Wastes and Recycling

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Lecture 12 Wastes and Recycling Brown, M.T and V. Buranakarn, 2002. Emergy indices and ratios for sustainable material cycles and recycle options. Resources, Conservation and Recycling Vol. 38:1 pp 1-22.

To recycle or not to recycle that is the question.

Emergy Evaluations of Material Systems and Recycle Options

Recycle Pathways Recycle of waste products follows one of three pathways... Tidal Energy Geologic Processes 1. 2. Fuels, Materials Stock Pile 3. Recycle Soils, Wood Assets Sunlight Environmental Systems Economic Systems Wastes Biosphere

Scope of the Study Study focuses on recycling patterns of major building materials. For each major material, three different patterns of building material cycles were evaluated: 1. emergy of manufacture from raw resources, 2. emergy of demolition, and 3. emergy of recycle. In addition, the emergy costs of landfilling of materials were also evaluated.

Materials Evaluated Building Material Use as Finish Use as Structure Cement mortar -- Concrete pavement column or beam Masonry clay tile clay brick Ferrous metal wall panel column or beam Non-ferrous metal aluminum sheet column or bean Wood plywood post or beam Plastics vinyl floor plastic lumber Glass ceramic tile --

Emergy Analysis of Recycle 4 Material Cycles Evaluated Standard material cycle Standard cycle with RECYCLE By-product use Adaptive reuse

Material Cycles Energy, Goods Labor, Service Env. Sources Environment Matr'l Extraction Refine Transform Use Landfill Standard material cycle...

Material Cycles Energy, Goods Labor, Service Env. Sources Environment Matr'l Extraction Refine Transform Use Recycle Landfill Standard cycle with RECYCLE...

Material Cycles Energy, Goods Labor, Service Env. Sources Environment Matr'l Other Process Byproduct Extraction Refine Transform Use Landfill By-product use.

Material Cycles Energy, Goods Labor, Service Env. Sources Environment Matr'l Other Process Use Recycle Extraction Refine Transform Use Landfill Adaptive reuse...

Recycle Indices Performance and Efficiency Ratios Recycle Benefit Ratio (RBR) Recycle Yield Ratio (RYR) Landfill to Recycle Ratio (LRR) Recycle Efficiency Ratio (RER)

Recycle Indices Recycle Benefit Ratio (RBR) the ratio of emergy used in providing a material from raw resources (A1) to the emergy used in recycle (F).

Recycle Indices Recycle Yield Ratio (RYR) The ratio of emergy in recycled material (E2) to emergy used for recycle (F).

Recycle Indices Landfill to Recycle Ratio (LRR) The ratio of emergy required for landfilling a material (C1) to the emergy required for recycle (F).

Recycle Indices Recycle Efficiency Ratio (RER) The ratio of material and energy conserved when recycled materials are used to the emergy required for recycle.

Recycle Ratios Fuels, Goods, Service Raw resource A 1 B 1 C 1 F 1 R 1 Refine Transform Use Collection RBR = A 1 /F 2 RYR = Y/F 2 LRR = F 1 /F 2 RER = [(R 1 +A 1 +B 1 +F 1 )- (R 2 +A 2 +B 2 +F 2 )]/F 2 Conventional Solid Waste System Fuels, Goods, Service Landfill Raw Resource R 2 A 2 B 2 C 2 Refine Transform Use Collection F 2 Recycle Y Recycle System

Solid Wastes Emergy Intensity of Solid Waste Cololection an Emergy Intensity of Solid Waste Collection & Disposal Service Emergy (E6 sej/g) Municipal solid wastes Collection 233 Separating 8.2 Landfilling 35.2 Construction and Demolition Wastes Demolition 49.1 Truck transportation 19.7 Sorting 6.7

Life Cycle Emergy Intensity of Building Materials Material Raw Mat'rl Production Construction Demolition Collection Landfill Total (E9 sej/g) Cement 1.06 0.92 2.14 0.048 0.019 0.013 4.2 Cement w/ fly ash 1.04 1.16 2.14 0.048 0.019 0.013 4.42 Concrete 0.44 1 2.14 0.048 0.019 0.013 3.66 Concrete w/ recycled aggregate 0.44 1 2.14 0.068 0.035 3.68 Clay brick 2.0 0.22 2.14 0.048 0.019 0.013 4.44 Steel 2.44 1.71 2.14 0.048 0.019 0.013 6.37 Recycled steel 1.59 2.45 2.14 0.048 0.109 6.34 Aluminum 2.16 10.54 2.14 0.048 0.019 0.013 14.92 Recycled aluminum 0.65 12.05 2.14 0.048 0.149 15.04 Wood lumber 0.59 0.29 2.14 0.048 0.019 0.013 3.1 Recycled Lumber 0.59 0.75 2.14 4.95 0.45 8.88 Plastic 3.62 2.13 2.14 0.048 0.019 0.013 7.97 Plastic lumber w/ recycled plastic 3.62 2.45 2.14 0.048 0.26 8.52 Ceramic tile w/ recycled glass 0.82 2.24 2.14 0.048 0.019 0.013 5.28 Ceramic tile w/ recycled glass 0.82 2.53 2.14 0.048 0.08 0.013 5.63 Glass 1.35 6.52 2.14 0.048 0.019 0.013 10.09 Glass w/ in-house recycle 0.72 6.94 2.14 0.048 0.019 0.013 9.88

