VINKOCIDE CMI 14 -Broad spectrum preservative-

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PRODUCT FEATURES Vinkocide CMI 14 is a formulation of 5-Chloro-2-methyl-2H-isothiazol-3-one (CIT) with 2-Methyl-2H-isothiazol-3-one (MIT). Synonyms of 5-Chloro-2-methyl-2H-isothiazol-3-one: 5-chloro-2-methyl-4-isothiazolin-3-one, CIT synonyms of 2-Methyl-2H-isothiazol-3-one: 2-Methyl-4-Isothiazolin-3-one, MIT. Vinkocide CMI 14 is a biocide to be used as a preservative for technical applications like paints, adhesives, household and industrial cleaning products. ideal for use in aqueous and water miscible systems broad antimicrobial spectrum against bacteria, fungi and yeasts often effective where other preservatives fail free from formaldehyde, formaldehyde releasers, phenolics or heavy metals good chemical stability non-volatile excellent long-term efficacy belongs to the best evaluated broad spectrum biocides Vinkocide CMI 14 meets the highest purity standards. Impurities are often the cause of undesired side effects in terms of toxicological or technical properties. Also the efficacy can be influenced by impurities. These are reduced to a minimum in Vinkocide CMI 14. Vinkocide CMI 14 penetrates the cells of microorganisms, reacts with vital parts of the cell and inactivates important substrates and enzymes necessary to normal cell function. These relatively unspecific reactions prevent the development of microbial adaptation. Vink Chemicals GmbH & Co. KG, Eichenhöhe 2, D-21255 Kakenstorf, Tel. + 4 4186/8877-0, Fax.: +4 4186/8877-10 2015-0-25 Page 1 of 6

Vinkocide CMI 14 prevents microbial deterioration of products and the resulting effects such as: - phase separation - odor build up - gas build up - changes in viscosity - build up of health threatening toxins Minimum inhibition concentrations: MIC / ppm a.i. Bacteria Fungi, yeasts Bacillus subtilis Enterobacter aerogenes Escherischia coli Klebsiella pneumoniae Proteus vulgaris Pseudomonas aeruginosa Pseudomonas cepacia Salmonella cholerasuis (typhi) Staphylococcus aureus Aspergillus niger Aspergillus oryzae Chaemotomium globosum Penicillium funiculosum Pullularia pullulans Candida albicans Saccharomyces cervisiae 11,5 11,5 11,5 2,3 Vinkocide CMI 14 is effective against Legionella. Concentrations as low as 4 ppm a.i. lead to a significant reduction of Legionella pneumophila. Vink Chemicals GmbH & Co. KG, Eichenhöhe 2, D-21255 Kakenstorf, Tel. + 4 4186/8877-0, Fax.: +4 4186/8877-10 2015-0-25 Page 2 of 6

APPLICATION NOTES Under certain physico-chemical conditions the stability of CIT/MIT can be limited. Therefore we recommend testing the compatibility in individual formulations. For special formulations it can be desirable to combine Vinkocide CMI 14 with further biocides. Depending on the individual demands Vinkocide CMI 14 can be combined with most commonly used biocides. It can be used in a ph range of 3-8,5. Temperatures > 40 50 C should be avoided. Under normal use patterns concentrations (w/w) of 0,01 0,025 % are sufficient in most applications. Vinkocide CMI 14 is used for technical applications. For better dosing pre-dilutions can be made. Such pre-dilutions should not be stored for a long time. Storage conditions: Keep away from freezing, heat and direct sun. Store in original package at room temperature. Packaging: Shelf lift: 25 kg, 200 kg, 1.000 kg 24 months Product selection: Vinkocide CMI 14 is available with different stabilizers. The selection of stabilizing salts can influence the efficacy. Usually copper salts result in a slightly higher efficiency. Also the matrix of the formulation to be preserved is important for the selection of the right biocidal product. Vinkocide CMI 14 is an aqueous, magnesium stabilized solution of 14 % CIT/MIT. Vinkocide CMI 14 M is an aqueous, monovalent stabilized solution of 14 % CIT/MIT. Vinkocide CMI 14+ is an aqueous, magnesium and copper stabilized solution of 14 % CIT/MIT. Vink Chemicals GmbH & Co. KG, Eichenhöhe 2, D-21255 Kakenstorf, Tel. + 4 4186/8877-0, Fax.: +4 4186/8877-10 2015-0-25 Page 3 of 6

