Reservoir Surveillance Fundamentals Lab Work. Compliments of Intertek Westport Houston Laboratory

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Reservoir Surveillance Fundamentals Lab Work Compliments of Intertek Westport Houston Laboratory

Lab Work for PEs and Background to ARE Course Lab Work Geochemistry Phase Behavior Miscibility/Immiscibility of Displacement Flow Assurance Core Analysis Geology/Petrology SCAL EOR/IOR Relative Flow

Geochemistry Petroleum Geochemistry Geochemical Correlations Oil Fingerprinting/Reservoir Continuity Source Rock Analyses Generation, Migration, Accumulation, Alteration Tar Mat/Oil Quality Distribution Leak and Fluid Loss Evaluation Inorganic Geochemistry Chemostratigraphy

Geochemistry Analytical Services HPLC Chromatography Extended Gas - Hydrocarbons to C13+, CO 2, Nitrogen, Oxygen Whole Oil to C90+ ICP/MS Whole Oil Elemental Analysis Whole Rock Elemental Analysis Water Analysis Laser Induced Breakdown Spectroscopy Whole Rock Elemental Analyses GC Mass Spec Biomarkers Isotope Mass Spectroscopy Carbon and Deuterium

Phase Behavior / PVT Reservoir Fluid Studies Sample Validation Black Oil Studies Volatile Oil Studies Gas Condensate Studies Advanced PVT Studies Swelling Tests (P-x Diagram) Multiple Contact Tests Slimtube Experiments

First Contact Miscibility Pressure Saturation Pressure Reservoir Pressure Mol % Gas Addition Determine the minimum pressure required to have a certain amount of injection gas dissolved in the original oil in place.

Swelling Factor and Other Volumetric Parameters Swelling Factor Mol % Gas Addition Swelling of the oil phase causes: Breakdown of the original capillary equilibrium, Pore-scale redistribution of the phases.

Determination of Dynamic MMP or MME Oil Recovery, % 100 75 50 25 MMP or MME 100 90 80 70 Oil Recovery after 1.2 PV, % 0 0.3 0.6 0.9 Gas injected, in PV 1.2 1 1.1 1.2 1.3 1.4 Pressure or y i, (-)

Multiple Contact Experiment Forward Contacting 2 nd Contact 3 rd Contact 1 st Contact Reverse Contacting 2 nd Contact 3 rd Contact Multi-contact Experiment determines the miscibility mechanism and the level of IFT at operating pressure.

Flow Assurance Gas Hydrate Studies Gas Hydrate Prediction and Inhibition Multiphase Fluids, Drilling and Completion Fluids Proprietary WHyP hydrate prediction model Visual Cell Testing Pipeline Testing Secure, independent third-party testing of inhibitor systems

Flow Assurance Wax and Asphaltene Studies Cross Polarization Microscopy Wax and Asphaltene particle onset using NIR laser light scattering Wax and Asphaltenes Deposition Flow Loop Studies Secure, independent third-party testing of inhibitor systems Pipeline Transport Studies Cold Re-start Rheology / viscosity at P & T Computer controlled temperature ramping

Rock Properties / Core Analysis Routine Core Analysis (SCA- Standard Core Analysis) Wellsite handling and preservation of conventional cores Gamma Logging CT Imaging Core Slabbing and Photography Basic Petrophysical Measurements

Geology/Petrology Services Thin Section Analysis Scanning Electron Microscopy (SEM) X-Ray Diffraction Core Description Fracture Analysis Formation Damage Prediction

Special Core Analysis (SCAL) Reservoir Engineering Capillary pressure measurements Relative permeability measurements Reservoir condition core floods measurements Petrophysical Correlation Electrical, Acoustic, and NMR Formation Damage Studies Drilling, Completion and Production Damage Stimulation Geomechanical Properties Perforating

SCAL Multiphase flow in porous media is controlled by a relatively small number of key parameters, including: Reservoir fluid PVT and phase behavior properties Interfacial tension (IFT) of in-situ and injected fluids Viscosity ratios of flowing fluids Reservoir Heterogeneity (Micro-scale and macro-scale pore size distributions) The effect of Gravity Wettability of the porous media Flow velocity

Objectives For SCAL Testing 1. Duplicate your reservoir in the laboratory 2. Duplicate the sequence of events that has occurred in your reservoir 3. Design a test program that accurately models the key parameters that control fluid flow in porous media Phase behavior influences Interfacial tension (IFT) Viscosity ratios Micro-scale and macro-scale pore size distributions Gravity Wettability Flow rate

Procedures for SCAL Testing Full Reservoir Condition Testing: Reservoir temperature, reservoir pressure, total overburden pressure Wettability: Preserved or restored-state core IFT and Viscosity Ratio: Live reservoir fluids Composite core stacks of plugs in capillary contact Run tests in primary, secondary or tertiary mode Use field-real flow rates Drainage and inhibition tests

EOR/IOR Studies Gas Injection Studies Field Gas CO2 Injection Miscible Gas Injection Water Alternating Gas (WAG) Thermal Recovery Studies Steam Floods Steam Floods with Additives Chemical Flood Studies Polymer Alkaline Surfactant Polymer Consulting

Miscible Gas Injection EOR Advanced PVT experiments and EOS characterization and modeling of fluid phase behavior in the entire (P V μ z i K i go ) envelope at Tres Special Core flood displacement experiments on samples representing the principal reservoir rock types at Tres to: Generate Sor(σ go ), Pc(σ go ), Kr ow (S w ), kr og (S g,σ go ) Evaluate the longitudinal dispersion Evaluate secondary and/or tertiary recovery processes Accurate reservoir description combined with compositional simulation to predict process performance and to study design parameters sensitivities

Relative Flow Current simulation practices model the reservoir using one set of relative permeability data per rock region. Once rock regions are assigned they are usually fixed over the life of the simulation. 1 Relative Permeability 0 Saturation 1

High and Low IFT Relative Permeability Represents a reservoir scenario where interfacial tension effects dominate and are significant in increasing the recovery of oil.

High and Low IFT Relative Permeability Case 2 provides an illustration of a reservoir scenario where the mobility, pore size distribution, and wettability effects appear to completely dominate.