Chapter 10 Vapor and Combined Power Cycles

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Chapter 10 Vapor and Combined Power Cycles Dr. Mohammad Tarawneh Thermodynamics: An Engineering Approach, 5th edition by Yunus A. Çengel and Michael A. Boles

We consider power cycles where the working fluid undergoes a phase change. The best example of this cycle is the steam power cycle where water (steam) is the working fluid. Carnot Vapor Cycle 2

The heat engine may be composed of the following components. The working fluid, steam (water), undergoes a thermodynamic cycle from 1-2-3-4-1. The cycle is shown on the following T-s diagram. 3

700 Carnot Vapor Cycle Using Steam 600 500 400 6000 kpa T [C] 300 2 3 100 kpa 200 100 1 4 The thermal efficiency of this cycle is given as 0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 s [/-K] Note the effect of T H and T L on th, Carnot. The larger the T H the larger the th, Carnot The smaller the T L the larger the th, Carnot W net th, Carnot 1 Qin 1 T T L H Q Q out in 4

To increase the thermal efficiency in any power cycle, we try to increase the maximum temperature at which heat is added. Reasons why the Carnot cycle is not used: Pumping process 1-2 requires the pumping of a mixture of saturated liquid and saturated vapor at state 1 and the delivery of a saturated liquid at state 2. To superheat the steam to take advantage of a higher temperature, elaborate controls are required to keep T H constant while the steam expands and does work. To resolve the difficulties associated with the Carnot cycle, the Rankine cycle was devised. Rankine Cycle The simple Rankine cycle has the same component layout as the Carnot cycle shown above. The simple Rankine cycle continues the condensation process 4-1 until the saturated liquid line is reached. Ideal Rankine Cycle Processes Process Description 1-2 Isentropic compression in pump 2-3 Constant pressure heat addition in boiler 3-4 Isentropic expansion in turbine 4-1 Constant pressure heat rejection in condenser 5

The T-s diagram for the Rankine cycle is given below. Locate the processes for heat transfer and work on the diagram. 500 Rankine Vapor Power Cycle 400 300 6000 kpa 3 T [C] 200 100 0 2 1 0 2 4 6 8 10 12 4 s [/-K] 10 kpa Example 10-1 Compute the thermal efficiency of an ideal Rankine cycle for which steam leaves the boiler as superheated vapor at 6 MPa, 350 o C, and is condensed at 10 kpa. We use the power system and T-s diagram shown above. P 2 = P 3 = 6 MPa = 6000 kpa T 3 = 350 o C P 1 = P 4 = 10 kpa 6

Pump The pump work is obtained from the conservation of mass and energy for steady-flow but neglecting potential and kinetic energy changes and assuming the pump is adiabatic and reversible. m m m m h W m h 1 1 pump 2 2 W m ( h h ) pump 1 2 2 1 Since the pumping process involves an incompressible liquid, state 2 is in the compressed liquid region, we use a second method to find the pump work or the h across the pump. Recall the property relation: dh = T ds + v dp Since the ideal pumping process 1-2 is isentropic, ds = 0. 7

The incompressible liquid assumption allows v v const. 1 h h v ( P P ) 2 1 1 2 1 The pump work is calculated from W m ( h h ) mv ( P P ) Using the steam tables w pump pump 2 1 1 2 1 W pump v1( P2 P1 ) m h1 hf 191.81 P1 10 kpa 3 Sat. liquid m v 1 v f 0.00101 w v ( P P ) pump 1 2 1 3 m 0. 00101 ( 6000 10) 6. 05 kpa 3 m kpa 8

Now, h 2 is found from Boiler h w h 2 pump 1 6.05 191.81 197.86 To find the heat supplied in the boiler, we apply the steady-flow conservation of mass and energy to the boiler. If we neglect the potential and kinetic energies, and note that no work is done on the steam in the boiler, then m m m 2 3 m 2h2 Qin m 3h3 Q m ( h h ) in 3 2 9

We find the properties at state 3 from the superheated tables as The heat transfer per unit mass is 3 P3 6000 kpa T 3 h 3043.9 o 350 C s3 6.3357 K Q m in qin h3 h2 (3043.9 197.86) 2845.1 10

