LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA

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1 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance Low-level 8260/ /624 SWRCB MDL RL Attach B ug/l ug/l GCMS ML ug/l ug/l ug/l ug/l ug/l 1,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethene ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3-Dichlorobenzene ,3-Dichloropropene (reported as cis & trans) ,4-Dichlorobenzene Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Ethylbenzene Methylene chloride Tetrachloroethene Toluene trans-1,2-dichloroethene Trichloroethene Vinyl chloride ,2,3-Trichloropropane na -- 1,2-Dibromoethane (EDB) na Naphthalene na Trichlorofluoromethane na -- VOC - Add-ons 8260/ /624 SWRCB MDL RL Attach B ug/l ug/l GCMS ML ug/l ug/l ug/l ug/l ug/l 1,1,2-Trichloro-1,2,2-Trifluoromethane (Freon 113) na -- 1,2-Dichloro-1,1,2-Trichloroethane (Freon 123a) na 2.5 na -- Cyclohexane (TIC) na 2.5 na -- Page 1 of 9

2 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance Oxygenates 8260/ /624 SWRCB MDL RL Attach B ug/l ug/l GCMS ML ug/l ug/l ug/l ug/l ug/l Di-isopropyl Ether (DIPE) na -- Methyl-tert-butyl Ether (MTBE) na -- tert-butanol (TBA) na / /624 SWRCB MDL RL ML 624/8260B A-A+2CVE LOW ug/l ug/l GCMS (ug/l) ug/l ug/l ug/l ug/l ug/l Acrolein Acrylonitrile Chloroethylvinylether ML< MDL SWRCB 625+NDMA+Hydrazine -Standard MDL RL Attach B ug/l ug/l GCMS ML 1,2,4-Trichlorobenzene MDL<ML<RL 1,2-Dichlorobenzene ML< MDL 1,2-Diphenylhydrazine/Azobenzene MDL<ML<RL 1,3-Dichlorobenzene ML< MDL 1,4-Dichlorobenzene ML< MDL 2,4,6-Trichlorophenol MDL<ML<RL ,4-Dichlorophenol MDL<ML<RL 2,4-Dimethylphenol e ML< MDL 2,4-Dinitrophenol ML< MDL 2,4-Dinitrotoluene MDL<ML<RL ,6-Dinitrotoluene MDL<ML<RL 2-Chloronaphthalene Chlorophenol MDL<ML<RL 2-Nitrophenol ,3-Dichlorobenzidine ML< MDL 4,6-Dinitro-2-methylphenol MDL<ML<RL 4-Bromophenyl phenyl ether MDL<ML<RL 4-Chloro-3-methylphenol ML< MDL 4-Chlorophenyl phenyl ether MDL<ML<RL 4-Nitrophenol MDL<ML<RL Acenaphthene ML< MDL Acenaphthylene Anthracene Benzidine ML< MDL Benzo(a)anthracene MDL<ML<RL Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene MDL<ML<RL Page 2 of 9

3 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance Benzo(k)fluoranthene Bis(2-chloroethoxy)methane MDL<ML<RL Bis(2-chloroethyl)ether ML< MDL Bis(2-chloroisopropyl)ether ML< MDL Bis(2-ethylhexyl)phthalate MDL<ML<RL Butyl benzyl phthalate MDL<ML<RL Chrysene Dibenz(a,h)anthracene MDL<ML<RL Diethyl phthalate ML< MDL Dimethyl phthalate ML< MDL Di-n-butyl phthalate MDL<ML<RL Di-n-octyl phthalate MDL<ML<RL Fluoranthene ML< MDL Fluorene Hexachlorobenzene ML< MDL Hexachlorobutadiene ML< MDL Hexachlorocyclopentadiene ML< MDL Hexachloroethane ML< MDL Indeno(1,2,3-cd)pyrene MDL<ML<RL Isophorone ML< MDL Naphthalene ML< MDL Nitrobenzene ML< MDL n-nitrosodimethylamine MDL<ML<RL n-nitroso-di-n-propylamine MDL<ML<RL n-nitrosodiphenylamine ML< MDL Pentachlorophenol MDL<ML<RL Phenanthrene MDL<ML<RL Phenol ML< MDL 2,4,5-Trichlorophenol na -- Pyrene Methylnaphthalene na -- 2-Methylphenol na -- 2-Nitroaniline na -- 3-Nitroaniline na -- 4-Chloroaniline na -- 4-Methylphenol na -- 4-Nitroaniline na -- Aniline na -- Benzoic acid na -- Benzyl alcohol na -- Dibenzofuran na -- SWRCB 625+NDMA+Hydrazine -Low-level MDL RL ML ug/l ug/l GC/MS (ug/l) ug/l ug/l ug/l ug/l ug/l Page 3 of 9

