Leonardo Riera and Bary W. Wilson. Presented at the 4th Global Economic Leaders Summit, Changchun China, August 30 - September 1, 2015

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Municipal Solid Waste as a Renewable Resource Leonardo Riera and Bary W. Wilson Presented at the 4th Global Economic Leaders Summit, Changchun China, August 30 - September 1, 2015 Abstract: Improperly handled Municipal Solid Waste (MSW) can be a health hazard that damages the environment. Its continued storage, even in landfills, also represents a source of air contamination and a waste of fuel that could otherwise be used to generate renewable electrical power. Recent advances in thermal conversion technology, including three chamber gasification systems, make thermal treatment technically and economically feasible, not only greatly reduce the volume of waste going to landfill, but to also generate electrical power and produce a solid inert or cementitious material that can be sold into the market. Variants of the gasification technology described in this presentation can also be used to thermally treat coal fly ash waste, producing electrical power and cementitious additives. Background Total global energy consumption in 2014 was estimated at approximately 500 exajoules (equal to approximately 475 quads or about 139,000 terawatt-hours). In spite of stated policies in many countries to increase renewable energy generation in recent years, energy production from all renewable sources combined remains at between 12% and 19% of total energy consumption, depending on estimate methodology (mostly represented by Biofuels and Hydroelectric, as shown in Figure 1 below). Figure 1. Estimated total annual world energy consumption from 1820 to 2015 according to source 1

In the US, approximately 1.2 quads of recoverable renewable energy is sent to landfills each year, much of which could be converted to electrical power or usable heat energy through thermal or biological processes. In other words, well over 1% of the US energy requirements could be met by thermally converting waste going to landfills. Unlike renewable energy from wind and solar, gasification of solid waste provides power that is constant and available on a 24/7 basis (base power). Such conversion would also greatly reduce greenhouse gas equivalent emissions from landfills, which are a major source of fugitive methane (Thorneloe, 2012). As shown below in Table 1, there is wide variation in the utilization of solid waste as a fuel resource, with jurisdictions such as Singapore and Tokyo thermally treating some 90% of their non-recycled MSW to generate power, while cities such as New York elect to landfill essentially 100% of their non-recycled solid waste. Table 1. Comparison of Waste to Energy (WTE) conversion in selected cities* City Waste Not Recycled (TPD) Landfilled (TPD) Used for WTE (TPD) Illegally Dumped (TPD) Beijing 11,326 90% 8% 0% Singapore 7,000 10% 90% 0% Tokyo 9,589 10% 90% 0% Manilla 6,000 75% 0% 25% Seoul 3,742 45% 55% 0% Jakarta 6,000 78% 22% 0% Mumbai 9,200 85% 0% 15% Kolkata 2,920 70% 0% 30% New York 12,000 100% 0% 0% *Data sources provided in the References Section. European best practices guidelines for solid waste management (now being adopted by many countries outside the EU) mandate the minimization of waste going to landfill by only allowing inert residue (non-recyclable, non-putrescible and non-combustible waste) to be placed there. Waste that does not meet these criteria should be recycled, composted, or thermally converted to electrical power or to process heat or steam (Amec, et al., 2011). While incineration of MSW is widely practiced, the preferred process for thermal conversion of combustible, non-recyclable solid waste residue, especially at smaller scales, is gasification. While most of the thermal treatment plants for MSW operating in Tokyo (for example) are incinerators, there are also now several gasification plants. In terms of cost per ton, thermal efficiency, and inherently low emissions for the conversion of waste into energy, gasification is the best available technology thermal conversion. 2

