FIELD TESTING ALGAE TREATMENT OPTIONS FOR CLASS B & C RECYCLED WATER LAGOON STORAGES. David Diaz & Shane Smith. Yarra Valley Water

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FIELD TESTING ALGAE TREATMENT OPTIONS FOR CLASS B & C RECYCLED WATER LAGOON STORAGES Paper Presented by: David Diaz & Shane Smith Authors: David Diaz, Process Engineer, Shane Smith, Eastern Treatment Plant Co-ordinator, Yarra Valley Water 75 th Annual Water Industry Engineers and Operators Conference Bendigo Exhibition Centre 4 to 6 September, 2012 75 th Annual Victorian Water Industry Engineers & Operators Conference Page No. 36

FIELD TESTING ALGAE TREATMENT OPTIONS FOR CLASS B & C RECYCLED WATER LAGOON STORAGES David Diaz, Process Engineer, Yarra Valley Water Shane Smith, Eastern Treatment Plant Co-ordinator, Yarra Valley Water ABSTRACT Historically, Yarra Valley Water (YVW) has experienced seasonal blue-green algal blooms which restrict the ability to supply recycled water to customers and often require the use of costly algaecides to control. During 2011/12, YVW conducted an investigation into several alternate control methods promoted as preventing the formation of BGA blooms. The intent of the study was to develop an understanding of their; mechanisms of action, ease of implementation and effectiveness. The control methods investigated included application of barley straw, surface aeration, ultrasonics and lagoon recirculation systems. An additional study was commissioned to ensure that the application of barley straw would not compromise the use of recycled water for Class A production from a water quality perspective. The control methods were trialled in four separate recycled water lagoons with another lagoon used as the control. Water level and blue-green algal counts were recorded weekly during the peak reuse summer season in 2011/12. Results suggested algae levels were somewhat controlled throughout the trial period in most lagoons when compared to the control water body, with algae growth occurring only when environmental factors sharply altered. Various external factors during the course of the trial decreased the confidence in determining the effectiveness of the algae treatment methods. 1.0 INTRODUCTION Yarra Valley Water operates a number of relatively small decentralised sewage treatment plants <5ML/day to treat sewage from sewage catchments located on the outskirts of Melbourne which cannot yet be economically connected to the main metropolitan sewage system. Of the five treatment plants examined in this study, only one (Lilydale) is licensed to discharge to a waterway. The other four have no discharge licenses and treated effluent must be reused. Irrigation is the primary method of reuse and may be either on Yarra Valley Water owned sites or supplied to approved recycled water customers such as golf courses or farms. While sewage treatment plants provide a relatively consistent volume of treated effluent, seasonal conditions, as well as recycled water demand, create considerable variability in required flow rates. To overcome the discrepancy between recycled effluent production and reuse, YVW utilises storage lagoons for winter storage and buffering purposes. Table 1: Yarra Valley Water Treated Effluent Storage Lagoon Overview Lagoon Volume (ML) EPA Treatment Standard Aurora 280 Class B Beveridge 160 Class C Lilydale 80 Class B Whittlesea North 80 Class B Whittlesea South 180 Class B Wallan 160 Class C 75 th Annual Victorian Water Industry Engineers & Operators Conference Page No. 37

Figure 1: Winter Storage Lagoons (A. Aurora Storage Lagoon, B. Wallan Storage Lagoon 6, C. Beveridge Storage Lagoon, D. Lilydale Storage Lagoon, E&F. Whittlesea North and South Lagoons) Turnover through the lagoons is rapid in summer with relatively low inflows and high outflows whereas in winter, inflows remain constant but outflows are negligible. Effluent stored at these lagoons is rich with nitrates and phosphorus. Typical levels of nutrients are Nitrogen of 5 mg/l and Phosphorus of 1 mg/l for Class B storages. Class C nutrient levels average Nitrogen of 30 mg/l and Phosphorus of 10 mg/l. These nutrient levels, promote both growth of both green algae and cyanobacteria (Blue Green Algae or BGA ) during summer. Every YVW storage lagoon has experienced BGA activity during summer irrigation seasons. Historically, response measures included isolation of the BGA contaminated effluent water and chemical dosing utilising an approved algaecide (i.e. Coptrol). Given the high community impact to reuse customers of ceasing supply due to BGA exposure, as well as operational costs involved with chemical dosing, an alternative approach was required to provide a lower cost solution to these issues. A number of potential control measures were identified including: surface aeration, ultrasonic algae control, flow recirculation and the application of barley straw. 2.0 DISCUSSION 2.1 Trial Establishment The trial was established to try to distinguish the effectiveness of each algae control method. It was decided that various technologies would be implemented in each lagoon. Aurora lagoon was selected as the control lagoon with no control measures implemented. Assumptions were made to conduct this trial, including that each lagoon system would experience similar climatic conditions, and that algae levels in the lagoons would react similarly to algae treatment technologies. 75 th Annual Victorian Water Industry Engineers & Operators Conference Page No. 38

