Revised edition: 15.08.2013 1. 1. 1. Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Iron Oxide Red, clinker red 1. 2. Article No.: 48151 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent (pigment and dyes), inorganic. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: 2. 3. Hazardous components for labelling: Other Hazards Composition/Information on Ingredients 2
3. 3. 1. Substance 3. 2. Mixture Page 2 Chemical Characterization: Pigment Red 101, C.I. 77491, Fe2O3 (CAS No. 1309-37-1, EINECS 215-168-2) REACH Reg. No.: 01-2119457614-35-0009 Information on Components / Hazardous Ingredients: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Supply fresh air and seek medical advice in case of complaints. Wash with soap and rinse with plenty of water. Remove contaminated clothing. Rinse open eyes with plenty of water. In case of discomfort seek medical help. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth thoroughly with plenty of water and drink plenty of water. Consult a physician. Symptoms: No further information available. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Use extinguishing media for surrounding fire. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture 5. 3. Special hazards: Advice for Firefighters Product is not flammable. Protective equipment: Wear self-contained respiratory protective device. 3
Further information: 6. Accidential Release Measures 6. 1. Personal Precautions, Protective Equipment and Emergency Procedures Page 3 6. 2. Personal precautions: Environmental Precautions Wear protective clothing. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Clean up mechanically. Avoid dust formation. No special measures required. Provide adequate ventilation. Avoid formation of dust. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Store in tightly sealed containers in a dry and well ventilated location. Store the product in the original container. Information on fire and explosion protection: Storage class (VCI): 13; Non combustible solids 7. 3. 8. 8. 1. Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Iron(III) oxide (CAS 1309-37-1): TRGS 900 TLV: 10 mg/m3 inhalable fraction (general dust limit) TLV: 3 mg/m3 air-borne fraction (general dust limit) 4
Parameters to be controlled: Page 4 Derived No-Effect Level (DNEL): Iron(III) oxide (CAS 1309-37-1): 10 mg/m3 (worker, inhalation, long-term exposition - local effects) 3 mg/m3 (worker, inhalation, long-term exposition - local effects) Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Personal Protection General protective measures: Respiratory protection: Hand protection: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Respiratory equipment required in case of insufficient ventilation, filter type P2. Chemical protective gloves (EN 374 (Europe), F739 (US)). Protective glove material: Eye protection: Safety glasses with protective shields (EN 166). Body protection: 9. 9. 1. Environmental precautions: Do not allow entering sewerage system. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: powder red odorless 4-8 g/cm3 (100 g/l) Melting temperature: > 1000 C Boiling temperature: Flash point: Evaporation rate: 5
Page 5 Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: no information available no information available Vapor density: Density: 5.2 g/cm3 Solubility in water: insoluble Coefficient of variation (n- Octanol/Water): not determined Auto-ignition temperature: Decomposition temperature: not determined Viscosity, dynamic: Explosive properties: Oxidizing properties: no information available Bulk density: 600-1000 kg/m3 9. 2. Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: No further information. 10. Stability and Reactivity 10.1. Reactivity 6
10.2. 10.3. 10.4. Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Page 6 No decomposition if used according to specifications. Unknown. 10.5. 10.6. 10.7. 11. 11. 1. Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: No decomposition if used according to specifications. Strong reducing agents, such as aluminium, magnesium, ethylene oxide, calcium hypochlorite None known. Iron(III) oxide: > 5000 mg/kg (rat) No irritant effect known. Reversible, mechanical irritation possible. No information available No sensitizing effects known. No relevant data found. Cancerogenity: No relevant data found. 7
Teratogenicity: Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. 13. 1. Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: No relevant data found. No toxicity expected. Since the pigment is almost insoluble in water, it can be separated after each filtration and sedimentation step. Not applicable. Not hazardous. If product cannot be reused or recycled, it has to be disposed of according to current local regulations. 060316 - Wastes from the MFSU of salts and their solutions and metallic oxides other than those mentioned in 06 03 15. Packaging may be disposed of in the same manner as the product. Waste Code No.: 14. Transport Information 8
14. 1. UN Number Page 8 14. 2. ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation). 14. 3. IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: 14. 4. Hazard no.: Packaging Group ADR/RID: IMDG: 14. 5. 14. 6. 14. 7. 14. 8. 15. 15. 1. IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous (German Regulation; Self-assessment) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: 9
15. 2. 15. 3. 16. Chemical Safety Assessment Further Information Other Information Page 9 A Chemical Safety Assessment is not necessary for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.