Gasification Waste to Energy Technology Zaman (2009) provided a comparative life cycle assessment comparing landfill, incineration and gasification as primary technologies for treatment and disposal of MSW. Again, gasification ranked highest overall when considering the combined characteristics of conversion efficiency, cost per unit of power generated, and favorable environmental impact. Specifically, these published studies and reports have shown that gasification technology is inherently: - more thermally efficient than incineration (by as much as 18%); - cleaner than incineration, with fewer air emissions including less entrained particulate, less CO 2, and lower emissions of nitrogen and sulfur oxides (NOx and SOx), as well as lower concentrations of other pollutants in the flue gas; - less expensive than incineration facilities to build and operate; - capable of producing commercially beneficial by products. In addition, MSW gasifiers can be designed to produce a low carbon, inert and non-leachable slag or vitreous frit instead of a leachable bottom ash (as is produced by incinerators). Residual slag or vitreous frit can be beneficially used in cement making, or as an aggregate for cement blocks or for fill materials. As such, gasification adds additional sources of potential revenue to the operator through the sale of this material. Gasifiers have a history of safe and dependable commercial operation and can be used for reliably firing steam boilers to generate electrical power, as well as for combined heat and power. Gasification involves the heating of combustible waste in a low oxygen environment to a temperature at which the solid materials are converted to a gas. Since the gasification process is carried out with insufficient oxygen to complete combustion, it produces a clean burning fuel gas generally known as syngas. There is a significant difference between incinerators and gasifiers with gasifiers not only being more cost effective to operate, but also far friendlier to the environment in terms of reduced particulate matter emissions. The specific differences between incinerators and gasifiers, as options for thermal conversion of MSW, are depicted in Figure 2 below. One important difference is that the total amount of air needed for combustion must flow through an incinerator chamber, while only about 30% to 40% of that amount flows through a gasifier. The chemical reactions occurring in the gasifier (chemically reducing environment) are different from those occurring in the incinerator (chemically oxidizing environment). In addition to being cleaner, gasifiers are smaller, more efficient, and less expensive to build for a given fuel load. Syngas produced in the gasifier can be used to fire a boiler for steam generation and subsequent production of electricity by conventional means. The conversion of waste material, such as MSW is accomplished in a gasifier similar to the one shown in Figure 3 on the following page. The syngas created in the gasifier (mainly CO, H 2, CH 4, CO 2, N 2 and H 2 O) is a clean burning fuel from which the particulate matter has removed by a cyclone prior to entering the oxidizer. The syngas emerges from the gasifier at a relatively high temperature and addition thermal energy is created by cleanly burning this gas in the oxidizer. 3

The thermal energy is used to create steam for the purpose of powering a steam turbine generator for conventional production of electrical energy. The only difference between the production of electric energy from a conventional steam plant and a gasifier powered steam plant operating on MSW is the fuel, which the plant operator is paid to consume. Gasification of MSW for the production of electricity is the only form of electric power generation where the generating facility is paid to take the fuel, making these plants very attractive to the private investment community. Incineration Gasification Figure 2: (Left) Incinerators operate with excess air, generates more PM, NOx, VOC than gasifiers, their equipment is larger and more expensive and incinerator ash is generally special or hazardous waste (Right) Gasifiers operate on sub stochiometric air (about 30% -40% of that required for complete combustion), generate less particulate matter, most of which is removed prior to combustion generating less PM, NOx, CO 2 VOC and no ozone, use smaller and less expensive equipment per ton of waste processed, generate an ash residue that can be made non leachable and useful as aggregate. Figure 3. (TOP) Drawing showing the main components of the EPR gasification systems (BOTTOM) Air Fed gasification power plant (without acid gas removal unit or ESP) in commercial operation and in compliance with EPA emission requirements since 1995. 4