Monthly algae samples were taken at all lagoons with samples increasing in frequency once blue green algae was detected at a given storage. Algae samples were taken at multiple locations at the surface of the lagoons, and subjected to laboratory assessment for algae count analysis. Table 2: Effluent Storage Algae Treatment Technology Overview Lagoon Ultrasonic Algae Control Barley Straw Surface Aeration & Recirculation Algae Sampling Aurora Beveridge (Nov 2011) Lilydale (Oct 2011) (Nov 2011) Whittlesea North (Jan 2011) (Nov 2011) Whittlesea South (Dec 2011) (Nov 2011) Wallan (Dec 2011) (Dec 2011) 2.2 Surface Aeration & Recirculation (Lilydale Lagoon) An existing surface aerator at Lilydale STP was utilised in the recycled water storage lagoon. A Dissolved Oxygen probe was installed to confirm that the surface aerator was maintaining oxygen levels within the lagoon thereby reducing the likelihood of algae growth (GWRC, pg 11, 2009). A recirculation line was also retrofitted to the Lilydale lagoon to decrease stagnation. The recirculation was also utilised to increase the effectiveness of the surface aeration. 2.3 Ultrasonic Units (Whittlesea North, Whittlesea South and Wallan Lagoon) Ultrasoinc units from two competing suppliers were utilised to test the effectiveness of ultrasonic algae control. One model was deployed in both Whittlesea storages, with the other model being installed at the Wallan storage lagoon. The design and positioning of the units was conducted by the suppliers based on their recommendations. 2.4 Barley Straw (All Lagoons except Aurora Lagoon) Barley straw was sourced from a local farmer. Application rates were selected as 50 g of barley straw per m 2 of lagoon surface (Christensen, pg 524, 2002). The barley straw was bailed into small square bales and wrapped in individual nets prior to immersing them at the water s edge. Additionally, the consequences of barley straw for production of Class A recycled water was unknown. Consequently, YVW engaged ALS to undertake a water quality study to identify any chemical contaminants that might be released into the water body during the decomposition of the barley straw. Of particular concern were chemical herbicide and pesticides which that may have been present. 2.5 Aurora Barley Straw Experimentation Results Barley Straw experimentation conducted at Aurora lagoon determined that there was negligible presence of heavy metals or chemicals in the recycled water exposed to barley straw, with the exception of tebuconazole, a fungacide detected in insignificant concentrations. 75 th Annual Victorian Water Industry Engineers & Operators Conference Page No. 39

The application of barley straw was therefore deemed to be safe for use in Class A treatment technologies provided that application rates remained below 1kg/50L, the point at which unacceptable levels of contaminants formed (ALS, pg 27, 2012). Unfortunately, there was no clear mechanism of action identified for determining how barley straw could reduce algae concentrations. The simulated experimentation and subsequent analysis determined no clear linkages between the recycled water quality and potential effects on algae growth dynamics (ALS, pg 2, 2012). 2.6 Algae Treatment Technology Results Algae sampling results were collected throughout the irrigation season and concluded in April 2012. Additionally, BGA levels were also measured and concentrations were scaled against the alert framework in Management Strategies for Cyanobacteria (Blue-Green Algae): A Guide for Water Utilities (WQRA, pg 37, 2010). Algae levels were compared to lagoon characteristics to identify possible causes for increased algae concentrations. Although the majority of the investigations were focused towards identifying BGA impacts, other algae species were also investigated and results are discussed later on. Figure 2: Beveridge Lagoon Blue Green Algae Results against Storage Levels Beveridge lagoon experienced one significant BGA outbreak event in March 2012. This coincided with rapid turnover of the storage due to the irrigation demand. The combination of high temperature, sudden increases in nutrient rich water and stirred up water increases the potential for BGA growth (WQRA, pg 26, 2010). Identical patterns were seen with the Wallan, Aurora and Whittlesea Lagoons. Whittlesea Lagoon was seen to trigger BGA outbreaks once lagoon levels stabilised for over 3 months, indicating stagnation could be a potential factor towards algae growth. Whittlesea recycled water also has higher ph than storage water from the other sites assessed, a key factor for the domination of algae growth (GWRC, pg 4, 2009). 75 th Annual Victorian Water Industry Engineers & Operators Conference Page No. 40

