Perspectives on ethanol sustainability in Brazil

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Symposium BGW 2012 Bagasse Gasification Week FAPESP, São Paulo, Brazil September, 2012 Perspectives on ethanol sustainability in Brazil Luiz A. Horta Nogueira Universidade Federal de Itajubá, Brazil 1

Symposium BGW 2012 Bagasse Gasification Week Aggregating science and technology to a traditional agro-industry, ethanol from sugarcane became a sustainable and competitive alternative for the current and future energy supply. Outline Context: bioenergy is relevant abroad and in Brazil The evolution of Brazilian bioenergy agro-industry Sustainability of sugarcane bioenergy: new facts Final comments 2

Symposium BGW 2012 Bagasse Gasification Week Context: bioenergy in the global scenario More and more, the main drivers towards a global energy transition; concerns on oil dependence and energy costs, global and local environmental problems, opportunity for economic activation of agro-industrial sector, are reinforced and fostered biofuels production and use abroad Global production of liquid biofuels (IEA, 2011) 3

Symposium BGW 2012 Bagasse Gasification Week Context: bioenergy in the global scenario as well as biofuel demand forecasts are indicating a huge market for bioenergy in the next decades. Global energy use in the transport sector and use of biofuels in different transport modes in 2050 (BLUE Map Scenario, IEA, 2011) 4

Context: bioenergy in Brazil Symposium BGW 2012 Bagasse Gasification Week Biofuels always accounted for a significant share of Brazilian energy matrix. Currently, sugar cane, wood and several waste biomass mean about 1/3 of total domestic energy consumption. Primary energy production in Brazil (EPE, 2011) 5

Symposium BGW 2012 Bagasse Gasification Week Context: the sugarcane energy in Brazil Sugarcane energy products (ethanol and electricity) demand in Brazil is equivalent to about 800 thousand barrels of oil per day. More than 30 million Brazilian cars run using ethanol, either pure (E100) or blended with gasoline (E25-E18). The area occupied with sugarcane plantation for energy represents a small share of arable land (<1%), with reduced impacts on biodiversity and the production of other agricultural products. Typical sugarcane mill in the Brazilian Center South region (BNDES, 2009) 6

Symposium BGW 2012 Bagasse Gasification Week The ethanol use: from the beginning Gasoline blended with ethanol has been a mandatory practice in Brazil since 1931 (minimum E5, average E7.5), reinforced after the oil crisis during the seventies, when the use of high blends (E25) in all gasoline motors and pure hydrous ethanol in dedicated motors was adopted. Ford Model T adapted for pure ethanol, used for public demonstrations in the 20 s 25% % ethanol % etanol 20% (INT, 2006) 15% 10% 5% Ethanol content in the Brazilian gasoline (BNDES, 2008) 0% 1925 1945 1965 1985 2005 7

Symposium BGW 2012 Bagasse Gasification Week The ethanol evolution: flex-fuel motors Vehicles with motors able to use any blend of pure hydrous ethanol (E100) and gasoline (E25), presenting good performance and accomplishing environmental requirements, were introduced successfully in the Brazilian market and today represents around 90% of new cars in the light vehicles fleet. 100% ethanol Hydrous Ethanol (6% water) Brazilian gasoline E25 to E20 Two phases region Ternary diagram ethanol/gasoline/water (CTC, 2004) 100% gasoline 100% water

Symposium BGW 2012 Bagasse Gasification Week New frontiers for ethanol use Besides the regular use as pure hydrous ethanol and in blend with gasoline, new interesting opportunities are opening new and promising markets for bioethanol. Airplane regularly produced to use pure hydrous ethanol (EMBRAER, 2008) Bus with Diesel engine able to use hydrous ethanol (BEST, 20099)

Symposium BGW 2012 Bagasse Gasification Week The ethanol evolution: productivity In the last three decades many improvements has been introduced in ethanol production, multiplying the total productivity by 2.6, due to agronomic and industrial gains. (CONAB/MAPA, 2010) 10

Symposium BGW 2012 Bagasse Gasification Week Context: the sugarcane energy in Brazil There is a large area for expansion of sugarcane in Brazil, currently occupied by low productivity pastures. Brazil s total area ( 851 Mha, 100%) Brazilian farm s area ( 355 Mha, 42%) Cultivated area ( 76,7 Mha, 9%) Area in sugarcane for ethanol ( 3,6 Mha, 0,5%) Similar situation is observed in several developing countries. (IBGE, 2008)

Symposium BGW 2012 Bagasse Gasification Week The ethanol evolution: productivity To reduce the competition for natural resources, efficiency is crucial at any level. For animal protein this aspect is more relevant yet. Million heads or Million ha PASTURE AREA BOVINE HERD Average density ~ 1 animal/ha In Brazil, better practices in calf breeding can liberated about 75 M ha. (FGV, IBGE, 2008)

