PV MODULE RELIABILITY ISSUES INCLUDING TESTING AND CERTIFICATION. Ulrike Jahn, TÜV Rheinland

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PV MODULE RELIABILITY ISSUES INCLUDING TESTING AND CERTIFICATION Ulrike Jahn, TÜV Rheinland Frankfurt, 24 September 2012

Outline Introduction IEC qualification testing Statistics of laboratory test failures Most frequent test failures and causes of module failures For c-si: DH, TCT (200), HF, ML, HS For TF: DH, ML, RC, HS Extended laboratory testing Conclusions

Introduction Reliable operation of PV modules Irradiance: sun, sky Temperature: heat, frost, night-day cycles Humidity Mechanical stress: wind-,snow load hail impacts Moisture: rain, dew, frost Atmosphere: Salt mist, dust, sand, pollution PV modules are complex products that combine materials of different physical and chemical properties.

Introduction Reliability Testing IEC test standards for product qualification of PV modules as a minimum requirement to undertake reliability testing. The primary goal of IEC testing is to identify the initial short-term reliability issues in the field. IEC 61215: c-si PV modules IEC 61646: Thin-film PV modules IEC 62108: CPV modules Extended IEC testing is typically applied to reveal weaknesses in the construction Failure Rate Early failures Random failures Degradation Wear-out failures Open the box failure Time of Operation

IEC standards Type approval of PV modules according to IEC 61215 and IEC 61646

IEC Qualification Testing Monitoring of degradation Degradation parameter Visual changes (Yellowing, soiling, corrosion etc.) Deterioration of max. power Insulation resistance Internal series resistance Microcracks in cells, interruptions of electrical interconnection circuit Test method / procedure Visual inspection Max. power characterisation at STC (5% threshold in IEC 61215) Dry insulation test Wet insulation test I-V measurement at 3 irradiances and constant module temperature Electroluminescence (EL) record I TEST = I SC,STC

IEC Qualification Testing Pass criteria for TF modules After completion of all test sequences, the following pass criteria have to be fulfilled: Final STC output power after stabilization (e.g., light-soaking) at least 90% of the minimum rated power : (0.9 x (P manufacturer tolerance)) Minimum requirements for the electric insulation (dry and wet) fulfilled: R iso > 40 MΩ / A [m²] (A = module area) No major visual defects detected

IEC Qualification Testing Failure rates c-si and TF modules (2007-2011)

IEC Qualification Testing Failure rates c-si modules (2007-2011)

IEC Qualification Testing Failure rates c-si modules (2007-2011)

Critical Tests for c-si Damp Heat Test (DH) 1000 h, 85 C, 85% RH DH is a stress test for the quality of the used encapsulant (moisture protection) Failure cause: Delamination due to processing, contamination, material properties Back sheet adhesion loss (lamination problems) Corrosion

Critical Tests for c-si Thermal Cycling Test (TCT) 200 cycles, -40 C to +85 C TCT is a stress test for cell connectors due to different thermal coefficients of glass, Si wafer and copper Failure cause: Thermo-mechanical stress

Critical Tests for c-si Humidity Freeze Test (HF) 10 cycles, -40 C to +85 C, 85% RH HF is stress test for cell connectors due to different thermal coefficients of glass, Si and copper Failure cause: Thermo-mechanical stress

Laboratory Testing Failure mechanism: Thermo-mechanical induced stress PV modules combine materials with different coefficients of thermal expansion (glass cover, polymeric encapsulation, solar cells, polymeric back sheet, metal parts of internal wiring) Degradation processes may occur originating from thermomechanically induced stresses to interconnects (cyclic movement of cells) of loss of adhesion strength at interfaces [1] Glass cover Solar cell Back sheet Cell interconnect / copper ribbon coated with solder Encapsulant [1] S. Dietrich: Mechanical and Thermo-Mechanical Assessment of Encapsulated Solar Cells by Finite-Element-Simulation, SPIE Optics+Photonics, 2010

Critical Tests for c-si Mechanical Load Test (ML) Uniform loads of 2400 Pa, applied for 1 hour to front and back surfaces in turn ML is a stress test for the mechanical quality of modules (frame, glass, laminate) in combination with mounting system Failure cause: High wind and snow loads

Critical Tests for c-si Hot Spot Test (HS) Shading of one cell of the module HS is a stress test for cell quality Failure cause: Different cell qualities Local defects, shunts in wafer Shunts due to soldering problems

IEC Qualification Testing Failure rates thin film modules (2007-2011)

IEC Qualification Testing Failure rates thin film modules (2007-2011)