Recycle Indices Recycle Indices of Building Materials Material RBR RYR LRR RER Cement with fly ash 9.2 2.2 0.8 20 Concrete with recycled aggregate 2.3 2.9 0.5 10 Recycled steel 3.4 6.9 0.7 34 Recycled aluminum 49.9 42.5 0.4 64 Recycled lumber 0.05 0.1 0.01 0.16 Plastic lumber from recycled plastic 3.3 18.9 0.3 22 Ceramic tile from recycled glass 32 17.7 1.1 45 RBR = Recycle Benefit Ratio RYR = Recycle Yield Ratio LRR = Landfill to Recycle Ratio RER = Recycle Efficiency ratio

Conclusions Materials and material quality 1.Emergy per mass may be a good indicator of recycle-ability. 2.The emprice (emergy received for money spent) is highest for primary building materials and lowest for materials that contain more human services. 3.Quality and versatility of a material are related to emergy per mass. The larger the emergy per mass, the more valuable and versatile the product and the greater the potential for recycle. 4.The emergy yield ratio (EYR) may provide important information regarding recycle-ability. 5.Price, expressed as mass per dollar is inverse to the amount of human service inputs to a material s production.

Conclusions Recycling Patterns 1. Materials that have large refining costs have greatest potential for high recycle benefits. 2. The highest benefits to society appear to accrue from material recycle systems, followed by adaptive reuse systems, and finally by by-product reuse systems. 3.The landfill recycle ratios for all the material recycle systems studied, with the exception of glass, were less than one. This may result from the fact that environmental impacts of landfilling were not evaluated. 4.The yields from recycling are extremely high, far greater than the yields that society obtains from energy sources indicating the very important contributions that effective recycling systems will have in the long run.

Recycle Emergy Information. information.. EMformation

Recycle Emergy Processes of divergence disorder structure and disperse materials and information. Processes of convergence build order, adding structure, reassembling materials, upgrading energy and creating new information. Energy Sources Disorded Parts Order Material dispersal/recycle Production of Order Depreciation of Order

Cycle Emergy Systems of the biosphere are maintained by flows of energy that cycle materials and information. Without continual flows of input energy that build order, systems degrade away. It is through cycling that systems remain adaptive and vital. Energy Sources Divergence Materials Information Convergence

Emformation All processes require three driving energies Energy Information Matter

Emformation A material and energy hierarchy. Materials are concentrated with each transformation, while increasing quantities of energy are required, thus emergy/gram increases. Two types of recycle pathways are shown, a dispersal pathway where the materials carry no emergy, and material recycle pathways where the materials carry some emergy as they are recycled

Emformation

Emformation Form as Information

Emformation Emergy in Material and Form Material Table 3. Material emergy and Raw Emformation* Material of common Production/Construction building materials Material Raw Material (E9 sej/g) Finished Product (E9 Emformation* sej/g) (E9 sej/g) (E9 sej/g) (E9 sej/g) Wood Lumber 0.59 2.43 Glass Wood Lumber 0.59 1.35 2.43 8.66 1.84 (76%) Aluminum Glass 1.35 2.16 8.66 12.68 7.31 (84%) Steel Aluminum 2.16 2.44 12.68 3.85 10.52 (83%) Steel 2.44 3.85 1.41 (37%) *Emformation is equal to the difference between emergy of the finished product and the raw material emergy.

Emformation

Emformation If they crush the can then its emergy is 2.4 E10 sej/g

Emformation The emergy of the product equal to the sum of the inputs (7.9 E10 sej) and UEV = 1.8 E9 sej/g The UEV of the waste flow equals the sum of the inputs divided by the total quantity of material produced (product + waste), (6.6 E8 sej/g) and the emergy equals 76 * 6.6 E8 = 5.0 E10 sej

Emformation

Emformation Without can recycle With can recycle

Questions? Comments? Concerns?