Symposium BGW 2012 Bagasse Gasification Week Sustainability: role of R&D Innovation has been essential for ethanol development. In agronomic or industrial activities, in logistics or management, new techniques are frequently introduced, cutting costs, diversifying products and reducing environmental impacts of ethanol production. The use of water, agrochemicals, fossil fuels in sugarcane energy production is reduced in comparison with other agro systems. 80% 60% 40% 20% 0% 1984 1986 1988 1990 1992 1994 1996 1998 2000 2002 Varietal diversification of sugarcane in Brazil (Burnquist e Landell, 2005) Biological control of sugarcane borer (Diatraea saccharalis) using a wasp (Cotesia flavipes) (Bento, 2006)

Operation Symposium BGW 2012 Bagasse Gasification Week Sustainability: the energy balance One fundamental feature of sugarcane ethanol is its high efficiency in solar energy conversion to chemical energy and consequently fuel energy. Sugar cane production Agricultural operations Cane transportation Fertilizers Lime, herbicides Seeds Equipment Ethanol production Electricity Chemicals and lubricants Buildings Equipment Energy requirements or production (MJ/ tonne of processed cane) average 202 38 43 66 19 6 29 49 0 6 12 31 best values Total energy input 251 232 Energy output Ethanol Bagasse surplus 2089 1921 169 192 38 36 63 19 6 29 40 0 6 9 24 2367 2051 316 Net energy balance (out/in) 8,3 10,2 (Macedo et al., 2006)

Sustainability: new frontiers Symposium BGW 2012 Bagasse Gasification Week 1. Biofuels utilization in cane agriculture and transport Fuel corresponds to approx. 40% of energy consumed in sugarcane production. During the 80 s, alternatives for replacing the conventional diesel oil used in sugarcane agriculture were evaluated. Basically two routes were assessed, with a limited outcome: Ethanol additivation (lubricity and cetane improvers) to allow its use in conventional Diesel motors. Diesel engine conversion ( Ottolization ), reducing compression rate and adding ignition systems in order to make possible hydrous ethanol use. Tractor for ethanol use (66 CV, carbureted electronic ignition) (Ford, 1985) 15

Sustainability: new frontiers Symposium BGW 2012 Bagasse Gasification Week 1. Biofuels utilization in cane agriculture and transport More recently: High performance Diesel engines using low additivation (5%) hydrous ethanol have been launched (Scania, 2008). Biodiesel has been regularly used. Since January 2010 all diesel used in Brazilian trucks has 5% biodiesel (B5). Electronic injection Diesel engine for hydrous ethanol (270 CV) (Scania, 2008) 16

Sustainability: new frontiers Symposium BGW 2012 Bagasse Gasification Week 1. Biofuels utilization in cane agriculture and transport Considering biofuels utilization in agriculture operations and sugarcane transportation, five scenarios were evaluated, taking into account current and prospective conditions of composition and feedstock used in biofuels. Reference scenario: conventional diesel oil Scenario 1: current B5 (methyl biodiesel, 85% soybean oil, 15% tallow) Scenario 2: improved B5 (methyl biodiesel, 85% palm oil, 15% tallow) Scenario 3: optimized B100 (ethyl biodiesel, 85% palm oil, 15% tallow) Scenario 4: E100 (hydrous ethanol, 5% cetane improver additive) 17

Symposium BGW 2012 Bagasse Gasification Week Sustainability: new frontiers 1. Biofuels utilization in cane agriculture and transport To estimate the impact of different fuels on energy consumption and GHG emissions associated to ethanol production and use, a set of data was prepared, considering the current and prospective Brazilian conditions. Diesel and Biofuels basic data (Horta Nogueira, 2010) Biofuel Fossil energy consumption in production (MJ/L) GHG emission factor (kg CO 2 /L) Convencional diesel oil 41,22 2,489 Methyl soybean oil biodiesel 11,16 1,019 Methyl tallow biodiesel 5,50 0,469 Methyl palm oil biodiesel 10,53 0,796 Ethyl palm oil biodiesel 7,40 0,250 Ethyl tallow biodiesel 2,25 0,135 Hydrous ethanol, additived 2,71 0,257 18

Sustainability: new frontiers Symposium BGW 2012 Bagasse Gasification Week 1. Biofuels utilization in cane agriculture and transport For more details on the energy balance and emissions for biodiesel production in Brazil: 19

Sustainability: new frontiers Symposium BGW 2012 Bagasse Gasification Week 1. Biofuels utilization in agriculture and transport Assuming a typical South-Center mill operation, the impact on renewable energy yield and GHG mitigation were assessed. 20

Sustainability: new frontiers 2. Increase of sugarcane mill capacity Symposium BGW 2012 Bagasse Gasification Week Induced by the scale factor in the cost of industrial equipment, the expansion of ethanol production in new areas has been associated with the increase of processing capacity. In the last two years the average capacity rose 9.5%. In this context, is important to assess the impact of increase in sugarcane transportation energy cost, which can be reduced by the intensification of cultivated areas in the mills vicinity.