Critical Tests for TF Mechanical Load Test (ML) Uniform load of 2400 Pa, applied for 1 hour to front and back surfaces in turn ML is a stress test for the mechanical quality of modules (frame, glass, laminate) in combination with mounting system Failure cause: High wind and snow loads

Critical Tests for TF Reverse Current Test (RC) Apply reverse current to module RC is stress test for cell quality Failure cause: Series fuse rating too high Local heating (e.g., close to JB) glass breakage

Critical Tests for TF Hot Spot Test (HS) Shading of cells of the module HS is a stress test for cell quality Failure cause: Different cell qualities Local defects, shunts HS may lead to overheating of material and glass breakage

Laboratory Testing Extended Thermal Cycling Test 7 crystalline silicon PV modules with intermittent diagnostic measurements after 200, 400, 600 and 800 cycles Results: Pmax change related to initial power 10% 0% -10% -20% -30% -40% -50% M1 M2 M3 M4 M5 M6 M7 Initial TC200 TC400 TC600 TC800 IEC Test level All modules fulfill IEC 61215 test requirements (TC200) Three modules still fulfill IEC 61215 test requirements after TC800 Increased power degradation starting from TC400

Laboratory Testing Extended Thermal Cycling Test Electroluminescence analysis: Variations in brightness across the cell area indicates inhomogeneous current flows between bus bars => Total or incomplete crack of cell connectors Loose contact Change of contact resistance TC200 TC400 TC600

Laboratory Testing Summary of Thermal Cycling Test Breakage of cell connectors is the dominating degradation mechanism for thermal cycling tests of c-si modules in the test lab. EL analysis is appropriate diagnostic method for identification of cracks in internal wiring, but may not find all failures in the interconnection circuit (loose contacts). Cracks are potential locations for heating if all interconnects of a cell are affected by material fatigue. Standard TC200 test does not reveal weaknesses in the module construction and a higher number of cycles may be required (>400). => Compare the relative reliability and durability of different module designs or materials [2] N. Bogdanski: Weighting of climatic impacts on PV-module degradation - Comparison of outdoor weathering data and indoor weathering data, 27th EU PVSEC, 2011

Laboratory Testing Extended Damp Heat Test High power degradation observed for > 2000 hours (DH2000: -4%, DH3000: -28%) Major failure mechanism is corrosion of electrical contacts caused by water ingress into the encapsulation => Increase of module internal series resistance I [A] 6 5 4 3 2 1 0 1000 h 2000 h 3000 h 0 10 20 30 40 50 U [V] 3000 h 2000 h 1000 h

Laboratory Testing Extended Damp Heat Test Degradation behaviour of 8 modules of the same type and production lot is different, indicating the dominance of various degradation mechanisms (both FF and I sc affected). P MAX degradation beyond -5% threshold is observed beyond 2000 h exposure. 1.0% Initial DH1000 DH1500 DH2000 0.0% -1.0% Pmax change -2.0% -3.0% -4.0% -5.0% -6.0% -7.0%

Laboratory Testing Summary of Damp Heat Test Power degradation is not the dominating failure mechanism (<30% of total DH failure rate) Other degradation mechanisms also important EL analysis can visualize propagating corrosion starting from cell edges Junction box area may be a week point of the module design regarding moisture ingress Initial 1000 h 1500 h 2000 h Corrosion effects will appear for >2000 h exposure time [2] N. Bogdanski: Weighting of climatic impacts on PV-module degradation - Comparison of outdoor weathering data and indoor weathering data, 27th EU PVSEC, 2011

Conclusions (1) Failure rates of IEC qualification testing tend to decrease over the past years due to advanced/advancing technologies and improved quality control (both c-si and TF) Most test failures are due to problems in module processing and quality control issues. Most frequent failures causes of IEC qualification are: soldering problems, lamination problems and glueing materials for c-si.

Conclusions (2) PV modules are complex products and are subject to fabrication and material-related tolerances: Degradation processes and long-term reliability are complex and may not be uniform for modules of the same construction and type; For laboratory tests also variations in test conditions need to be considered. IEC test levels are normally not sufficient to find out weaknesses in the module construction. For c-si modules enhanced degradation will appear beyond 2000 hours test duration for Damp Heat Test and beyond 400 cycles for Thermal Cycling Test. More sophisticated non-destructive diagnostic tools are needed to better monitor degradation processes on module and materials level.

Acknowledgements To all colleagues from the TÜV Rheinland R&D team for their contributions To all colleagues from the TÜV Rheinland thin-film team for their support To the German Federal Ministry for the Environment, Nature Conversation and Nuclear Safety for the funding of this project under contract number 0325194A IEA PVPS TASK13.

Thank You for Your Attention!