Recommended Applications: PT 2 - Disinfectants and algaecides not intended for direct application to humans or animals Water bed fluids PT 6 In-can preservatives Products used for the preservation of manufactured products, other than foodstuffs or feedingstuffs, in containers by the control of microbial deterioration to ensure their shelf life. dispersion paints printing inks dispersion plasters polymer dispersions Adhesives, Glues sealants Kaolin-, chalk-, starch-slurries Pigment slurries Cleaning- and household Products Car care products wax emulsion concrete additives building materials Leather and textile fountain solutions PT 11 Preservatives for liquid-cooling and processing systems Products used for the preservation of water or other liquids used in cooling and processing systems by the control of harmful organisms such as microbes, algae and mussels. Cooling and processing systems Air-conditioning systems oil production Textile and spinning fluids Paint spray booths and electrodeposition coating systems PT 12 Slimicides Products used for the prevention or control of slime growth on materials, equipment and structures, used in industrial processes, e.g. on wood and paper pulp, porous sand strata in oil extraction. Slimicide Pulp and cellulose production Papermaking oil production Fracking Flotation PT 13 Metalworking-fluids preservatives Products used for the preservation of metalworking fluids by the control of microbial deterioration. Metal working fluids Vink Chemicals GmbH & Co. KG, Eichenhöhe 2, D-21255 Kakenstorf, Tel. + 4 4186/8877-0, Fax.: +4 4186/8877-10 2015-0-25 Page 4 of 6

REGULATIONS EU: For the active ingredients the transitory periods of the biocidal products regulation 528/2012/EC are valid. Intended applications: PT 2, 6, 11, 12, 13. Make sure that the biocide is allowed for any further downstream uses. Authorized as an additive for aqueous polymer dispersions in contact with food (EC/135/2004), Ref.-No. 66755 Meets the requirements of the EU Ecolabel 2014/312/EC (indoor and outdoor paints and varnishes) Meets: Framework Resolution RESAP (2004)1 on Coatings Intended to Come Into contact with Foodstuffs - Version 3-12 February 200: PM/REF-No.: 43760 Meets the requirements of: Toy Safety Directive 200/48/EC EU-national: Germany: please ask us BAuA-No.: CMI 14: N-52835 (PT 2) N-52833 (PT 6) N-38780 (PT 11) N-52831 (PT 12) N-5282 (PT 13) CMI 14+: N-53438 (PT 2) N-44237 (PT 6) N-5343 (PT 11) N-53440 (PT 12) N-53441 (PT 13) CMI 14 M: N-62753 (PT 2) N-43585 (PT 6) N-62754 (PT 11) N-62755 (PT 12) N-62756 (PT 13) Meets BfR XIV. (Plastics Dispersions) Meets BfR XXXVI. (Paper and board for food contact) Meets RAL UZ 102 (low emission paints) Meets RAL UZ 12a (low emission varnishes) Meets RAL UZ 113 (low emission floor-covering adhesives) WGK: 3 Vink Chemicals GmbH & Co. KG, Eichenhöhe 2, D-21255 Kakenstorf, Tel. + 4 4186/8877-0, Fax.: +4 4186/8877-10 2015-0-25 Page 5 of 6

Australia: Canada: China: Japan: Korea: New Zealand: Philippines: Taiwan: USA: AICS The active ingredients are listed in the inventory of chemical Substances DSL IECSC ENCS KECI The active ingredients are listed in the inventory of chemical Substances NZIOC PICCS NECI TSCA meets FDA 21 CFR 175.105 (adhesives with food contact) 175.300 (Resinous and Polymeric Coatings) 175.320 (Resinous and polymeric coatings for polyolefin films) 176.170 (components of paper and paperboard in contact with Aqueous and fatty food) 176.300 (paper slimicides) Our recommendations regarding our products are given in good faith, but imply no corresponding liability. Our Conditions of Sales and Supply apply in all other respects. Use biocides safely. Always read the label and product information before use. Vink Chemicals GmbH & Co. KG, Eichenhöhe 2, D-21255 Kakenstorf, Tel. + 4 4186/8877-0, Fax.: +4 4186/8877-10 2015-0-25 Page 6 of 6