Sustainability: new frontiers 2. Increase of sugarcane mill capacity Symposium BGW 2012 Bagasse Gasification Week To evaluate the effect of mill capacity on energy demand and thus on GHG emission, it was adopted as parameter the average densification of sugarcane fields, which is the ratio of the sugarcane cultivated area (determined by the capacity) and the area determined by the average distance of transport. AM Total area Sugarcane cultivated area as defined by theaverage radius of transport 0,01. AC 3.R π. 2 ref 2 transp 22

Sustainability: new frontiers 2. Increase of sugarcane mill capacity Symposium BGW 2012 Bagasse Gasification Week Considering as baseline a typical ethanol mill (2,27 Mtc/ano, R=23 km, AM=7%, 36,8 MJ/tc), it was possible to evaluate the effect of increasing capacity on sugarcane transport energy and GHG emission. GHG emission as function of mill capacity and sugarcane field concentration 23

Sustainability: new frontiers Symposium BGW 2012 Bagasse Gasification Week 3. Adoption of efficient modals in ethanol logistic The recent expansion of ethanol production in Brazil has fostered investment in logistics, particularly in more efficient transportation modals, such as pipelines and barges, considering also ethanol trade. In the next years new systems of ethanol transport will be in place, reducing costs and improving efficiency in the whole production-use chain. Sugarcane barges in Tiete-Paraná waterway (Globo Rural, 2009) 24

Symposium BGW 2012 Bagasse Gasification Week Sustainability: new frontiers 3. Adoption of efficient modals in ethanol logistic A relevant initiative put forward to reduce logistic cost is Logum venture, joining six big Brazilian companies (Copersucar, Cosan, Odebrecht, Petrobras, Camargo Corrêa e Uniduto) in a R$ 7,0 billion deal to establish a 1,300 km pipeline for ethanol connecting new production areas to exporting harbors, able to move annually about 20 million cubic meters of ethanol. Logum multimodal main routes (Logum, 2011)

Sustainability: new frontiers Symposium BGW 2012 Bagasse Gasification Week 3. Adoption of efficient modals in ethanol logistic Modeling the energy performance of different modals is possible to assess the GHG emission for ethanol transportation in each alternative. GHG emission when transporting one cubic meter of ethanol/km 26

Sustainability: new frontiers 4. New processes for bagasse valorization Symposium BGW 2012 Bagasse Gasification Week Introduction of new processes can improve its performance and increase the amount of ethanol produced per hectare. Range of costs for conventional sugarcane ethanol in Brazil Ethanol from bagasse demonstration plant, DEDINI (5,000 liters/day) What is more attractive to produce: motor fuel or electricity? (Seabra, 2009)

Bioethanol or bioeletricity? L.A. Horta Nogueira UNIFEI/2008 Symposium BGW 2012 Bagasse Gasification Week From a Brazilian point of view and considering current costs and prices scenarios, sugarcane bagasse is more valuable for power. Opportunity value of bagasse for power production. Opportunity value of bagasse for ethanol production 28

Final comments Symposium BGW 2012 Bagasse Gasification Week Bioethanol from sugarcane offer an effective approach to face the new challenges posed by climate change, energy and food security and socio-economic activation. The current performance of this route is the highest among all other biofuel productive systems (feedstock + processing). Besides, there are relevant opportunities for additional improvements. In this direction, efficiency is name of the game.

Symposium BGW 2012 Bagasse Gasification Week Sugarcane Ethanol: Energy for Sustainable Development Available in English, Spanish, French and Portuguese, 300 pg, 2008 For download: www.sugarcanebioethanol.org Contents 1. Bioenergy and biofuels 2. Ethanol as a vehicle fuel 3. Bioethanol production 4. Co-products of sugarcane bioethanol 5. Advanced technologies in the sugarcane agro-industry 6. Sugarcane bioethanol in Brazil 7. Sustainability of sugarcane bioethanol: the Brazilian experience 8. Perspectives for a global biofuel market 9. An outlook for bioethanol fuel 30

Symposium BGW 2012 Bagasse Gasification Week Routes to Cellulosic Ethanol, Springer, 2011 Part 1, 27-41 DOI: 10.1007/978-0-387-92740-4_3 31

Symposium BGW 2012 Bagasse Gasification Week Obrigado por sua atenção. L. A. Horta Nogueira horta@unifei.edu.br Universidade Federal de Itajubá Minas Gerais, Brazil