Figure 4 below depicts each of the main operational components (color coded) of a waste to energy gasification facility as designed and developed by EnviroPower Renewable, Inc. Figure 4. Color coded components of an air fed gasification waste to energy facility Feedstock is delivered to the facility. Acceptable feedstocks include municipal solid waste (MSW), biomass, green waste, tires, construction and demolition waste, as well as medical waste and certain kinds of sludge. Fuel Preparation: waste is sorted using a semi-automated system to remove potentially recyclable and hazardous materials. Feedstock is then shredded to produce RDF (Refuse Derived Fuel). Gasification: RDF is gasified to produce to a fuel consisting mainly of N 2, CO, H 2, CO2, H 2 O and CH 4. The fuel gas is cleanly combusted in an oxidizer and the heat is used to produce steam. The fuel gas can also be use to fire internal combustion (IC) engine prime movers. Steam Production: Hot gasses from the oxidizer enter a boiler that produces high temperature, high pressure steam, which is used to drive a steam turbine generator. Flue Gas Clean-up: The flue gas clean up system reduces the emission of particulate matter and other regulated constituents to levels well below USEPA Air Quality Standard concentrations. Electric Power Generation: Steam from the boiler drives a turbine to generate electricity. Depending on fuel, up to 1.0 MW hours, or more, of electrical energy can be generated from one ton of RDF. Ash Treatment: Bottom ash and fly ash is conveyed to a high temperature rotary kiln where the residual fixed carbon is converted to syngas and the remaining mineral ash is sintered. 5

Modern air fed gasifiers operating on municipal solid waste are exemplified by a system built and operated by our teaming partner, CHO Power, in France. Gasifiers designed by PRM Energy, who is also our partner and the manufacturer of our reactors, have an outstanding performance record, with some having been in operation for more than 30 years with only routine maintenance required. The full commercial scale gasification facility shown to the right is based on the PRME Model KC-24 air fed gasifier (Figure 5 TOP). In this application, the gasifier operates on a blend of refuse derived fuel (RDF) that is 70 % MSW and 30% woody biomass. The woody biomass is used to qualify the system for a closed loop biomass based premium electrical feed in rate. This system, located in France, uses both a steam turbine and syngas-fired reciprocating engines to drive generators for production of electrical power. A similar system operating on wood and carpet waste (C&D waste), and producing steam only, has been operating in Dalton, GA since 2007. Some two dozen of these systems are in operations worldwide. Use of these reactors in the EPR modular facility design with indoor waste processing affords both effective odor control and rapid processing of the incoming MSW with recyclables separated and Figure 5. (Top) PRM KC-24 MSW gasifier (Bottom) HTT Rotary Kiln the resulting MSW prepared for gasification. A typical gasification plant using a set of gasifiers shown in Figure 5 (TOP) can produce 16 MWe (nameplate) with approximately 13.5 MWe per line delivered to the grid. A 48 MW (nameplate) plant, a layout, is comprised of three 16MWe gasification lines. EPR has designed and patented waste gasification systems using proven equipment, improved thermal efficiencies, reduced emissions and improved ash management via proprietary processes that incorporate a rotary kiln of the type shown in Figure 5 (BOTTOM). The EPR system has been considered the most comprehensive and advanced system for the conversion of waste to energy and has been selected in open international competitions for projects in Ireland, Mexico, and in the United States. EPR WTE technology has been approved by the US Army after rigorous evaluation by two US National Laboratories. Shown below in Figure 6 is a rendering of the 48 MW WTE facility being permitted in Ireland. Figure 6. Rendering of 48 MW Waste to energy facility in Ireland designed to operate on black bag waste 6