Turbine The turbine work is obtained from the application of the conservation of mass and energy for steady flow. We assume the process is adiabatic and reversible and neglect changes in kinetic and potential energies. m m m 3 4 m h W turb m h W m ( h h ) 3 3 4 4 turb 3 4 We find the properties at state 4 from the steam tables by noting s 4 = s 3 = 6.3357 /-K and asking three questions. at P4 10 kpa : s f 0.6492 ; sg 8.1488 K K is s 4 f g s f 4 4? is s s s is s s? g? 11

s s x s x 4 f 4 4 s s The turbine work per unit mass is fg 6.3357 0.6492 7.4996 4 f s fg h h x h 4 f 4 0.758 191.81 0.758(2392.1) turb 2005.0 fg w h h 3 4 (3043.9 2005.0) 1038.9 12

The net work done by the cycle is The thermal efficiency is w w w net turb pump (1038.9 6.05) 1032.8 w net th qin 1032.8 2845.1 0.363 or 36.3% 13

Ways to improve the simple Rankine cycle efficiency: Superheat the vapor Average temperature is higher during heat addition. Moisture is reduced at turbine exit (we want x 4 in the above example > 85 percent). Increase boiler pressure (for fixed maximum temperature) Availability of steam is higher at higher pressures. Moisture is increased at turbine exit. Lower condenser pressure Less energy is lost to surroundings. Moisture is increased at turbine exit. Extra Assignment For the above example, find the heat rejected by the cycle and evaluate the thermal efficiency from th w q net in 1 q q out in 14

Reheat Cycle As the boiler pressure is increased in the simple Rankine cycle, not only does the thermal efficiency increase, but also the turbine exit moisture increases. The reheat cycle allows the use of higher boiler pressures and provides a means to keep the turbine exit moisture (x > 0.85 to 0.90) at an acceptable level. Let s sketch the T-s diagram for the reheat cycle. T 15 s

Rankine Cycle with Reheat Component Process First Law Result Boiler Const. P q in = (h 3 - h 2 ) + (h 5 - h 4 ) Turbine Isentropic w out = (h 3 - h 4 ) + (h 5 - h 6 ) Condenser Const. P q out = (h 6 - h 1 ) Pump Isentropic w in = (h 2 - h 1 ) = v 1 (P 2 - P 1 ) The thermal efficiency is given by w th q net in ( h3 - h4 ) + ( h5 - h6 ) - ( h2 - h1 ) ( h - h ) + ( h - h ) 1 3 2 5 4 h6 h1 ( h - h ) + ( h - h ) 3 2 5 4 16

Example 10-2 Compare the thermal efficiency and turbine-exit quality at the condenser pressure for a simple Rankine cycle and the reheat cycle when the boiler pressure is 4 MPa, the boiler exit temperature is 400 o C, and the condenser pressure is 10 kpa. The reheat takes place at 0.4 MPa and the steam leaves the reheater at 400 o C. th x turb exit No Reheat 35.3% 0.8159 With Reheat 35.9% 0.9664 17

Regenerative Cycle To improve the cycle thermal efficiency, the average temperature at which heat is added must be increased. One way to do this is to allow the steam leaving the boiler to expand the steam in the turbine to an intermediate pressure. A portion of the steam is extracted from the turbine and sent to a regenerative heater to preheat the condensate before entering the boiler. This approach increases the average temperature at which heat is added in the boiler. However, this reduces the mass of steam expanding in the lowerpressure stages of the turbine, and, thus, the total work done by the turbine. The work that is done is done more efficiently. The preheating of the condensate is done in a combination of open and closed heaters. In the open feedwater heater, the extracted steam and the condensate are physically mixed. In the closed feedwater heater, the extracted steam and the condensate are not mixed. 18

Cycle with an open feedwater heater 19

Rankine Steam Power Cycle with an Open Feedwater Heater 600 3000 kpa 500 5 500 kpa 400 T [C] 300 200 4 6 10 kpa 100 0 2 1 3 0 2 4 6 8 10 12 s [/-K] Cycle with a closed feedwater heater with steam trap to condenser 7 20