Whittlesea South Lagoon did not experience a BGA outbreak. This lagoon had previously been quarantined from the supply network due to high ph identified in the recycled water, and several algae outbreaks had occurred in 2010/11. Considering algae outbreaks consume readily available nutrients in water bodies (GWRC, pg 5, 2009), it is likely there was little nutrients available in the 2011/12 period for a BGA outbreak to occur. Lilydale Lagoon also did not experience any significant BGA levels during the 2011/12 investigation period. Beveridge Aurora Wallan Figure 3: Total Algae Counts from Each Storage Lagoon (Stacked Area Graph) From the above graph it is evident that Aurora lagoon had a consistently high number of algae levels. As a control site, this was to be expected, however operational changes in mid December may also have contributed. Table 3: Algae Treatment Effectiveness Summary Lagoon BGA Outbreak Duration Total Algae Levels Preliminary Treatment Effectiveness Aurora 4 Months Very High N/A - Control Site Beveridge 2 Months Very High Poor Lilydale - Low Good Whittlesea North 1 Month Low Good Whittlesea South - Low Good Wallan 1 Month Medium Average The Beveridge Lagoon experienced significant algae activity, as did Wallan Lagoon to a lesser degree. 75 th Annual Victorian Water Industry Engineers & Operators Conference Page No. 41

Both Beveridge and Wallan Lagoons store Class C recycled water, which inherently have significantly higher levels of nutrients (particularly phosphorus) than other lagoons. As such, algae levels were anticipated to be higher. It is important to note that the Wallan Lagoon showed consistently lower levels of algae compared to Beveridge. Finally, the Lilydale Lagoon was shown to have one of the lowest total algae levels of any lagoon site. This correlates to the low BGA levels discussed earlier. Determining the relative contribution of surface aeration, barley straw or recirculation had on these results is beyond the scope of this assessment. However these results are promising and indicate that this combination of technologies (whether individually or together) has successfully managed algae levels. 3.0 CONCLUSION Field tests determined that treatment technologies had difficulty managing algae in Class C recycled water effluent, however Class C lagoons with ultrasonic technologies installed maintained lower algae levels than the control site. Lagoons with ultrasonic units demonstrated lower total algae counts, with BGA outbreaks still occurring. However BGA outbreak causes were able to be traced back to operational changes to the lagoon. Lilydale and Whittlesea Lagoons performed best; likely due to a combination of high flow turnover and a raft of algae treatment technologies. Barley straw appears to have had minimal effect on reducing BGA outbreaks. The only site where barley straw was the sole control measure was Beveridge which performed poorly. Additionally, further investigations will need to be conducted to improve ph levels within the lagoons, as no treatment technology succeeded in preventing ph from rising above 9.0. Finally, recirculation and surface aeration will need to be assessed individually in future irrigation seasons to determine their individual effectiveness in algae management. 4.0 ACKNOWLEDGEMENTS I would like to thank Treatment Plant Operations staff Ray Crilly, Grant Donnelly, Clint Vandepeer and Daryl Haag for their collaborative efforts in establishing these trials and sharing their site knowledge. 5.0 REFERENCES GWRC, 2009. International Guidance Manual for the Management of Toxic Cyanobacteria. Developed by Global Water Research Coalition in conjunction with SA Water. Alliance House, United Kingdom. Christensen, Bent T 2002. Barley straw decomposition under field conditions: Effect of placement and initial nitrogen content on weight loss and nitrogen dynamics. Soil Biology and Biochemistry (Volume 18, Issue 5, 1986, Pages 523 529) WQRA, 2010. CRC for Water Quality and Treatment Project No. 2.0.2.4.1.2: Management Strategies for Cyanobacteria (Blue-Green Algae): a Guide for Water Utilities. Copyright Water Quality Research Australia Limited. Research Report 74 ISBN 18766 16245. 75 th Annual Victorian Water Industry Engineers & Operators Conference Page No. 42