fertility or the unborn child. Prolonged inhalation may be harmful. Revision date: Issue date: vember-21-2013 4 / 6
12. Ecological information Ecotoxicity Components Aquatic Crustacea Contains a substance which causes risk of hazardous effects to the environment. EC50 Species Water flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. Persistence and degradability data is available on the degradability of this product. Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information Test Results 98 mg/l, 48 hours Wash to drains with lots of water. Dispose of contents/container in accordance with local/regional/national/international regulations. DOT t regulated as a hazardous material by DOT. IATA t regulated as a dangerous good. IMDG t regulated as a dangerous good. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. information available. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) t on regulatory list. CERCLA Hazardous Substance List (40 CFR 302.4) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Other federal regulations Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Revision date: Issue date: vember-21-2013 5 / 6
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number t listed. Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) DEA Exempt Chemical Mixtures Code Number Food and Drug Administration (FDA) US state regulations US. Massachusetts RTK - Substance List California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance t listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s) 16. Other information, including date of preparation or last revision Issue date Version # 01 Further information Disclaimer Revision Information vember-21-2013 The information in the sheet was written based on the best knowledge and experience currently available. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Revision date: Issue date: vember-21-2013 6 / 6