Let s sketch the T-s diagram for this closed feedwater heater cycle. T s 21

Cycle with a closed feedwater heater with pump to boiler pressure 22

Let s sketch the T-s diagram for this closed feedwater heater cycle. T Consider the regenerative cycle with the open feedwater heater. To find the fraction of mass to be extracted from the turbine, apply the first law to the feedwater heater and assume, in the ideal case, that the water leaves the feedwater heater as a saturated liquid. (In the case of the ideal closed feedwater heater, the feedwater leaves the heater at a temperature equal to the saturation temperature at the extraction pressure.) Conservation of mass for the open feedwater heater: s 23

Let y m / m heater. 6 5 be the fraction of mass extracted from the turbine for the feedwater m in m out m m m m 6 2 3 5 m m m m ( y) 2 5 6 5 1 Conservation of energy for the open feedwater heater: E E m h m h m h ym h ( 1 y) m h m h in h y h out 6 6 2 2 3 3 5 6 5 2 5 3 h h 3 2 6 2 24

Example 10-3 An ideal regenerative steam power cycle operates so that steam enters the turbine at 3 MPa, 500 o C, and exhausts at 10 kpa. A single open feedwater heater is used and operates at 0.5 MPa. Compute the cycle thermal efficiency. The important properties of water for this cycle are shown below. States with selected properties State P kpa T C h / s /-K Selected saturation properties P kpa T sat C v f m 3 / h f / 1 10 10 45.81 0.00101 191.8 2 500 500 151.83 0.00109 640.1 3 500 3000 233.85 0.00122 1008.3 4 3000 5 3000 500 3457.2 7.2359 6 500 2942.6 7.2359 7 10 2292.7 7.2359 25

The work for pump 1 is calculated from Now, h 2 is found from w v ( P P ) pump 1 1 2 1 3 m 0. 00101 (500 10) 05. h w h 2 pump 1 1 05. 1918. 192. 3 kpa 3 m kpa 26

The fraction of mass extracted from the turbine for the open feedwater heater is obtained from the energy balance on the open feedwater heater, as shown above. y (640.1 192.3) h h h 6 h2 (2942.6 192.3) 3 2 0.163 This means that for each of steam entering the turbine, 0.163 is extracted for the feedwater heater. The work for pump 2 is calculated from w v ( P P ) pump 2 3 4 3 3 m 0. 00109 ( 3000 500) 2. 7 kpa 3 m kpa 27

Now, h 4 is found from the energy balance for pump 2 for a unit of mass flowing through the pump. E out E in h w h 4 pump 2 3 2.7 640.1 642.8 Apply the steady-flow conservation of energy to the isentropic turbine. E in out 5 5 turb 6 6 7 7 W m [ h yh (1 y) h ] turb E m h W m h m h 5 5 6 7 Wturb wturb h yh (1 y) h m 5 5 6 7 [3457.2 (0.163)(2942.1) (1 0.163)(2292.7)] 1058.6 28

The net work done by the cycle is W W W W net turb pump 1 pump 2 m w m w m w m w 5 net 5 turb 1 pump 1 3 pump 2 m w m w m (1 y) w m w 5 net 5 turb 5 pump 1 5 pump 2 w w (1 y) w w net turb pump 1 pump 2 [1058.6 (1 0.163)(0.5) 2.7] 1055.5 Apply the steady-flow conservation of mass and energy to the boiler. m m 4 5 m 4h4 Qin m 5h5 Q in m 5( h5 h4 ) Q in qin h h m 5 5 4 29

The heat transfer per unit mass entering the turbine at the high pressure, state 5, is The thermal efficiency is q h h in 5 4 (3457.2 642.8) 2814.4 w net th qin 1055.5 2814.4 0.375 or 37.5% If these data were used for a Rankine cycle with no regeneration, then th = 35.6 percent. Thus, the one open feedwater heater operating at 0.5 MPa increased the thermal efficiency by 5.3 percent. However, note that the mass flowing through the lower-pressure turbine stages has been reduced by the amount extracted for the feedwater and the net work output for the regenerative cycle is about 10 percent lower than the standard Rankine cycle based on a unit of mass entering the turbine at the highest pressure. 30

Below is a plot of cycle thermal efficiency versus the open feedwater heater pressure. The feedwater heater pressure that makes the cycle thermal efficiency a maximum is about 400 kpa. 0.376 0.374 0.372 0.370 th vs OFWH Pressure th 0.368 0.366 0.364 0.362 0.360 0 450 900 1350 1800 2250 P ofwh [kpa] 31

