MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identifier Other names Polyester chips Product Use Extrusion of fibers, non-wovens, inyection molding Manufacturer s Name Akra Polyester S.A. de C.V. Polyester polymer, polyester pellets, polyester resin Steet Address Av. Ruiz Cortines y Priv. Roble City / State Country Postal Code Emergency Telephone Monterrey, N.L. Mexico 64400 ( 81 ) 8865 3100 Date MSDS Prepared MSDS Prepared by Phone Number July 13 th, 2009 Akra Polyester S.A. de C.V. ( 81 ) 8865 3100 SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients (specific) % CAS Number LD 50 of Ingredient (specify species and route) Polyethylene terephthalate > 98.0 25038-59-9 Additives < 2.0 LC 50 of Ingredient (specify species) SECTION 3 HAZARDS IDENTIFICATION Route of Entry X X X Skin Contact Skin Absorption Eye Contact Inhalation Ingestion [Potential Health Effects] There are no known physical or health hazards associated with this product. The polymer immobilizes the constituents of the polymer system (delusterants, catalyst residues, etc.), which, therefore, present no likelihood of exposure under normal conditions of handling. However, exposure to chemical substances may occur as a result of processing this polymer. Molten polymer or prolonged air-drying of polymer at temperatures above 200 C will release small quantities of acetaldehyde ( CAS # 75-07-0 ) and volatile degradation products. THE MOLTEN MATERIAL WILL PRODUCE THERMAL BURNS! SECTION 4 FIRST AID MEASURES Skin Contact The material is not likely to be hazardous by skin contact but cleansing after use is a good industrial practice. If burned by contact with molten material, cool as quickly as possible, do not peel material from skin and get medical attention for thermal burn. Eye Contact In case of contact, immediately flush with plenty of water for at least 15 minutes and get medical attention. Inhalation The material is not likely to be hazardous by inhalation. However, if exposed to fumes move to fresh air. Get medical attention if sympthoms persist. Ingestion Ingestion is not an expected route of exposure during normal use. If ingested, get medical attention. Page 1 of 4
SECTION 5 FIRE FIGHTING MEASURES Flammability If yes, under which conditions? X Yes No The material will burn when exposed to fire Means of Extinction Water fog, foam, carbon dioxide and dry chemicals Flashpoint (ºC) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume) Autoignition Temperature (ºC) Explosion Data Hazardous Combustion Products Carbon dioxide, carbon monoxide and acetaldehyde [NFPA] Health 1, Flammability 1, Chemical Reactivity 0 Powdered material may form explosive dust air mixtures The rating involves data interpretations that may vary from company to company. They are intended only for general identification of the specific hazard. SECTION 6 ACCIDENTAL RELEASE MEASURES Leak and Spill Procedures Stepping or walking on chips can cause falls : Avoid accumulation on floors and walkways. Sweep or scoop up and dispose properly. SECTION 7 HANDLING AND STORAGE Storage Requirements Store the product in a closed covered area protected from dust and environmental agents since they can deteriorate the product or affect its performance. Handling Procedures and Equipment Avoid contact with molten material, cool the material with plenty of water before handling and wear protection equipment. The interior of molten masses may remain hot for some time due to low heat conductivity. Minimize dust generation and accumulation. Accumulation of resin on hot machine surfaces should be avoided to minimize the possible generation of volatile decomposition products, which may be irritating, toxic and combustible. The amorphous polyester at a temperature of 110 C ( 230 F ) or above starts a crystallization process. In the case of the clear resins this crystallization process turns the resin appearance to a milky color. For this reason, high temperatures should be avoided during the handling of the product specially in conveying systems where high temperatures can be developed from friction, restrictions or closed turns in the pipes. SECTION 8 EXPOSURE CONTROL/PERSONAL PROTECTION Exposure Limits ACGIH TLV OSHA PEL None established None established Other (specify) Specific Engineering Controls (such as ventilation, enclosed process) Use good ventilation to control fumes when processing molten material Personal Protective Equipment X X X Gloves Respirator Eye Footwear Clothing Other If checked, specify type Skin protection : It is a good industrial practice to minimize skin contact, wear leather gloves to protect against thermal burns from molten material. Eye protection : It is a recommended to wear safety glasses or goggles to minimize eye contact with pellets or dust. When working with molten material wear a face shield. Footwear : It is recommended to wear safety boots to avoid falls due to spilled pellets Page 2 of 4
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Physical State Odour Appearance Solid ( pellets or chips ) None Clear to white pellets depending on the amount and type of additives Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmhg) 1.33 Evaporation Rate Melting Point (ºC) Boiling Point (ºC) None 257-260 Ph Coefficient of Water/Oil Distribution [Solubility in Water) None SECTION 10 STABILITY AND REACTIVITY Chemical Stability If no, under which conditions? X Yes No Incompatibility with Other Substances If yes, which ones? X Yes No The material reacts with strong oxidizing agents Reactivity, and under what conditions? The material is chemically stable and resistant to attack by oils, common solvents, weak acids and weak alkalis. Hazardous Decomposition Products Molten polymer or prolonged air-drying of polymer at temperatures of 200 C or above generates small amounts of volatile degradation products. One of the degradation products is acetaldehyde ( CAS # 75-07-0 ). Established exposure limits for acetaldehyde are : ACGIH TLV = 25 ppm CEILING OSHA PEL = 200 ppm TWA SECTION 11 TOXICOLOGICAL INFORMATION Effects of Acute Exposure Effects of Chronic Exposure No adverse health effects have been attribuited to polyester. Acetaldheyde vapors, which are released in small quantities from molten polyester are potent irritants. Irritancy of Product Polyester is not a skin irritant Skin Sensitization None ( guinea pig ) Carcinogenicity IARC Animal testing indicates that polyester does not have carcinogenic, mutagenic or reproductive effects. Reproductive Toxicity Respiratory Sensitization Carcinogenicity ACGIH Teratogenicity Embryotoxicity Mutagenicity Name of Synergistic Products/Effects SECTION 12 ECOLOGICAL INFORMATION [Aquatic Toxicity] Not available. The product is insoluble in water. Page 3 of 4
SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal Disposal must be according to applicable Federal, State and Local regulations. SECTION 14 TRANSPORT INFORMATION Special Shipping Information PIN TDG [DOT] Not regulated [IMO] Not restricted [ICAO] Not regulated SECTION 15 REGULATORY INFORMATION [WHMIS CLASSIFICATION] Non controlled [OSHA] [SARA] This material is not known to contain extremely hazardous substances [TSCA] In compliance with TSCA inventory requirements for commercial purposes Title III Hazard classifications sections 311, 312 Acute, Chronic, Fire, Reactivity, Pressure : NO Hazardous Chemical lists : SARA extremely hazardous substance : NO CERCLA hazardous substance : NO SARA toxic chemical : NO SECTION 16 OTHER INFORMATION To the best of our knowledge, the information contained herein is accurate. However, Akra Polyester does not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of the material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Page 4 of 4
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