MATERIAL SAFETY DATA SHEET CE Item #DPS00FX6 NAME OF PRODUCT: MSDS Rev. DATE: June 26, 2007 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Toner Cartridge SYNONYMS: PRODUCT CODES: MANUFACTURER: Corporate Express, Inc. DIVISION: ADDRESS: 1 Environmental Way Broomfield CO 80021 EMERGENCY PHONE: CHEMTREC PHONE: 800-424-9300 OTHER CALLS: FAX PHONE: CHEMICAL NAME: CHEMICAL FAMILY: CHEMICAL FORMULA: PRODUCT USE: This is a toner cartridge that is used as a replacement in Canon Laser Facsimiles. PREPARED BY: SECTION 1 NOTES: SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT: Mixture CAS NO. % WT % VOL SARA 313 REPORTABLE ppm mg/m3 Styrene-Acrylate Copolymer 58048-89-8 40-45 Not listed Magnetite 1309-37-1 30 50 Not Listed Polypropylene/Ethylene Copolymer Wax 9010-79-1 < 5.0 Not Listed Dye 84179-66-8 < 5.0 Not Listed Silica 68909-20-6 < 1.0 Not Listed OSHA PEL-TWA: Toner is regulated under OSHA as particulate not otherwise regulated. OSHA PEL STEL: NA OSHA PEL CEILING: 15mg/m3 5mg/m3 for respirable fraction ACGIH TLV-TWA: 10mg/m3 for nuisance particulate ACGIH TLV STEL: NA ACGIH TLV CEILING: NA SECTION 2 NOTES: Toner is regulated under OSHA as particulate not otherwise regulated. SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: ROUTES OF ENTRY: Possible routes of exposure under normal use are skin, eye contact, and inhalation. POTENTIAL HEALTH EFFECTS EYES: May cause slight irritation. SKIN: Slight irritation possible INGESTION: Ingestion is not expected to be a primary route of exposure for this product when used as intended. INHALATION: Minimal respiratory tract irritation may occur with exposure to large amounts of toner. ACUTE HEALTH HAZARDS: NA CHRONIC HEALTH HAZARDS: Prolonged inhalation of excessive amounts of any dust may cause lung damage. This product when used as intended does not result in inhalation of excessive amounts of dust. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Unknown Page 1 of 6
CARCINOGENICITY None of the ingredients have been classified as carcinogens according to OSHA, ACGIH, NTP, IARC OTHER: This product is not classified as hazardous according to OSHA, CFR 1910.1200. SECTION 3 NOTES: This product is not classified hazardous according to OSHA CFR 1910.1200 or EU Directive 1999/45/EC as amended. SECTION 4: FIRST AID MEASURES EYES: Do not rub. Immediately flush with large amounts of clean warm water under low pressure for at least 15 minutes. If irritation persists, consult a physician. SKIN: Thoroughly wash the affected areas with mild soap and water. Seek medical attention is irritation develops or persists. INGESTION: Rinse mouth with water. Drink one or two glasses of water. Consult a physician if symptoms occur. INHALATION: Move the person to fresh air immediately and consult a physician if irritation persists. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: NA SECTION 4 NOTES: SECTION 5: FIRE-FIGHTING MEASURES FLAMMABLE LIMITS IN AIR, UPPER: (% BY VOLUME) LOWER: FLASH POINT: Not Applicable METHOD USED: NA AUTOIGNITION TEMPERATURE: No data available NFPA HAZARD CLASSIFICATION HEALTH: FLAMMABILITY: 1 Slight REACTIVITY: OTHER: HMIS HAZARD CLASSIFICATION HEALTH: FLAMMABILITY: 1 Slight REACTIVITY: PROTECTION: EXTINGUISHING MEDIA: Water, CO2, or dry chemical, foam, carbon dioxide or halon fire extinguishers. SPECIAL FIRE FIGHTING PROCEDURES: Do not release runoff into sewers or waterways. UNUSUAL FIRE AND EXPLOSION HAZARDS: Like any other powdered organic material toner can form explosive dust-air mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Product will produce carbon monoxide and carbon dioxide, nitrogen oxide and smoke. SECTION 5 NOTES: No special firefighting procedures have been established. SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Environmental Considerations: Do not flush into surface water or sanitary sewer systems. Cleanup procedures if material is spilled: Small Spills: Scoop into container for disposal, suction up remaining material with high efficiency vacuum cleaner. Large Spills: Scoop into container for disposal, suction up remaining material with high efficiency vacuum cleaner. Containment:: For large spills avoid suspending particles, collect for later disposal. Do not release into sewers or waterways. Page 2 of 6
