GTC Tour. Coffeyville Resources Nitrogen Fertilizer. June 17, 2008

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GTC Tour of Coffeyville Resources Nitrogen Fertilizer Facility June 17, 2008

Coolwater Demonstration Project

Coffeyville Nitrogen Plant

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

Block Flow Diagram Linde ASU Nitrogen Ammonia Synthesis Hydrogen UAN Plant NH 3 Product UAN Product Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

Linde Air Separation Unit

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Slag Sulfur Recovery H 2 S

Refinery Cokers

Coke Handling

Coke Conveyor and Rod Mill Structure

Main and Spare Gasifier Structures

M Main Gasifier Vessel

Slag

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Raw H 2 CO 2 Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

CO 2 Absorber

H2S Concentrator and Stripper

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Tessenderlo Kerley Sulfur Recovery H 2 S

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen CO2 Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification CO2 Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Raw H 2 Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

PSA Vessels

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis Hydrogen UAN Plant UAN Product Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

Ammonia Synthesis and Refrigeration

Syn-gas and Refrigeration Compressors

Ammonia Storage Tank

Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis Ammonia UAN Plant UAN Product Oxygen Quench Gasifier Hydrogen Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S

UAN Plant

UAN Rail Loading Facility

Operators at work in the control room

Nitrogen Fertilizer 101

Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants

Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants It does not build up in the soil, so it needs to p be applied each growing season

Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen.

Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen. In 2005, the US produced 8.7 million tons of ammonia.

Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen. In 2005, the US produced 8.7 million tons of ammonia. In 2005, the US consumed 14.7 million tons of ammonia.

Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen. In 2005, the US produced 8.7 million tons of ammonia. In 2005, the US consumed 14.7 million tons of ammonia. Nearly all was produced using natural gas!

Nitrogen Fertilizer 102

Nitrogen Fertilizer 102 Ammonia cash cost build-up (example) Gas Cost $10 per mmbtu x Gas consumption 32 mmbtu per short ton = Gas cost $320 per short ton + other production costs $20 per ton = Total Cash Cost $340 per ton

Nitrogen Fertilizer Market Global market

Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US

Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US US Production is in decline primarily due to low cost gas overseas

Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US US Production is in decline primarily due to low cost gas overseas Due to infrastructure limitations (pipelines, rail cars), domestic plants continue to operate when the demand (and price) support it.

Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US US Production is in decline primarily due to low cost gas overseas Due to infrastructure limitations (pipelines, rail cars), domestic plants continue to operate when the demand (and price) support it. US Demand is set by acres of corn (primarily) and wheat (to a lesser extent).

The future looks bright for Gasification!