4 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance 1,2,4-Trichlorobenzene ,2-Dichlorobenzene ,2-Diphenylhydrazine/Azobenzene ,3-Dichlorobenzene ,4-Dichlorobenzene ,4,6-Trichlorophenol ,4-Dichlorophenol ,4-Dimethylphenol ,4-Dinitrophenol ,4-Dinitrotoluene ,6-Dinitrotoluene Chloronaphthalene Chlorophenol Nitrophenol ,3-Dichlorobenzidine na ,6-Dinitro-2-methylphenol Bromophenyl phenyl ether Chloro-3-methylphenol MDL<ML<RL 4-Chlorophenyl phenyl ether Nitrophenol Acenaphthene Acenaphthylene Anthracene Benzidine na Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate PL < ML&RL 4.0 Butyl benzyl phthalate Chrysene Dibenz(a,h)anthracene Diethyl phthalate Dimethyl phthalate Di-n-butyl phthalate Di-n-octyl phthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene MDL<ML<RL Hexachlorocyclopentadiene Page 4 of 9

5 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance Hexachloroethane MDL<ML<RL Indeno(1,2,3-cd)pyrene Isophorone Naphthalene Nitrobenzene n-nitrosodimethylamine n-nitroso-di-n-propylamine n-nitrosodiphenylamine Pentachlorophenol Phenanthrene Phenol ,4,5-Trichlorophenol na -- Pyrene SWRCB PCB, LL in Water (EPA 608) MDL RL ML ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Aroclor PL < ML&RL Aroclor PL < ML&RL Aroclor PL < ML&RL Aroclor PL < ML&RL Aroclor PL < ML&RL Aroclor PL < ML&RL Aroclor PL < ML&RL SWRCB Pesticides in Water, Low Level (EPA 608) MDL RL ML ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Aldrin alpha-bhc beta-bhc MDL<ML<RL delta-bhc gamma-bhc (Lindane) Chlordane PL < ML&RL ,4'-DDD PL < ML&RL ,4'-DDE PL < ML&RL ,4'-DDT PL < ML&RL Dieldrin PL < ML&RL Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone na -- Heptachlor Page 5 of 9

6 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance Heptachlor epoxide Methoxychlor na -- Toxaphene PL < ML&RL Chlorpyrifos (525.2) PL < ML < RL 0.02 / 0.74 Diazinon (525.2) PL < ML 0.16 / 0.91 SWRCB MDL RL ML ICP/MS ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Antimony MDL<ML<RL Arsenic Beryllium Cadmium (Low Level test code) MDL<ML<RL / (outfall 008) / Chromium ML<MDL see Cr VI see Cr VI Copper ML<MDL Lead MDL<ML<RL Manganese n/a Nickel MDL<ML<RL Selenium /5 5 (outfall 008) 5 Silver ML<MDL Thallium Zinc ML<MDL (outfall 008) 159 SWRCB MDL RL ML ICP ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Antimony PL < ML&RL Arsenic Beryllium Cadmium PL < ML&RL / (outfall 008) / Chromium see Cr VI see Cr VI Copper PL < ML&RL Lead PL < ML&RL Nickel Selenium PL < ML&RL /5 5 (outfall 008) 5 Silver PL < ML&RL Thallium PL < ML&RL Zinc (outfall 008) 159 Page 6 of 9

7 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance SWRCB MDL RL ML ICP mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l Boron na Iron na Barium na SWRCB ML Mercury ug/l ug/l ug/l ug/l ug/l ug/l Mercury (245.1) PL < ML&RL SWRCB ML Chromium VI ug/l ug/l ug/l ug/l ug/l ug/l Chromium IV (218.6/7199) SWRCB Attach B ML Chromium III (calc) na -- SWRCB MDL RL ML ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Cyanide by SM4500 (was EPA 335.2) PL < ML&RL SWRCB MDL RL ML MFL MFL MFL MFL MFL MFL MFL MFL Asbestos by EPA (TEM) (EMS Lab) na na na SWRCB MDL RL Attach B 8260B-Mod ug/l ug/l ML ug/l ug/l ug/l ug/l ug/l 1,4-Dioxane na -- 3 SWRCB MDL RL Attach B 8015-Mod ug/l ug/l ML ug/l ug/l ug/l ug/l ug/l Volatile Fuel Hydrocarbons na Page 7 of 9