Below is a plot of cycle net work per unit mass flow at state 5 and the fraction of mass y extracted for the feedwater heater versus the open feedwater heater pressure. Clearly the net cycle work decreases and the fraction of mass extracted increases with increasing extraction pressure. Why does the fraction of mass extracted increase with increasing extraction pressure? 1200 1150 1100 w net and y vs OFWH Pressure 0.25 0.23 0.20 0.18 w net / 1050 1000 950 0.15 0.13 0.10 0.08 0.05 y 900 0.03 0 450 900 1350 1800 2250 P ofwh [kpa] 32

Placement of Feedwater Heaters The extraction pressures for multiple feedwater heaters are chosen to maximize the cycle efficiency. As a rule of thumb, the extraction pressures for the feedwater heaters are chosen such that the saturation temperature difference between each component is about the same. T T, etc. Example 10-4 cond to FWH boiler to FWH An ideal regenerative steam power cycle operates so that steam enters the turbine at 3 MPa, 500 o C, and exhausts at 10 kpa. Two closed feedwater heaters are to be used. Select starting values for the feedwater heater extraction pressures. 400 Steam T [C] 300 233.9 C 200 100 45.85 C 1 0 3000 kpa T 62.68 T 62.68 T 62.68 10 kpa C C 815 kpa 0 2 4 6 8 10 12 C s [/-K] 136.2 kpa 33

Deviation from Actual Cycles Piping losses--frictional effects reduce the available energy content of the steam. Turbine losses--turbine isentropic (or adiabatic) efficiency. T P 3 3 4s 4a P 4 turb w w actual isentropic s h h h h 3 4a 3 4s The actual enthalpy at the turbine exit (needed for the energy analysis of the next component) is h h ( h h ) 4a 3 turb 3 4s 34

Pump losses--pump isentropic (or adiabatic) efficiency. 2 s 2 a T P 2 1 P 1 pump w isentropic w actual s h h h h 2s 1 2a 1 The actual enthalpy at the pump exit (needed for the energy analysis of the next component) is 1 h2 a h1 ( h2 s h1 ) Condenser losses--relatively small losses that result from cooling the condensate below the saturation temperature in the condenser. pump 35

The following examples you should try on your own. Regenerative Feedwater Heater problem Consider an ideal steam regenerative Rankine cycle with two feedwater heaters, one closed and one open. Steam enters the turbine at 10 MPa and 500 C and exhausts to the condenser at 10 kpa. Steam is extracted from the turbine at 0.7 MPa for the closed feedwater heater and 0.3 MPa for the open one. The extracted steam leaves the closed feedwater heater and is subsequently throttled to the open feedwater heater. Show the cycle on a T-s diagram with respect to saturation lines, and using only the data presented in the data tables given below determine a) the fraction of steam leaving the boiler that is extracted at 0.3 MPa z=0.1425 b) the fraction of steam leaving the boiler that is extracted at 0.7 MPa y=0.06213 c) the heat transfer from the condenser per unit mass leaving the boiler q_out=1509 / d) the heat transfer to the boiler per unit mass leaving the boiler q_in=2677 / e) the mass flow rate of steam through the boiler for a net power output of 250 MW m_dot=214.1 /s f) the thermal efficiency of the cycle. Eta_th=0.4363 36

37

Cogeneration Plant A cogeneration plant is to generate power and process heat. Consider an ideal cogeneration steam plant. Steam enters the turbine from the boiler at 7 MPa, 500 C and a mass flow rate of 30 /s. One-fourth of the steam is extracted from the turbine at 600-kPa pressure for process heating. The remainder of the steam continues to expand and exhausts to the condenser at 10 kpa. The steam extracted for the process heater is condensed in the heater and mixed with the feedwater at 600 kpa. The mixture is pumped to the boiler pressure of 7 MPa. Show the cycle on a T-s diagram with respect to saturation lines, and determine a) the heat transfer from the process heater per unit mass leaving the boiler Qdot,process = 15,774 kw. b) the net power produced by the cycle. Wdot,net = 32,848 kw. c) the utilization factor of the plant Qdot,in = 92,753 kw, Utilization factor = 52.4%. 38

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Combined Gas-Steam Power Cycle Example of the Combined Brayton and Rankine Cycles (a) Explain what s happening in the various process for the hardware shown below. 40