Department of Chemical Engineering West Virginia University. ChE 414 Coal Utilization Engineering Spring 2008

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Monday, Wednesday 3:00 4:50 Room 209, Mineral Resources Building Department of Chemical Engineering West Virginia University ChE 414 Coal Utilization Engineering Spring 2008 Instructor: John W. Zondlo Office: Room 415 ESB Phone: 293-2111 x2409 Office Hours: Wednesday 2:00 3:00 or by Appointment Required Text: An Introduction to Coal Technology, 2 nd Edition, N. Berkowitz, Academic Press, 1994. Reference Texts: * Coal: The Energy Source of the Past and Future, Harold H. Schobert, American Chemical Society, Washington, DC, 1987. * Synthetic Fuels, R.F. Probstein and R.E. Hicks, McGraw-Hill, 1982. * The Chemistry and Technology of Coal, James G. Speight, Marcel Dekker Inc., New York, 1983. * Coal Conversion Technology, C.Y. Wen and E.S. Lee, Addison-Wesley Pub. Co., 1979. Reaction Engineering in Direct Coal Liquefaction, Y.T. Shah, Addison-Wesley Pub. Co., 1981. Coal Conversion, E.J. Hoffman, The Energon Co., Laramie, Wyoming, 1978. * Chemistry of Coal Utilization, H.H. Lowry (Editor), J. Wiley & Sons, Vol. I & II (1945). Supplementary Vol. (1963); Second Supplementary Vol., M.A. Elliott (editor) (1981). * Coal Preparation, Fourth Edition, J.W. Leonard (Editor), American Institute of Mining, Metallurgical, and Petroleum Engineering, Inc., New York (1979). Energy and Society, An Introduction, Harold H. Schobert, Taylor and Francis, 2002. Sustainable Energy, Choosing Among Options, J.W. Tester, E.M. Drake, M.J. Driscoll, M.W. Golay and W.A. Peters, The MIT Press, 2005.

*Good References Other Related References: Basis for Course Grade: Handbook of Synfuels Technology, R.A. Meyers (Editor), McGraw-Hill, 1984. Coal Gasification, L.G. Massey (Editor), Advances in Chemistry Series 131, American Chemical Society, Washington, DC, 1974. Combustion, Second Edition, I. Glassman, Academic Press, 1987. Coal Gasification, Existing Processes and New Developments, H.D. Schilling, B. Bonn and U. Krauss, Graham & Trotman Limited, London, 1979. Production and Utilization of Synthetic Fuels, An Energy Economics Study, F.R. Benn, J.O. Edewor and C.A. McCauliffe, Applied Science Publishers, London, 1981. The Beehive Coke Years, J.K. Gates, Uniontown, PA, 1990. Chemical Reaction Engineering, 2 nd Edition, O. Levenspiel, J. Wiley & Sons, 1972. Energy Conversion Engineering, R.C. Bailie, Addison-Wesley Pub. Co., 1978. Introduction to Chemical Engineering Thermodynamics, 3 rd Edition, J.M. Smith and H.C. Van Ness, McGraw-Hill, 1975. Unit Operations of Chemical Engineering, 6 th Edition, W.L. McCabe, J.C. Smith and P. Harriott, McGraw-Hill, 2001. Chemical Engineering Handbook, 7 th Edition, J. Perry and D.W. Green (Editors), McGraw-Hill, 1998 (available in ChE Library). Mid Term Exam 30% Final Exam 30% Special Projects 30% Homework 10% Course Objectives: To integrate the discovery and use of coal into the development of energy generation, industrial growth and world history. To gain an appreciation for the physical and chemical properties of coal, coal structure and coal characterization. To survey the many possible chemical reactions and transformations of coal during its processing and use.

To learn about the main technologies and processes associated with coal utilization, viz. Mining, combustion, pyrolysis, liquefaction and gasification. To address the significant economic and environmental issues related to fossil fuel combustion and utilization. To have fun learning about coal! NOTE: During the semester we may have several field trips to view some current and past coalprocessing facilities. We will also tour the coal-processing labs at WVU and the Beechurst Power Plant. NOTE: In addition to the readings from the Recommended Text by Berkovitz, there will be numerous class handouts. It is suggested that you get a three-ring binder to keep the handouts in an orderly fashion! NOTE: We will also have several films/slide shows on various aspects of coal utilization.

Spring 2008 Course Outline ChE 414 Coal Utilization Engineering Text: An Introduction to Coal Technology, N. Berkowitz I. Introduction Chapters 1 and 2 Sources of Energy, Reserves and Production History of Coal Utilization Coal Formation Coal Mining Overview of Coal Conversion Technologies II. Analysis and Characterization of Coal Chapters 3,4,5,8 & 9 Chemical and Physical Nature Proximate analysis Ultimate analysis Coal Rank ASTM Classification Other Characteristic Tests Petrography Coal Cleaning III. Coal Pyrolysis Chapters 6 and 11 Coke Making Mild Gasification Chemicals From Coal Kinetics IV. Coal Gasification Chapter 12 Reactions Gas Cleanup Gasifier Reactors Typical Processes Methanation Oxygen and Methane Production V. Coal Liquefaction Chapter 13 Direct vs. Indirect Liquefaction Upgrading of Products Typical Processes VI. Solvent Extraction Chapter 7 Types of Solvents Nature of Products Some Processes Problems

VII. Coal Combustion Chapter 10 Combustion Products Typical Combustion Systems Environmental Problems VIII. Environmental Issues Chapter 14 Mine Wastes Land Reclamation Ash and Char Disposition Air Pollution -- Fly Ash -- Acid Rain -- Greenhouse Effect and Global Warming IV. The Future of Coal Utilization Future Gen Combined Cycle Processes