SECTION 6 NOTES: No special cleanup requirements. SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: The product should be stored at room temperature out of the reach of children, strong oxididents, heat, sparks and open flame. It should only be used in well-ventilated areas. OTHER PRECAUTIONS: SECTION 7 NOTES: SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: VENTILATION : Use with adequate ventilation. RESPIRATORY PROTECTION: None required when used as intended. EYE PROTECTION: None required when used as intended. SKIN PROTECTION: None required when used as intended. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None WORK HYGIENIC PRACTICES: NA EXPOSURE GUIDELINES: Use with adequate ventilation. SECTION 8 NOTES: SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Fine black powder ODOR: Slight plastic odor PHYSICAL STATE: Solid ph AS SUPPLIED: Not Applicable ph (Other): BOILING POINT: Not Applicable MELTING POINT: 212-302 100-150 FREEZING POINT: Not Applicable VAPOR PRESSURE (mmhg): Not Applicable @ VAPOR DENSITY (AIR = 1): Not Applicable @ SPECIFIC GRAVITY (H2O = 1): 1.3 @ 4 degrees Page 3 of 6
EVAPORATION RATE: Not Applicable BASIS (=1): SOLUBILITY IN WATER: Insoluble OTHER SOLUBILITIES: None PERCENT SOLIDS BY WEIGHT: PERCENT VOLATILE: BY WT/ BY VOL @ VOLATILE ORGANIC COMPOUNDS (VOC): WITH WATER: LBS/GAL WITHOUT WATER: LBS/GAL MOLECULAR WEIGHT: Unknown VISCOSITY: Not Applicable SECTION 9 NOTES: SECTION 10: STABILITY AND REACTIVITY STABLE STABILITY: Stable under normal storage and use conditions. CONDITIONS TO AVOID (STABILITY): OPC drum: Exposure to light. INCOMPATIBILITY (MATERIAL TO AVOID): Strong oxidizers HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Carbon monoxide and carbon dioxide. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID (POLYMERIZATION): None SECTION 10 NOTES: SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Acridity: Eyes: None Skin: None Corrosion: None Sensitizing property: None Chronic Toxicity: None Carcinogenicity: None Mutagenicity: Ames test - Negative Acute Toxicity: None Subacute: None SECTION 11 NOTES: This product when used as intended does not present a health or safety hazard. SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: The product has not been tested for ecological effects. SECTION 12 NOTES: SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Do not shred without taking explosive dust prevention measures. Dispose of in compliance with federal, state and local regulations. Page 4 of 6
RCRA HAZARD CLASS: (40 CFR 261) Not classified. SECTION 13 NOTES: SECTION 14: TRANSPORT INFORMATION This product is not a regulated article under United States DOT, IATA, ADR, IMDG, or RID U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: (49 CFR 172.101) Not specifically listed. HAZARD CLASS: NA ID NUMBER: NA PACKING GROUP: NA LABEL STATEMENT: NA WATER TRANSPORTATION PROPER SHIPPING NAME: NA HAZARD CLASS: NA ID NUMBER: NA PACKING GROUP: NA LABEL STATEMENTS: NA AIR TRANSPORTATION PROPER SHIPPING NAME: NA HAZARD CLASS: NA ID NUMBER: NA PACKING GROUP: NA LABEL STATEMENTS: NA OTHER AGENCIES: UN# 2807 UN SHIPPING NAME: Magnetized material UN CLASSIFICATION: 9 UN PACKING GROUP: None MARINE POLLUTANT: No SECTION 14 NOTES: 10 or more of these products shipped together, by air, are regulated as magnetized material. SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): All chemical substances in this product comply with all rules or orders under TSCA CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Listed/unlisted specific per RCRA, sec. 3001; CWA sec.311 (b) (4); CWA, Sec. 307 (a), CAA, Sec. 112 CERCLA Reportable Quantity (RQ), Not Listed SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): 311/312 HAZARD CATEGORIES: NA 313 REPORTABLE INGREDIENTS: Not Listed STATE REGULATIONS: Not Applicable INTERNATIONAL REGULATIONS: SECTION 15 NOTES: All ingredients are listed on the TSCA inventory. SECTION 16: OTHER INFORMATION OTHER INFORMATION: This MSDS was prepared in accordance with USA OSHA Hazard Communication regulation (29 CFR 1910.1200). PREPARATION INFORMATION: NA DISCLAIMER: The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty expressed or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. Page 5 of 6
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