A project depicted in Figure 6 is being developed by EPR under contract to the government of County Limerick, Ireland. A similar plant is being permitted for Las Vegas, Nevada. If additional power is required by the customer, additional 16MW (nameplate) gasifier lines to the plant either as part of the initial plant design or as downstream pre-planned plant upgrade. Comparing Environmental Impacts Gasification, Incineration and Landfill for Generation of Power It is now widely recognized that landfill of MSW results in much higher methane emissions, and in fact in higher greenhouse gas equivalent emissions overall, than does gasification. Figure 7 (Left) below compares the carbon dioxide equivalent emissions per unit of electrical power generated from MSW by gasification, incineration and landfill gas recovery and combustion. As shown, landfill gas generation releases more than 2.5 times as much green house gas equivalents per kwh of energy produced as does gasification. Likewise, Figure 7 (Right) shows that gasification generates far less NOx and SOx and particulate matter than incineration, and far less SOx and NOx than landfill gas, per kwh or energy generated. Figure 7. Comparison of greenhouse gas equivalent emissions and regulated pollutant emissions pre kwh of energy generates by gasification, incineration and landfill gas MSW gasifiers can be operated with extremely low air emissions as confirmed by the recent Minor Source permit issued to our 48 MW facility in Las Vegas, NV. Figure 8 below compares the maximum worst case PM 10 concentrations at a residence located 500 meters from a EPR 48 MW WTE gasification facility to Irish EPA regulatory limits and measured PM 10 background along a highway. 7

Figure 8 below is a comparison of Irish EPA Lower Assessment Threshold Values for PM 10 and PM 2.5 as compared to PM 10 highway background concentrations and maximum and annual average PM 10 values from an EPR 48 MWe (nameplate) gasification facility. As can be seen, the maximum PM 10 concentrations at a distance of 500 m from the Gasification Power Plant (distance to closest residence) is approximately 100 times lower than the average background PM 10 concentration measured along a highway. More importantly, this value is approximately 500 times lower than the Irish EPA health effects based Lower Assessment Threshold for PM 2.5 of 12 ug/m 3. Figure 8. PM 10 concentrations compared to regulatory thresholds and highway background Dumpsite Remediation and Gasification of Combustible Fractions Uncontrolled dumpsites, especially those on which open burning is allowed in an attempt to reduce volume and control odors, are among the most significant sources of environmental pollution in developing countries. Open burning of a single 50 gallon barrel of domestic waste in someone's back yard results in more emission of criteria pollutants into the atmosphere than a full day's operation of a 50 MW gas fired power plant. Legacy dumping of municipal solid waste or construction and demolition waste in unlined landfills can give rise to large plots of contaminated soil, sometimes in areas that have increased in land values since the dumping occurred. The three images to the right show the remediation of a contaminated construction and demolition waste dumpsite on land that has since risen substantially in value. In these cases, the dumped material must be excavated and separated, with the contaminated material hauled to a lined landfill. Figure 9. Remediation of a legacy C&D dumpsite 8

Municipal solid waste landfill sites, even if lined and well managed, can still represent a resource for renewable fuel for electrical power generation by gasification. In order to extend the service life of lined landfills by reducing waste volume, it is often economically viable to recover combustible waste from these for use as renewable fuel. As illustrated by the images in Figure 9, remediation of sites with improperly dumped or managed materials can be accomplished using modern equipment including excavators, vibrating screens, trommel screens, air flow (air knife) separation, crushers, compactors and, in some cases, a final hand sorting. These methods and equipment can be applied to reducing the overall cost of remediating a variety of dumpsites where the land is worth reclaiming. Coal Fly Ash Remediation and Production of Cementitious Additives Thermal treatment of coal fly ash, along with ancillary coal and limestone in a three chamber gasification process, can be used to produce steam for power generation as well as a cementitious additive that can partially replace portland cement in high strength concrete mixes. This proprietary (ATEC) process is another illustration of the versatility of air fed gasification in conversion of solid waste to electrical energy and useful aggregate or cementitious products. Concrete mixes wherein the ATEC product was substituted for 25% of the ordinary portland cement showed substantially greater compressive strength upon curing than the same mixes using only ordinary portland cement. Figure 10 (below) shows the schematic of this patented process. Shown to the right are the starting, intermediate and end products of the ATEC process Figure 10. (ABOVE) Schematic of the EPR ATEC Process for conversion of mixed coal, coal fly ash and MSW to electrical power and cementitious materials (RIGHT) starting, intermediate and end products of the ATEC process applied to coal fly ash. 9

