Bentonite Perlite Wollastonite

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RAW MATERIALS UNIVERSITY DAY Future, needs and opportunities Athens, June 19 th Bentonite Perlite Wollastonite Dr. A. Karalis, R&D Specialties Manager, Global Market Organization, S&B Industrials Minerals 1

tonite producer in Europe and No 2 worldwide graded Perlite producer worldwide lastonite producer worldwide (in value) ducer of Casting Fluxes worldwide xite producer in the EU We provide innovative Industrial Solutions globally by developing and transforming natural resources into value creating products 2

Transforming natural resources to provide industrial solutions globally to Four key market Segments Bentonite Wollastonite Perlite Continuous Casting Fluxes Specialty Minerals Bauxite Metallurgy Continuous steel casting Iron ore pelletizing Alumina Refractories Iron smelting Foundry Mold sand additives Core sand additives Inorganic binders Construction Building materials Civil engineering Cements Drilling Cryogenics Other Specialties Plastics Glass & ceramics Horticulture Absorbents Paints & Coatings Other 3

Sales 2012 in million -2.2% Sales per Segment and per Region -1.6% +21% +8.3% +3.2% Total 5 Regions 211 122 108 27 468 Specialties4 45 11 19 1 76 +9% Construction 3 39 45 18 7 108 +8% Foundry 2 70 14 34 0 118-1% Metallurgy 1 57 51 38 20 165 +1% 0 N. Europe S. Europe Americas Asian/Pacific Total Business Segments 4

Global presence with dispersed operations 30 mines 50 plants 26 Distribution centers 4 countries 25 site locations 411 employees 108 m sales 7 countries 26 site locations 530 employees 211 m sales 7 countries 42 site locations 886 employees 124 m sales 3 countries 13 site locations 274 employees 27 m sales 5

To discuss today: Development of the New Strategy for IM Questions: How a Greek Company becomes a Global player? How a Mining Company is transformed into an Industrial Solutions provider? Answers: Switch from Mine to Market to Market-to-Mine approach Invest in People Find and secure Funding 6

Downstream diversification through targeted key-investments 230+ million in key acquisitions for geographical, downstream and applications diversification 98-99 2000 2001 2003 2004 2007 2012 Otavi Mykobar Perlite Mineral Trading Bentonite Pelletising Construction Horticulture IKO Bentonite Foundry Civil engineering Cat litter Specialties..from digger & shipper.. S&B Hungary Bentonite Civil engineering S&B Bulgaria Bentonite Perlite Civil engineering Cat litter Construction Horticulture Stollberg Group Fluxes Continuous steel casting Hill & Griffith CEBO JV Bentonite Foundry Drilling NYCO Minerals Wollastonite Tripoli Plastics Paints Coatings...to an industrial solutions provider 7

The 3 Dimensions of the New Strategy New geographies New solutions Diversify applications 8

The New Strategy of S&B for Industrial Minerals An example: From Bentonite and Perlite in Greece to Wollastonite in USA 9

What is Bentonite? Bentonite is a Clay which contains a mineral from the Smectite Group Smectites are Trioctaedral (Talc, Vermiculite) or Dioctaedral (Montmorillonite, Nontronite) Minerals, characterized by their Exhangeable Cations (Ca +2, Na +1 ) Greek Bentonites contain mainly Ca-Montmorillonite, non swellable in H 2 O After Activation Montm becomes highly swellable (12-18 to 1) and is used in several Applications (Metallurgy, Foundries, Construction, Drilling, Water Treatment, Catalysis,..) Key-properties: Swelling, H 2 O absorption (7-10 to 1), Binding, Colloidality, Thixotropy Smectite in H 2 O environment 10 (Holtz and Kovacs, 1981)

How Bentonite is processed Activation through Extrusion in the Lab Activation through Extrusion in the Plant 11

What is Perlite? Perlite is a generic term for naturally occurring siliceous rock: Volcanic glass (70-76% amorphous silica and alumina) Perlite expands 4-20 times its original volume, when rapidly heated to its softening temperature range (>870 C), due to the presence of 2-5% combined H 2 O and Alkalis (6-10%) Combined H2O: mainly in the form of Silanol groups [Si-OH bonds] Key-properties: after expansion perlite particles become extremely lightweight porous bubbles with cellular structure Applications: Insulation (Buildings & Cryogenics), Hydroponics, Building, Filtration (Beverages, antibiotics) 12

How Perlite is processed 13

What is Wollastonite? Wollastonite is a naturally occurring non-metallic white mineral (Calcium Silicate -CaSiO 3 ) In the ore body it co-exists with Quartz, Pyroxene, Garnets, and Calcite Wollastonite has originally Acicular structure and if it is properly treated it yields fibers of high Aspect Ratio (8-12 : 1) providing excellent reinforcement properties to plastics (PO, PA) Its secondary treatment with polysiloxanes (chemical coating at elevated T) is crucial Applications: Functional Filler in Plastics and Coatings, Starting material for Ceramics and Metallurgical Fluxes Key-properties: Acicularity, Purity, whiteness, ph = 10, high melting point 14

How Wollastonite is processed Primary Crushing is followed by Secondary crushing and Milling in order the Wollastonite fibers to be deliberated from other minerals Beneficiation is required to remove impurities (up to 45%) and obtain pure wollastonite It may include Magnetic Separation or Floatation or both Surface coating takes place in simple stirring reactors at T<100 C 15

How the New Strategy works. Entering the world of Plastics & Coatings (2009-2011) Need for expanding S&B s Product Portfolio (2011) Acquisition of a Market Leader (2012): NYCO, US: Wollastonite for P&C Other Minerals for P&C R&D Geological Exploration NYCO as Vehicle for Perlite in P&C R&D: Micronized Perlite for Plastics & Coatings (2008-9) Delaminated Bentonite for Coatings (2007-8) 16

Thank you for your attention! 17