8 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance SWRCB MDL RL Attach B 8015-Mod ug/l ug/l ML ug/l ug/l ug/l ug/l ug/l Extractable Fuel Hydrocarbons (low-level) na SWRCB MDL RL Attach B ug/l ug/l ML (ug/l) ug/l ug/l ug/l ug/l ug/l Perchlorate by EPA na SWRCB MDL RL Attach B ug/l ug/l ML (ug/l) ug/l ug/l ug/l ug/l ug/l 2,3,7,8, TCDD (Vista Lab)* 3.50E E-06 na E E E E-08 2,3,7,8, TCDD (TA West Sac)* na 1.00E-05 na E E E E-08 SWRCB MDL RL Attach B General Chemistry mg/l mg/l mg/l mg/l mg/l mg/l mg/l Suspended Soilids (TSS) na BOD na Conductivity (umhos/cm) na -- Settleable Solids (ml/l) na Oil & Grease (1664-HEM) na Ammonia-N na (outfall 008) 10.1 Turbidity y( (NTU) na -- Total Residual Chlorine na Total Organic Carbon na -- Total Dissolved Solids na / 950 (outfall 008) 950 Chloride na Sulfate na / 300 (outfall 008) 300 Detergents (MBAS) na Nitrate + Nitrite-N na (outfall 008) / 10 8 Nitrate-N na (outfall 008) 8 Nitrite-N na (outfall 008) 1 Fluoride na Page 8 of 9

9 SANTA SUSANA FIELD LABORATORY SURFACE WATER SAMPLING PROGRAM LABORATORY MDLs, REPORTING LIMITS, STATE MINIMUM LEVELS, AND PERMIT LIMITS COMPARISON NPDES PERMIT CA Order No. R Monthly Ave. Daily Max Daily Max Daily Max Receiving Water Limits Limits Limits Limits Limits 001 Benchmark 001 Benchmark Compliance Benchmark Compliance Benchmark 008 Benchmark Laboratory 011 Compliance 011 Compliance 009 Benchmark 009 Compliance Laboratory Laboratory SWRCB vs Compliance 010 Compliance 010 Compliance Analyte 2009 MDL 2009 RL ML ML(1) 019 Compliance 019 Compliance SWRCB MDL RL Attach B Radiochemistry (TA St. Louis) pci/l pci/l ML pci/l pci/l pci/l pci/l pci/l Gross Alpha** na 3.0 na Gross Beta** na 4.0 na Radium ** na 1.0 na Tritium** na 500 na Strontium 90** na 3.0 na Uranium** na 1.35 na Potassium-40** na na na -- Cesium-137** na 20 na -- SWRCB MDL RL Attach B 8315M (Truesdail Lab) ug/l ug/l ML (ug/l) ug/l ug/l ug/l ug/l ug/l Monomethyl hydrazine** na -- Dimethyl hydrazine na Hydrazine na SWRCB MDL RL Attach B Toxicity (Aquatic Lab) % Survival % Survival ML % Survival % Survival % Survival % Survival % Survival Acute Toxicity** na na na TUc TUc TUc TUc TUc TUc Chronic Toxicity** na na na SWRCB MDL RL Attach B Biological MPN MPN ML MPN MPN MPN MPN MPN Total Coliform** na na na -- Fecal Coliform** na na na -- SWRCB = State Water Resources Control Board * The permit limit for 2,3,7,8-TCDD is in the unit of TEQ Equivalent value. ** The SWRCB does not have MLs established for these analyses. As required In the NPDES Permit, a full list of MDL/RL's will be supplied to the RWQCB on an annual basis. Columns are used to compare laboratory's reporting limits (RLs) and method detection limits (MDLs) to the SWRCB MLs and the permit limits (1) This column indicates the status of analytical capabilities if the ML is < the laboratory RL or MDL. If nothing is displayed in the cell, the RL meets the ML and the Permit Limit. -- Laboratory RL meets ML and permit limit requirements The following designations which are in the table, summarize the comparison of RLs, MDLs, MLs, and permit limits: ML< MDL The laboratory MDL does not meet the ML MDL<ML<RL The ML is less than RL, but greater than the MDL PL < ML&RL The established permit limit is less than the ML and the RL Page 9 of 9

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25 Pa. Code Chapter 252 Page 1 of 5. DW/NPW Acidity, as CaCO 8 3 * 585 mg/l. DW/NPW Non-Filterable Residue (TSS) 8 14 mg/l

25 Pa. Code Chapter 252 Page 1 of 5. DW/NPW Acidity, as CaCO 8 3 * 585 mg/l. DW/NPW Non-Filterable Residue (TSS) 8 14 mg/l Microbiology Misc. Analytes NPW Total Coliform, MF 2 CFU/100mL DW/NPW Acidity, as CaCO 8 3 * 585 mg/l NPW Fecal Coliform, MF 2 CFU/100mL NPW Color * 1.7 PC units NPW E.coli, MF 2 CFU/100mL DW/NPW Non-Filterable