Economics and Business Model for Gasification WTE Deployment Our business model is one in which we maintain control of the plant from the design stage through the operation of the plant for the full extent of the Power Purchase Agreement (PPA), which ideally is 25 to 30 years. Our systems constitute a most attractive business model for investors, and for the local partner who may be the waste owner, land owner, or power off-take counterparty. This approach to the business of power generation allows EPR to maintain full operating control of the plant for quality control purposes, and takes advantage of revenues generated by the plant from the sale of the power, the sale of recyclables, and revenues generated from waste hauling tipping fees. This business model provides for three sources of revenue and uses proven gasification technology patented by EPR. Provided that contracts for waste supply and power off-take can be made with suitably credit worthy counterparties, project financing can be secured from a number of international institutions, private investors, multilaterals and merchant banks that provide infrastructure financing. In conclusion, the waste to energy systems, as designed by EnviroPower Renewable, have important attributes and advantages that municipalities, private operators of waste facilities, countries, and investors should consider: 1. Proven Technology: There is no technology risk. EPR s gasification technology is currently in use in several facilities around the world. Three facilities have been in continuous operation for over 30 years. 2. High Efficiency: The design modifications EPR implemented to the gasification process improve the efficiency from approximately 0.5-0.7 MWh/tonne of waste, to more than 1.0 MWh/tonne of waste, depending on the properties of the waste. 3. Superior Economic Performance: The projects that are under contract or in development typically have IRRs greater than 35%, and EBITDA margins in excess of 50 percent. 4. Superior Environmental Performance: The effluent emissions from the EPR gasification facilities are dramatically lower than from similarly sized incineration facilities. (An EPR 48 MW Facility has just been permitted as a Minor Source under USEPA Title V). 5. Managing High Water Content Waste: EPR s systems include thermal dryers and can also incorporate high pressure compaction for reducing waste moisture content when needed, for efficient gasifier operation. 6. Water Reuse: The water (leachate) from the waste is extracted, treated, and used as process and cooling water. The EnviroPower Gasification System can be engineered to prevent the release of waste water or gray water to the environment. All water is recycled or reused. 10

References Amec, et al. (2011): European Commission Report on Industrial Emissions of Nanomaterials and Ultrafine Particles http://ec.europa.eu/environment/industry/stationary/pdf/27924.pdf Thorneloe, SA (2012) U.S. Trends in Solid Waste Management and GHG Emissions Health and Environmental Concerns for Landfills,Berlin Germany http://www.umweltbundesamt.de/sites/default/files/medien/421/dokumente/us_epa_swm_and_ghg_emission.pdf Zaman, A U (2010) Comparative study of municipal solid waste treatment technologies using life cycle assessment method Int. J. Environ. Sci. Tech., 7 (2), 225-234, Spring 2010 http://link.springer.com/article/10.1007%2fbf03326132#page-1 City Source Date Tokyo Tokyo Municipal Government Bureau of Environment Website 2010 Seoul "Municipal Waste Management in Tokyo and Seoul", Institute for Global Environmental Strategies 2002 Jakarta "Winding Road of Jakarta Waste Management", Jakarta Post 2013 New York "New York City Trash: Where Does it All Go?" Sierra Club 2012 Kolkata "Solid Waste Management in Kolkata, India: Practices and Challenges", Waste Management Vol 29, 2009 Mumbai "Solid Waste Management in Mumbai India", UNESCO course on waste management 2013 Manilla "The Garbage Book, Solid Waste Management in Metro Manilla" Asian Development Bank 2004 Singapore "Integrated Thinking: Solid Waste Management in Singapore", Waste Management World 2006 Beijing "Municipal Solid Waste Management in Beijing City", Waste Management, Vol 29, Iss 9 2009 Shanghai "Where does Shanghai's Garbage Go?", NYU Shanghai Feature 2011 11